PHENYL CHLOROFORMATE FOR SYNTHESIS
- Part number
- RXSOL-60-6605-219
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Phenyl chloroformate appears as a colorless liquid with a strong odor. Toxic by ingestion, inhalation and skin absorption. Very irritating to skin and eyes. Used to make other chemicals.
Applications
Phenyl chloroformate has been used in the synthesis of poly(2-(phenoxycarbonyloxy)ethylmethacrylate) and phenyl-(4-vinylphenyl)carbonate.
Characteristics and notes
The method for the preparation of phenyl chloroformate which comprises adding to a solution of phosgene in at least one solvent selected from the group consisting of pentane, hexane, heptane, benzene, toluene and xylene, a slurry containing anhydrous sodium phenolate in at least one material selected from the group
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | PHENYL CHLOROFORMATE FOR SYNTHESIS |
| Part Number | RXSOL-60-6605-219 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS | EC number | Weight |
| PHENYL CHLOROFORMATE FOR SYNTHESIS | 1885-14-9 | 217-547-8 | 156.57 |
| Signal Word | Danger |
| Hazard Statements |
H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.H290 May be corrosive to metals.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H330 Fatal if inhaled.
H335 May cause respiratory irritation.
|
| P280 Wear protective gloves.P305 + P351 + P338 | Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Precautionary statements - response |
P234 Keep only in original packaging.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel
unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
|
| Response | None |
| Disposal | NA |
| Prevention | NA |
| Supplemental Hazard Statements | None |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice |
First aiders need to protect themselves. Show this material safety data sheet to the doctor
in attendance.First aiders need to protect themselves. Show this material safety data sheet to the doctor
in attendance.
|
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist.
Remove contact lenses.
|
| swallowed | After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| Inhalation: | NA |
| Ingestion: | NA |
| Notes to Physician | NA |
| If swallowed | After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | NA |
| Flash Point | NA |
| Suitable extinguishing media | Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | Foam Water |
| Special hazards arising from the substance or mixture |
Carbon oxides Hydrogen chloride gas Combustible. Fire may cause evolution of: Hydrogen chloride gas, Phosgene Caution! in contact with water product releases: Hydrogen chloride gas
Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.
|
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
NA. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | NA |
| Specific Hazards Arising from the Chemical | NA |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | NA. |
| Personal Protection | NA |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions(see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary
measures against static discharge.
|
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | NA |
| Conditions for safe storage, including any incompatibilities | NA |
| Storage conditions | Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label. |
| Storage conditions | NA |
| Storage class |
Storage class (TRGS 510): 6.1A: Combustible, acute toxic Cat. 1 and 2 / very toxic
hazardous materials
|
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling |
NA |
| Advice on general occupational hygiene | NA |
| Occupational Exposure limit values | No data available |
| Biological limit values | No data available |
| Exposure controls | NA |
| Engineering Control | NA |
| Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety
gogglesUse equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety
goggles
|
| Body Protection | protective clothing |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M)
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 240 min Material tested:Butoject® (KCL 898)
|
| Respiratory protection |
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic
compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | NA |
| Control of environmental exposure | Do not let product enter drains. |
| Thermal hazards | No data available |
Gloves Suit
| Physical state | iquid |
| Colour | light yellow |
| Odour | No data available |
| Odor Threshold | Not Applicable |
| pH | Not Applicable |
| Melting Point | Melting point/range: -25 °C |
| Boiling Point |
74 - 75 °C at 17 hPa
187 - 189 °C at 1.013 hPa
|
| Flash Point | 69 °C - closed cup |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure |
0,89 hPa at 20 °C
5,51 hPa at 50 °C
|
| Density | 1,244 g/cm3 |
| Vapour Density | No Data Available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | No data available |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Other safety information |
Relative vapor
density
5,41 - (Air = 1.0)
|
| Reactivity | Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | No data available |
| Incompatible materials | Bases, Strong bases, Alcohols, Amines |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity |
LD50 Oral - Rat - 1.754 mg/kg
LC50 Inhalation - Rat - 4 h - 280 mg/m3 - vapor
LD50 Dermal - Rabbit - 4.939 mg/kg
|
| Skin corrosion/irritation |
Skin - Rabbit
Result: Skin irritation - 24 h
|
| Serious eye damage/eye irritation |
Eyes - Rabbit
Result: Severe eye irritation - 24 h
|
| Respiratory or skin sensitization |
Prolonged or repeated exposure may cause allergic reactions in certain sensitive
individuals.
|
| Serious eye damage/eye irritation |
Eyes - Rabbit
Result: Severe eye irritation - 24 h
|
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | NA |
| Toxic Effects on Human | NA |
| Germ cell mutagenicity | No data available |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | Inhalation - May cause respiratory irritation |
| Special Remarks on other Toxi Effects on Humans: |
NA |
| Additional Information |
Material is extremely destructive to tissue of the mucous membranes and upper respiratory
tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea
|
| Assessment | NA |
| Endocrine disrupting properties | NA |
| Persistence and degradability | No data available |
| Toxicity | Toxicity to fish LC50 - Leuciscus idus (Golden orfe) - 10,6 mg/l - 48 h |
| Bioaccumulative potential | No data available |
| Toxicity to fish | NA |
| Toxicity to daphnia and other aquatic invertebrates | NA |
| Toxicity to algae | NA |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | NA |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | No data available |
| Assessment | na |
| Other adverse effects | No data available (Stability in water) |
| Remarks | Hydrolyzes readily. |
| Disposal methods | NA |
| Contaminated packaging | NA |
| Waste treatment Method |
Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.Product
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions.
|
| UN number |
ADR/RID: 2746 IMDG: 2746 IATA: 2746 |
| UN proper shipping name |
ADR/RID: PHENYL CHLOROFORMATE
IMDG: PHENYL CHLOROFORMATE
IATA: Phenyl chloroformate
|
| Transport hazard class(es) |
ADR/RID: 6.1(8) IMDG: 6.1(8) IATA: 6.1 (8) |
| Packaging group |
ADR/RID: II IMDG: II IATA: II |
| Environmental hazards |
ADR/RID: No IMDG: No IATA: No |
| Special precautions for user | No data available |
| Further information | No data available. |
| Tunnel restriction code | (D/E) |
| Transport in bulk according to IMOinstruments | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Safety, health and environmental regulations specific for the product in question | NA |
| National legislation |
Seveso III: Directive 2012/18/EU of the European : ACUTE TOXIC
Parliament and of the Council on the control of major-accident hazards involving dangerous substances.
|
| DSCL (EEC) | NA |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
|
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PALLADIUM NITRATE 44% PD content RXSOL-60-6605-164
PALLADIUM SPONGE 99.9% POWDER RXSOL-60-6605-165
PALLADIUM CALCIUM CARBONATE 10% pd RXSOL-60-6605-166
PARAFFIN WAX 58 60C BLOCK BRICKS RXSOL-60-6605-180
P DIMETHYL AMINO BENZALDEHYDE AR RXSOL-60-6605-192
P DIMETHYL AMINO CINNAMALDEHYDE AR RXSOL-60-6605-193
PEPTONE BACTERIOLOGICAL GRANULAR RXSOL-60-6605-197
PETROLEUM ETHER 100-2000 C FOR SYNTHESIS RXSOL-60-6605-205
PHENOL RED INDICATOR SOLUTION RXSOL-60-6605-215
PHENOLDISULPHONIC ACID SOLUTION 25% RXSOL-60-6605-216
PHENOLPHTHALEIN INDICATOR RXSOL-60-6605-218
PHENYL CHLOROFORMATE FOR SYNTHESIS RXSOL-60-6605-219
PHENYL HYDRAZINE AR RXSOL-60-6605-220
PHENYL HYDRAZINE FOR SYNTHESIS RXSOL-60-6605-221
PHENYL HYDRAZINE HYDROCHLORIDE AR RXSOL-60-6605-223
PHENYL MERCURY ACETATE FOR SYNTHESIS RXSOL-60-6605-224
PHENYL PHOSPHATE DISODIUM SALT AR RXSOL-60-6605-226
PHENYL TRIMETHYL AMMONIUM CHLORIDE RXSOL-60-6605-227
PHLOXIN B FOR MICROSCOPY RXSOL-60-6605-229
PHTHALAMIDE FOR SYNTHESIS RXSOL-60-6605-237
PHTHALIC ACID AR RXSOL-60-6605-238
PHTHALIC ACID FOR SYNTHESIS RXSOL-60-6605-239
PHTHALIC ANHYDRIDE FOR SYNTHESIS RXSOL-60-6605-249
PHTHALIDE FOR SYNTHESIS RXSOL-60-6605-250
PHTHALIMIDE FOR SYNTHESIS RXSOL-60-6605-251
PICRIC ACID SOLUTION AR 1.2% RXSOL-60-6605-256
PIPERAZINE Anhydrous 98% RXSOL-60-6605-257
PIPERAZINE Anhydrous 98% RXSOL-60-6605-257
PIPES BUFFER piperazine NN-Bis-2-Ethene Sulfonic acid RXSOL-60-6605-260
PLATINIUM OXIDE Pt 80% RXSOL-60-6605-261
POLYETHYLENE GLYCOL 600 RXSOL-60-6605-269
POLYVINYL PYRROLIDONE PVP RXSOL-60-6605-241
PONCEAU S FOR ELECTROPHORESIS RXSOL-60-6605-242
POPOP Scintillation Grade 1 4-bis5-phenyloxaza-2yl benzene RXSOL-60-6605-243
POPSO BUFFER FOR BIOCHEMISTRY RXSOL-60-6605-244
POTASSIUM ACETATE AR RXSOL-60-6605-245
POTASSIUM ACETATE LR RXSOL-60-6605-246
SODAMIDE RXSOL-60-6605-451
SODIUM ACETATE TRIHYDRATE AR RXSOL-60-6605-462
SODIUM ARSENITE SOLUTION AR 0.1N N10 RXSOL-60-6605-468
SODIUM BENZOATE AR RXSOL-60-6605-472
SODIUM BISELENITE Sodium Hydrogen Selenite RXSOL-60-6605-473
SODIUM BROMATE LR RXSOL-60-6605-481
SODIUM BROMIDE AR RXSOL-60-6605-482
SODIUM BROMIDE LR RXSOL-60-6605-483
SODIUM CHLORIDE SOLUTION0 85% wv RXSOL-60-6605-488
SODIUM CHROMATE TETRAHYDRATE LR RXSOL-60-6605-490
SODIUM DI CHLOROISOCYANURATE RXSOL-60-6605-495
SODIUM HYDROXIDE SOLUTION IN 1M N1 RXSOL-60-6605-519
SODIUM LAURYL SULPHATE AR 99% RXSOL-60-6605-529
SODIUM LAURYL SULPHATE POWDER LR RXSOL-60-6605-531
SODIUM META BORATE TETRAHYDRATE LR RXSOL-60-6605-534
SODIUM METHOXIDE AR RXSOL-60-6605-535
SODIUM METHOXIDE POWDER LR RXSOL-60-6605-536
SODIUM MOLYBDATE AR DIHYDRATE RXSOL-60-6605-537
SODIUM NITRITE AR RXSOL-60-6605-541
SODIUM NITRITE LR RXSOL-60-6605-542
SODIUM NITRO PRUSIDE AR RXSOL-60-6605-543
SODIUM NITRO PRUSIDE LR RXSOL-60-6605-544
SODIUM OXALATE AR RXSOL-60-6605-545
SODIUM PERBORATE TRIHYDRATE PURE RXSOL-60-6605-548
SODIUM PER CARBONATE GRANULAR RXSOL-60-6605-549
SODIUM PER CARBONATE TABLET RXSOL-60-6605-550
SODIUM PERSULPHATE AR RXSOL-60-6605-553
SODIUM PERSULPHATE LR RXSOL-60-6605-554
SODIUM PHOSPHATE DI BASIC DIHYDRATE RXSOL-60-6605-559
SODIUM PYRUVATE RXSOL-60-6605-562
SODIUM SALICYLATE AR RXSOL-60-6605-563
SODIUM SELENITE AR ANHYDROUS RXSOL-60-6605-566
SODIUM SELENITE LR ANHYDROUS RXSOL-60-6605-567
SODIUM SELENITE PENTAHYDRATE LR RXSOL-60-6605-568
SODIUM SILICATE POWDER META HYDRATED RXSOL-60-6605-569
SODIUM SILICATE SOLUTION RXSOL-60-6605-570
SODIUM SILICO FLUORIDE 99% RXSOL-60-6605-571
SODIUM STANNATE LR RXSOL-60-6605-572
SODIUM SULPHATE ANHYDROUS AR RXSOL-60-6605-573
SODIUM SULPHIDE FLAKES AR RXSOL-60-6605-576
SODIUM SULPHITE ANHYDROUS AR RXSOL-60-6605-577
SODIUM SULPHITE ANHYDROUS LR RXSOL-60-6605-578
SODIUM TELLURITE 96% RXSOL-60-6605-579
SODIUM Tert BUTOXIDE 98% RXSOL-60-6605-580
SODIUM THIOCYANATE AR RXSOL-60-6605-581
SODIUM THIOSULPHATE AR PENTAHYDRATE RXSOL-60-6605-583
Availability
PHENYL CHLOROFORMATE FOR SYNTHESIS manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
PHENYL CHLOROFORMATE FOR SYNTHESIS is available in small packing as well as in bulk. Buy premium quality PHENYL CHLOROFORMATE FOR SYNTHESIS and other lab chemicals from one of the most trusted brands.
