PERCHLORIC ACID AR 70% SUITABLE FOR DIAMOND INDUSTRY
- Part number
- RXSOL-60-6605-202
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid.
Applications
It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties.
Dosage and directions
Perchloric acid is produced industrially by two routes. The traditional method exploits the high aqueous solubility of sodium perchlorate (209 g/100 mL of water at room temperature). Treatment of such solutions with hydrochloric acid gives perchloric acid, precipitating solid sodium chloride:
Characteristics and notes
Perchloric acid is useful for preparing perchlorate salts, especially ammonium perchlorate, an important rocket fuel component. Perchloric acid is dangerously corrosive and readily forms potentially explosive mixtures.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | RXSOL-60-6605-202 |
| Product Type | PERCHLORIC ACID 70% AR SUITABLE FOR DIAMOND INDUSTRY |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : Preparation.
Substance name Contents CAS No
Perchloric acid : 70% 7601-90-3
Acetic acid glacial 30% 64-19-7
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Skin corrosion - Category 1A - Danger (CLP : Skin Corr. 1A) H314
Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318
Physical hazards : Oxidizing liquids - Category 1 - Danger (CLP : Ox. Liq. 1) H271
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : O : Oxidizing
C : Corrosive
R Phrase(s) : R5 : Heating may cause an explosion.
R8 : Contact with combustible material may cause fire.
R35 : Causes severe burns.
S Phrase(s) : S1/2 : Keep locked up and out of reach of children.
S23 : Do not breathe the gas, fumes, vapours, spray.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 : Wear suitable protective clothing and gloves & eye/face protecting.
S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show
the label when possible).
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H271 : May cause fire or explosion; strong oxidizer.
H314 : Causes severe skin burns and eye damage.
Precautionary statements
• General : P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
• Prevention : P210: Keep away from heat, sparks, open flames or hot surfaces. – No
smoking.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P260: Do not breathe dust, fume, gas, mist, vapours, spray.
P220: Keep away from clothing - combustible materials.
P264: Wash thoroughly after handling.
• Response : P371+P380+P375: In case of major fire and large quantities : Evacuate area.
Fight
fire remotely due to the risk of explosion.
P301+P330+P331: IF SWALLOWED : Rinse mouth. Do NOT induce vomiting.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated
clothing. Rinse skin with water/shower.
P306+P360: IF ON CLOTHING : Rinse immediately contaminated clothing and skin
with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use for extinction.
• Storage : P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor.
Skin contact : IF ON CLOTHING :
Rinse immediately contaminated clothing and skin with plenty of water before
removing clothes. Wash with plenty of soap and water. Remove/Take off
immediately all contaminated clothing. Immediately call a POISON CENTER or
doctor.
Eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Ingestion : Immediately call a POISON CENTER or doctor. Do NOT induce vomiting.
Rinse mouth.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Causes severe skin burns and eye damage.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : May cause fire or explosion; strong oxidizer.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
Thermal decomposition generates : Corrosive vapours.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment. In case of major fire and large quantities
Evacuate area. Fight fire remotely due to the risk of explosioun.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Special precautions : No naked lights. No smoking. May cause fire or explosion; strong
oxidizer.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Take any precaution to avoid mixing with combustibles. Do not breathe dust,
fume, gas, mist, vapours, spray. Avoid contact during pregnancy or while nursing. Wash
thoroughly after handling.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container closed when not in use. Keep in fireproof place.
Storage regulation : Comply with applicable regulations.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources. Combustible material.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or face shield.
• Others : When using, do not eat, drink or smoke.
Wear fire, flame resistant, retardant clothing.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : No data available.
Decomposition point [°C] : No data available.
Critical temperature [°C] : No data available.
Auto-ignition temperature [°C] : No data available.
Flammability (solid, gas) : No data available.
Flash point [°C] : No data available.
Initial boiling point [°C] : No data available.
Final boiling point [°C] : No data available.
Evaporation rate : No data available.
Vapour pressure [20°C] : No data available.
Vapour density : No data available.
Density [g/cm3] : No data available.
Relative density, liquid (water=1) : No data available.
Solubility in water : No data available.
Log Pow octanol / water at 20°C : No data available.
Viscosity at 40°C [mm2/s] : No data available.
9.2. Other information
Explosive properties : No data available.
Explosion limits - upper [%] : No data available.
Explosion limits - lower [%] : No data available.
Oxidising properties : May cause fire or explosion; strong oxidizer.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
Heat. Sparks. Overheating. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
Thermal decomposition generates : Corrosive vapouurs.
11.1. Information on toxicological effects
Toxicity information : The product has been not fully tested. The calculated risk has
been done under the requirements of the EU regulations.
Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Causes severe skin burns and eye damage. Causes serious eye damage.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : The product has been not fully tested. The calculated risk has
been done under the requirements of the EU regulations.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Hazardous waste due to potential risk of explosion. Dispose of
this material and its container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
14.1. Land transport (ADR-RID)
Proper shipping name : PERCHLORIC ACID
UN N° : 1873
H.I. nr : 558
ADR - Class : 5.1
Labelling - Transport : 5.1 : Oxidizing substances. 8 : Corrosive substance.
ADR - Classification code : OC1
ADR - Group : I
ADR - Packing instructions : P502
ADR - Limited Quantity : 0
ADR - Tunnel code : B/E : Tank carriage: Passage forbidden through tunnels of category
B, C, D y E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : PERCHLORIC ACID
UN N° : 1873
IMO-IMDG - Class or division : 5.1 : Oxidizing substances. ( 8 : Corrosive substance. )
IMO-IMDG - Packing group : I
IMO- IMDG - Packing instructions : P502
IMO-IMDG - Limited quantities : None
IMO-IMDG - Marine pollution : No
EMS-Nr : F-A S-Q
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : PERCHLORIC ACID
UN N° : 1873
IATA - Class or division : 5.1 : Oxidizing substances. ( 8 : Corrosive substance. )
IATA - Packing group : I
IATA - Passenger and Cargo Aircraft : NOT ALLOWED
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 553
- Cargo only - Maximum Quantity/ : 2.5 L
Packing
ERG-Nr : 5C
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
Availability
PERCHLORIC ACID AR 70% SUITABLE FOR DIAMOND INDUSTRY manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
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