PHENYL HYDRAZINE HYDROCHLORIDE AR
- Part number
- RXSOL-60-6605-223
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Phenylhydrazine is a widely used reagent in conjunction with sugars, aldehydes, and ketones. In addition, to its use in the synthesis of dyes; pharmaceuticals, such as antipyrin; cryogenin, and pyramidone; and other organic chemicals. The hydrochloride salt is used in the treatment of polycythemia vera.
Applications
Phenyl-hydrazine is used to prepare indoles by the Fischer indole synthesis, which are intermediates in the synthesis of various dyes and pharmaceuticals. Phenylhydrazine is used to form phenylhydrazones of natural mixtures of simple sugars in order to render the differing sugars easily separable from each other.
Dosage and directions
Osazone test is a chemical test used to detect reducing sugars. This test even allows the differentiation of different reducing sugars on the basis of the time of appearance of the complex. This test is also termed Phenyl hydrazine test based on the reagent used for this test.
Characteristics and notes
Phenylhydrazine is toxic by single exposure via the oral route and is expected to be toxic by the inhalation and dermal routes (data from these routes of exposure are less clear).
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | PHENYL HYDRAZINE HYDROCHLORIDE AR |
| Part Number | RXSOL-60-6605-223 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai, Chennai, Vizag , Kolkata, UAE, OMAN and KENYA
| Phone | +91 22 2087 1200 - 1400 |
| Fax | +91 22 2087 1500 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmarine.com |
| Chemical Name | CAS number | Weight % |
| PHENYL HYDRAZINE HYDROCHLORIDE AR | 59-88-1 | 97% |
| Signal Word | Danger |
|
Hazard statements (CLP) |
H301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H371 - May cause damage to organs H372 - Causes damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life |
| Precautionary statements (CLP) | P260 - Do not breathe dust/fume/gas/mist/vapours/spray P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
| Other hazards | No additional information available |
| Classification according to Regulation (EC) No. 1272/2008 [CLP | Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H301 Specific target organ toxicity — Repeated exposure, Category 1 H372 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Sensitisation — Skin, category 1 H317 Specific target organ toxicity — Single exposure, Category 2 H371 Hazardous to the aquatic environment — Acute H40 |
| Hazard Statements | Physical: H227: Combustible liquid. Health: H304: May be fatal if swallowed and enters airways. |
| Classification according to Directive 67/548/EEC or 1999/45/EC |
Carc.Cat.1; R45 Muta.Cat.3; R68 T; R23/24/25 T; R48/23/24/25 Xi; R36/38 R43 N; R50 Full text of R-phrases: see section 1.
|
| Symptoms/injuries | May cause damage to organs. Causes damage to organs through prolonged or repeated exposure |
| Symptoms/injuries after inhalation | May cause an allergic skin reaction. |
| Symptoms/injuries after skin contact | Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Causes skin irritation. |
| Eye Contact | Flush thoroughly with water. If irritation occurs, get medical assistance. |
| Symptoms/injuries after eye contact | Causes serious eye irritation. |
| Symptoms/injuries after ingestion | Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard. |
| Suitable extinguishing media | dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) |
| Unsuitable extinguishing media | Do not use a heavy water stream |
| Special hazards arising from the substance or mixture | No additional information available |
| Protection during firefighting | Do not attempt to take action without suitable protective equipment |
| Emergency procedures |
Evacuate unnecessary personnel.
|
| Protective equipmen |
Avoid breathing dust/fume/gas/mist/vapours/spray.
|
| Emergency procedures |
Stop release.
|
| Environmental precautions | Very toxic to aquatic life |
| Methods for cleaning up | Clear up rapidly by scoop or vacuum. |
| Reference to other section | No additional information available |
| Precautions for safe handling | Avoid breathing dust/fume/gas/mist/vapours/spray. Do not breathe dust/fume/gas/mist/vapours/spray |
| Hygiene measure | Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
| Storage conditions | Store in original container. Keep container tightly closed. Store in a dry place. Protect from moisture |
| Specific end use(s) | No additional information available |
| Personal protective equipment |
Personal protective equipment
|
| Hand protection |
protective gloves
|
| Eye protection |
Chemical goggles or safety glasses
|
| Skin and body protection |
Wear suitable protective clothing
|
| Respiratory protection | Where exposure through inhalation may occur from use, respiratory protection equipment is recommended |
| Other information |
Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product.
|
Gloves Suit
| Physical State | Solid |
| Molecular mass | 144.61 g/mol |
| Colour | white to cream. |
| Odour | NA |
| Odor Threshold | No data available |
| Relative Density (at 15 °C) | N/D |
| Boiling Point | No data available |
| Flash Point | No data available |
| Density (at 15 ºC): | No data available |
| Evaporation Rate | No data available |
| pH: | No data available |
| Flammability (Solid, Gas): | No data available |
| Flammable Limits (Approximate volume % in air) | No data available |
| Explosive limits | No data available |
| Vapour pressure | No data available |
| Log Pow (n-Octanol/Water Partition Coefficient): | No data available |
| Vapour Density | No data available |
| Secific Gravity | No data available |
| Decomposition Temperature | No data available |
| Solubility in Water | Freely soluble |
| Autoignition Temperature | No data available |
| Solubility in Water | No data available |
| Kintic viscositNo | No data available |
| Vapor Pressure | No data available |
| Molecular Weight | No data available |
| Oxidizing Properties | No data available |
| Freezing Point | No data available |
| Melting Point | 250 - 254 |
| Hygroscopic | No data available |
| Evaporation Rate (n-butyl acetate = 1) | No data available |
| Viscosity | No data available |
| Freezing Point | No data available |
| Reactivity | No additional information available |
| Chemical stability | Stable under normal conditions. |
| InPossibility of hazardous reactions | No additional information available |
| Conditions to avoid | Direct sunlight. Air contact. Moisture. |
| Incompatible materials | No additional information available |
| Hazardous decomposition products | No additional information available |
| Acute toxicity | Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. |
| Skin corrosion/irritatio | Causes skin irritation |
| Serious eye damage/irritation | Causes serious eye irritation. |
| Germ cell mutagenicity | Not classified |
| Carcinogenicity | Not classified. |
| Reproductive toxicity | Not classified |
| Specific target organ toxicity (single exposure) | May cause damage to organs. |
| Specific target organ toxicity (repeated exposure) | Causes damage to organs through prolonged or repeated exposure. |
| Aspiration hazard | Not classified |
| Potential adverse human health effects and symptoms | Toxic if swallowed. Toxic in contact with skin. |
| Ecology - wate | Very toxic to aquatic life. |
| Persistence and degradability |
No additional information available
|
| Mobility in soil | No additional information available |
| Results of PBT and vPvB assessment | No additional information available |
| Other adverse effects | No additional information available |
| Product/Packaging disposal recommendations | Dispose of contents/container to. |
| Ecology - waste materials | Hazardous waste due to toxicity. |
| UN number | UN-No. (ADR) : 2811 UN-No. (IMDG) : 2811 UN-No.(IATA) : 2811 UN-No.(ADN) : 2811 UN-No. (RID) : 2811 |
| UN proper shipping name |
Proper Shipping Name (ADR) : TOXIC SOLID, ORGANIC, N.O.S. Proper Shipping Name (IMDG) : TOXIC SOLID, ORGANIC, N.O.S. Proper Shipping Name (IATA) : TOXIC SOLID, ORGANIC, N.O.S. Proper Shipping Name (ADN) : TOXIC SOLID, ORGANIC, N.O.S. Proper Shipping Name (RID) : TOXIC SOLID, ORGANIC, N.O.S. Transport document description (ADR) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, III, (E), ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, III, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS Transport document description (IATA) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, III, ENVIRONMENTALLY HAZARDOUS Transport document description (ADN) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, III, ENVIRONMENTALLY HAZARDOUS Transport document description (RID) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S., 6.1, III, ENVIRONMENTALLY HAZARDOUS SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code. Marine Pollutant: No |
| ADR | Transport hazard class(es) (ADR) : 6.1 Danger labels (ADR) : 6.1 |
| IMDG | Transport hazard class(es) (IMDG) : 6.1 Danger labels (IMDG) : 6.1 |
| IATA | Transport hazard class(es) (IATA) : 6.1 Hazard labels (IATA) : 6.1 |
| ADN | Transport hazard class(es) (ADN) : 6.1 Danger labels (ADN) : 6.1 |
| RID | Transport hazard class(es) (RID) : 6.1 Danger labels (RID) : 6.1 |
| Packing group | Packing group (ADR) : III Packing group (IMDG) : III Packing group (IATA) : III Packing group (ADN) : III Packing group (RID) : III |
| Environmental hazards | Dangerous for the environment : Yes Marine pollutant : Yes Other information : No supplementary information available |
| Overland transpor | Classification code (ADR) : T2 Special provision (ADR) : 274, 614 Limite uantities (ADR) : 5kg Excepted quantities (ADR) : E1 Packing instructions (ADR) : P002, IBC08, LP02, R001 Special packing provisions (ADR) : B3 Mixed packing provisions (ADR) : MP10 Portable tank and bulk container instructions (ADR) : T1 Portable tank and bulk container special provisions (ADR) : TP33 Tank code (ADR) : SGAH, L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Bulk (ADR) : VC1, VC2, AP7 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9 Hazard identification number (Kemler No.) : 6 Tunnel restriction code (ADR) : E EAC code : 2X |
| Transport by sea | Special provision (IMDG) : 223, 274 Limited quantities (IMDG) : 5 kg Excepted quantities (IMDG) : E1 Packing instructions (IMDG) : P002 IBC packing instructions (IMDG) : IBC08 IBC special provisions (IMDG) : B3 Tank instructions (IMDG) : T1 Tank special provisions (IMDG) : TP33 EmS-No. (Fire) : F-A EmS-No. (Spillage) : S-A Stowage category (IMDG) : A MFAG-No : 154 |
| Air transport | PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y645 PCA limited quantity max net quantity (IATA) : 10kg PCA packing instructions (IATA) : 670 PCA max net quantity (IATA) : 100kg CAO packing instructions (IATA) : 677 CAO max net quantity (IATA) : 200kg Special provision (IATA) : A3, A5 ERG code (IATA) : 6L |
| Inland waterway transport | Classification code (ADN) : T2 Special provisions (ADN) : 274, 614, 802 Limited quantities (ADN) : 5 kg Excepted quantities (ADN) : E1 Carriage permitted (ADN) : T Equipment required (ADN) : PP, EP Number of blue cones/lights (ADN) : 0 |
| Rail transport | Classification code (RID) : T2 Special provision (RID) : 274, 614 Limited quantities (RID) : 5kg Excepted quantities (RID) : E1 Packing instructions (RID) : P002, IBC08, LP02, R001 Special packing provisions (RID) : B3 Mixed packing provisions (RID) : MP10 Portable tank and bulk container instructions (RID) : T1 Portable tank and bulk container special provisions (RID) : TP33 Tank codes for RID tanks (RID) : SGAH, L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE11 Hazard identification number (RID) : 60 |
| Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code | Not applicable |
| EU-Regulations | PHENYL HYDRAZINE HYDROCHLORIDE AR is not on the REACH Candidate List PHENYL HYDRAZINE HYDROCHLORIDE AR is not on the REACH Annex XIV List |
| Germany | AwSV/VwVwS Annex reference : Water hazard class (WGK) 3, strongly hazardous to water (Classification according to VwVwS, Annex 2; WGK No 883) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) |
| Denmark Recommendations Danish Regulation |
Young people below the age of 18 years are not allowed to use the product Pregnant/breastfeeding women working with the product must not be in direct contact with the product The requirements from the Danish Working Environment Authorities regarding work with carcinogens must be followed during use and disposa
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| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
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