PHENOLDISULPHONIC ACID SOLUTION 25%
- Part number
- RXSOL-60-6605-216
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
PHENOL DISULPHONIC ACID is a product provided by Research-Lab Fine Chem Industries. Laboratory reagents are chemicals which are used in laboratories as a part of experimental procedures. PHENOL DISULPHONIC ACID is a 25% weight/volume solution in sulphuric acid.
Applications
Phenoldisulphonic acid was prepared by dissolving 25g of phenol in 150ml of conc. H2SO4. 35ml of fuming H2SO4 (30% SO3) was added and the solution was heated at 100ºC for 2 hours on water bath.
Characteristics and notes
Nitrate reacts with phenoldisulphonic acid (PDA) to produce a nitro derivative, which in alkaline solution develops a yellow colour. ... The colour produced follows Beer's law and is proportional to the concentration of NO3- present in the sample.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | PHENOLDISULPHONIC ACID SOLUTION 25% |
| Part Number | RXSOL-60-6605-216 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS | EC number | Weight |
| PHENOLDISULPHONIC ACID SOLUTION 25% | 7664-93-9 | 231-639-5 | 75 |
| Physical hazards | Based on available data, the classification criteria are not met |
| Signal Word | Danger |
| Health hazards |
Skin Corrosion/Irritation Category 1 A (H314)
Serious Eye Damage/Eye Irritation Category 1 (H318)
|
| Hazard Statements |
H314 - Causes severe skin burns and eye damage. |
| P280 Wear protective gloves.P305 + P351 + P338 | NA. |
| Precautionary statements - response |
P280 - Wear protective gloves/protective clothing/eye protection/face protection P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physicianP280 - Wear protective gloves/protective clothing/eye protection/face protection
P301 + P330 + P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
|
| Response | None |
| Disposal | NA |
| Prevention | NA |
| Supplemental Hazard Statements | None |
| Other hazards | Water reactive |
| General advice | Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. |
| If inhaled | NA |
| Eye Contact | Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required |
| swallowed | NA |
| Skin Contact | Wash off immediately with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Call a physician immediately. |
| Inhalation: | If not breathing, give artificial respiration. Remove from exposure, lie down. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a physician immediately. |
| Ingestion: | Do NOT induce vomiting. Clean mouth with water. Never give anything by mouth to an unconscious person. Call a physician immediately. |
| Notes to Physician | Treat symptomatically. |
| If swallowed | NA |
| Self-Protection of the First Aider | Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. |
| Most important symptoms and effects, both acute and delaye | Causes burns by all exposure routes. Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation: Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated |
| Indication of any immediate medical attention and special treatment needed | Notes to Physician Treat symptomatically |
| Flammability | NA |
| Flash Point | NA |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water mist may be used to cool closed containers. CO 2, dry chemical, dry sand, alcohol-resistant foam. |
| Unsuitable extinguishing media | NA |
| Special hazards arising from the substance or mixture | Thermal decomposition can lead to release of irritating gases and vapors. The product causes burns of eyes, skin and mucous membranes. |
| Further information | NA |
|
Hazardous combustion products |
Carbon monoxide (CO), Carbon dioxide (CO2), Sulfur oxides. |
| Advice for firefighters | As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Thermal decomposition can lead to release of irritating gases and vapors. |
| Protective Equipment | NA |
| Specific Hazards Arising from the Chemical | NA |
| Personal precautions, protective equipment and emergency procedures | Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. |
| Spillage | NA |
| Personal Protection | NA |
| Enviromental Precaution | Should not be released into the environment. See Section 12 for additional Ecological Information |
|
Methods and materials for containment and cleaning |
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal |
| Reference to other sections | Refer to protective measures listed in Sections 8 and 13. |
| Advice on safe handling | NA |
| Advice on protection against fire and explosion | NA |
| Hygiene measures | Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. |
| Precautions for safe handling | Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on clothing. Use only under a chemical fume hood. Do not breathe mist/vapors/spray. Do not ingest. If swallowed then seek immediate medical assistance. Handle under an inert atmosphere. |
| Conditions for safe storage, including any incompatibilities | Keep containers tightly closed in a dry, cool and well-ventilated place. Corrosives area. Store under an inert atmosphere. Protect from moisture. |
| Storage conditions | Tightly closed. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Light sensitive. Moisture sensitive. |
| Storage conditions | NA |
| Storage class | NA |
| Specific end use(s) | Use in laboratories |
| Handling | NA |
| Advice on general occupational hygiene | NA |
| Occupational Exposure limit values | No data available |
| Biological limit values | No data available |
| Exposure controls | Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the riskelimination area |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Eye/face protection | Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US) |
| Body Protection | protective clothing |
| Skin protection | Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. |
| Respiratory protection | If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Thermal hazards | No data available |
Gloves Suit
| Physical state | Liquid |
| Colour | Off-white |
| Odour | Odorless |
| Odor Threshold | Not Applicable |
| pH | Not Applicable |
| Melting Point | No data available |
| Boiling Point | No data available |
| Flash Point | No data available |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No Data Available |
| Density | 1.82 |
| Vapour Density | No Data Available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | Water reactive |
| Ignition temperature | No information available. |
| Particle characteristics | Not applicable (liquid) |
| Reactivity | None known, based on information available |
| Stability | Stable under normal conditions |
| Possibility of hazardous reactions |
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
|
| Conditions to avoid | Incompatible products. Combustible material. Exposure to moist air or water. |
| Incompatible materials | Bases. Water. Combustible material. |
| Hazardous Polymerization | Hazardous polymerization does not occur. |
| Hazardous decomposition products | Carbon monoxide (CO). Carbon dioxide (CO2). Sulfur oxides. |
| Acute toxicity | Oral Based on available data, the classification criteria are not met Dermal No data available Inhalation No data available |
| Component | Sulfuric acid |
| LD50 Oral | 2140 mg/kg ( Rat ) |
| LD50 Dermal | NA |
| LC50 Inhalation | LC50 = 0.375 mg/L ( Rat ) 4 h |
| Skin corrosion/irritation | Category 1 A |
| Serious eye damage/eye irritation | Category 1 |
| Respiratory or skin sensitization | No data available |
| Serious eye damage/eye irritation | No data available |
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | NA |
| Toxic Effects on Human | NA |
| Germ cell mutagenicity | No data available |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans: |
NA |
| Additional Information | Endocrine disrupting properties |
| Assessment | NA |
| Endocrine disrupting properties |
Assess endocrine disrupting properties for human health. This product does not contain any
known or suspected endocrine disruptors.
|
| Persistence and degradability |
Persistence Persistence is unlikely, based on information available.
Degradability Reacts with water.Degradation in sewage treatment plant
Water reactive.
|
| Toxicity | NA |
| Bioaccumulative potential | Product does not bioaccumulate due to reaction with water |
| Toxicity to fish | NA |
| Toxicity to daphnia and other aquatic invertebrates | NA |
| Toxicity to algae | NA |
| Eco Toxicity | Reacts with water so no ecotoxicity data for the substance is available. |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | NA |
| Mobility in soil | Reacts with water Is not likely mobile in the environment |
| Results of PBT and vPvB assessment | Water reactive |
| Endocrine disrupting properties | This product does not contain any known or suspected endocrine disruptors |
| Assessment | NA |
| Other adverse effects |
Persistent Organic Pollutant This product does not contain any known or suspected substance
Ozone Depletion Potential This product does not contain any known or suspected substance
|
| Disposal methods | NA |
| Contaminated packaging | Dispose of this container to hazardous or special waste collection point |
| Waste treatment Method | NA |
|
Waste from Residues/Unused
Products
|
Waste is classified as hazardous. Dispose of in accordance with the European Directives
on waste and hazardous waste. Dispose of in accordance with local regulations.
|
| European Waste Catalogue (EWC) | According to the European Waste Catalog, Waste Codes are not product specific, but application specific. |
| Other Information | Waste codes should be assigned by the user based on the application for which the product was used. Do not empty into drains. Do not flush to sewer. Large amounts will affect pH and harm aquatic organisms |
| UN number |
UN1803 |
| UN proper shipping name |
Phenolsulphonic acid, liquid (Mixture) |
| Transport hazard class(es) |
8 |
| Packaging group |
II |
| Environmental hazards |
No hazards identified |
| Special precautions for user | No special precautions required |
| Further information | NA |
| Transport in bulk according to IMOinstruments | Not applicable, packaged goods |
| Safety, health and environmental regulations/legislation specific for the substance or mixture |
International Inventories X = listed, Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), China (IECSC), Japan (ENCS), Australia
(AICS), Korea (ECL).International Inventories
X = listed, Europe (EINECS/ELINCS/NLP), U.S.A. (TSCA), Canada (DSL/NDSL), Philippines (PICCS), China (IECSC), Japan (ENCS), Australia
(AICS), Korea (ECL).
|
| Safety, health and environmental regulations specific for the product in question | NA |
| National legislation | NA |
| WGK Classification | Water endangering class = 1 (self classification) |
| DSCL (EEC) | NA. |
| Other regulations | NA |
| Chemical Safety Assessment | A Chemical Safety Assessment/Report (CSA/CSR) has not been conducted |
| Component | EINECS | ELINCS | NLP | TSCA | DSL | NDSL | PICCS | ENCS | IECSC | AICS | KECL |
| Sulfuric acid | 231-639-5 | - |
|
X | X | - | X | X | X | X |
KE-32570
0KE-32570KE-3257 0KE-3257
0
|
|
1,3-Benzenedisulfonic acid,
4-hydroxy-
|
202-533-6 | - | X | - | X | - | - | X | X | - |
| Component | Germany - Water Classification (VwVwS) | Germany - TA-Luft Class |
| Sulfuric acid | WGK1 |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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