PHENYL HYDRAZINE AR
- Part number
- RXSOL-60-6605-220
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Phenyl-hydrazine is used to prepare indoles by the Fischer indole synthesis, which are intermediates in the synthesis of various dyes and pharmaceuticals.
Applications
Phenylhydrazine is toxic by single exposure via the oral route (LD50 80–188 mg/kg body weight) and is expected to be toxic by the inhalation and dermal routes
Characteristics and notes
Phenylhydrazine is used to form phenylhydrazones of natural mixtures of simple sugars in order to render the differing sugars easily separable from each other.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | PHENYL HYDRAZINE AR |
| Part Number | RXSOL-60-6605-220 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Webside | www.rxmarin.com |
| Chemical Name | CAS | EC number | Weight |
| PHENYL HYDRAZINE AR | 100-63-0 | 202-873-5 | 100% |
| Signal Word | - |
| Hazard Statements |
H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H341 - Suspected of causing genetic defects. H350 - May cause cancer. H372 - Causes damage to organs through prolonged or repeated exposure. H400 - Very toxic to aquatic life. |
| P280 Wear protective gloves.P305 + P351 + P338 | Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Precautionary statements - response |
P201 - Obtain special instructions before use. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER/doctor P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
| Response | None |
| Disposal | NA |
| Prevention | NA |
| Supplemental Hazard Statements | None |
| Other hazards | NA. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical. |
| Butyric Acid | Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. |
| swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | Immediately call a POISON CENTER/doctor. Take off immediately all contaminated clothing. Wash with plenty of water/…. Specific measures (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). If skin irritation or rash occurs |
| Inhalation: | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER/doctor. Specific treatment (see supplemental first aid instruction on this label).l. |
| Ingestion: | Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
| Notes to Physician | Treat symptomatically |
| If swallowed | Toxic if swallowed. |
| Most important symptoms and effects, both acute and delaye | No data available |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | NA |
| Flash Point | NA |
| Suitable extinguishing media | Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media | Do not use a heavy water stream |
| Special hazards arising from the substance or mixture | Carbon oxides Mixture with combustible ingredients. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. |
| Further information | Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | Wear self-contained breathing apparatus for firefighting if necessary. |
| Protective Equipment | Do not attempt to take action without suitable protective equipment |
| Specific Hazards Arising from the Chemical | Has a fire-promoting effect due to the release of oxygen.Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Evacuate unnecessary personnel |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided. |
|
Methods and materials for containment and cleaning |
Clear up rapidly by scoop or vacum |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions |
| Precautions for safe handling | Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam. |
| Conditions for safe storage, including any incompatibilities | Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
| Storage conditions | Tightly closed. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. Light sensitive. Moisture sensitive. |
| Storage conditions | Tightly closed. Dry |
| Storage class | Storage class (TRGS 510): 13: Non Combustible Solids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Occupational Exposure limit values | No data available |
| Biological limit values | No data available |
| Exposure controls | Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the riskelimination area |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Eye/face protection | Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US) |
| Body Protection | protective clothing |
| Skin protection | Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. |
| Respiratory protection | If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Thermal hazards | No data available |
Gloves Suit
| Physical state | Solid |
| Colour | Pale yellow. |
| Odour | Faint aromatic odor. |
| Odor Threshold | Not Applicable |
| pH | Not Applicable |
| Melting Point | 18 - 21 |
| Boiling Point | 238 - 241 |
| Flash Point | 89 °C |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No Data Available |
| Density | 1.098 g/cm³ |
| Vapour Density | No Data Available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | ≥ 0.011 vol % |
| Solubility | DMSO (Slightly), Water (Slightly) |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Relative vapour density at 20 °C | 3.7 |
| Reactivity | No data available |
| Stability | Stable under normal conditions. |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | Direct sunlight. Air contact. Moisture |
| Incompatible materials | No data available |
| Hazardous Polymerization | No data available |
| Acute toxicity | Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed |
| Skin corrosion/irritation | Causes skin irritation |
| Serious eye damage/eye irritation | Causes serious eye irritation |
| Respiratory or skin sensitization | May cause an allergic skin reaction |
| Serious eye damage/eye irritation | No data available |
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat]. |
| Toxic Effects on Human | May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
| Germ cell mutagenicity | No data availableSuspected of causing genetic defects |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans: |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Additional Information | Endocrine disrupting properties |
| Assessment | NA. |
| Endocrine disrupting properties | NA |
| Persistence and degradability | No data available |
| Toxicity | Very toxic to aquatic life. |
| Bioaccumulative potential | No data available |
| Toxicity to fish | No data available |
| Toxicity to daphnia and other aquatic invertebrates | No data available |
| Toxicity to algae | No data available |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | No data available |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | No data available |
| Endocrine disrupting properties | No data available |
| Assessment | No data available |
| Other adverse effects | No data available |
| Disposal methods | The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
| Contaminated packaging | Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. |
| Waste treatment Method | Hazardous waste due to toxicity |
| UN number |
UN-No. (ADR) : 2572 UN-No. (IMDG) : 2572 UN-No. (IATA) : 2572 UN-No. (ADN) : 2572 UN-No.(RID) : 2572 |
| UN proper shipping name |
Proper Shipping Name (ADR) : PHENYLHYDRAZINE Proper Shipping Name (IMDG) : PHENYLHYDRAZINE Proper Shipping Name (IATA) : Phenylhydrazine Proper Shipping Name (ADN) : PHENYLHYDRAZINE Proper Shipping Name (RID) : PHENYLHYDRAZINE Transport document description (ADR) : UN 2572 PHENYLHYDRAZINE, 6.1, II, (D/E), ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 2572 PHENYLHYDRAZINE, 6.1, II, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUSTransport document description (IATA) : UN 2572 Phenylhydrazine, 6.1, II, ENVIRONMENTALLY HAZARDOUS Transport document description (ADN) : UN 2572 PHENYLHYDRAZINE, 6.1, II, ENVIRONMENTALLY HAZARDOUS Transport document description (RID) : UN 2572 PHENYLHYDRAZINE, 6.1, II, ENVIRONMENTALLY HAZARDOUS |
| Transport hazard class(es) |
Transport hazard class(es) (ADR) : 6.1 Danger labels (ADR) : 6.1 IMDG Transport hazard class(es) (IMDG) : 6.1 Danger labels (IMDG) : 6.1 IATA Transport hazard class(es) (IATA) : 6.1 Hazard labels (IATA) : 6.1 ADN Transport hazard class(es) (ADN) : 6.1 Danger labels (ADN) : 6.1 RID Transport hazard class(es) (RID) : 6.1 Danger labels (RID) : 6.1 |
| Packaging group |
Packing group (ADR) : II Packing group (IMDG) : II Packing group (IATA) : II Packing group (ADN) : II Packing group (RID) : II |
| Environmental hazards |
Dangerous for the environment : Yes Marine pollutant : Yes Other information : No supplementary information available |
| Special precautions for user | - Overland transport Classification code (ADR) : T1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Orange plates : Tunnel restriction code (ADR) : D/E EAC code : •3X - Transport by sea Limited quantities (IMDG) : 100 ml Excepted quantities (IMDG) : E4 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A Stowage and handling (IMDG) : SW2 MFAG-No : 153 - Air transport PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L ERG code (IATA) : 6L - Inland waterway transport Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2 |
| - Rail transport | Classification code (RID) : T1 Limited quantities (RID) : 100ml Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage - Loading, unloading and handling (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 60 |
| Transport in bulk according to IMOinstruments | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | NA |
| Safety, health and environmental regulations specific for the product in question | NA |
| National legislation | NA |
| DSCL (EEC) | NA |
| Other regulations | NA |
| Chemical Safety Assessment | NA |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
