PHENYL HYDRAZINE FOR SYNTHESIS
- Part number
- RXSOL-60-6605-221
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
The synthesis of phenylhydrazine involving the diazotization of aniline, the reduction of the resulting diazonium salt with an excess amount of sodium sulfite, and the hydrolysis of phenylhydrazine sulfonic acid salt with hydrochloric acid is known as Fischer phenylhydrazine synthesis.
Applications
Dissolve 15 g PMA in 500 mL distilled water, allow to stand one day, and filter before use through a fluted paper filter. 7. Phenylhydrazine hydrochloride stock solution. Weigh accurately 0.1 g phenylhydrazine hydrochloride into a 100-mL volumetric flask and fill to the mark with 0.1 M HCl.
Dosage and directions
Phenylhydrazine exists as yellow to pale brown crystals or as a yellowish oily liquid. It is sparingly soluble in water and is miscible with other organic solvents.
Characteristics and notes
Osazone test is a chemical test used to detect reducing sugars. This test even allows the differentiation of different reducing sugars on the basis of the time of appearance of the complex. This test is also termed Phenyl hydrazine test based on the reagent used for this test.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | PHENYL HYDRAZINE FOR SYNTHESIS |
| Part Number | RXSOL-60-6605-221 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 2087 1500 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
| Camical Name | CAS | EC number | Weight % |
| PHENYL HYDRAZINE FOR SYNTHESIS | 100-63-0 | 202-873-5 | 98% |
| Signal word | - |
| Classification according to Regulation (EC) No. 1272/2008 [CLP] | Carcinogenicity, Category 1B H350 Acute toxicity (dermal), Category 3 H311 Acute toxicity (inhal.), Category 3 H331 Acute toxicity (oral), Category 3 H30 Specific target organ toxicity — Repeated exposure, Category 1 H372 Germ cell mutagenicity, Category 2 H341 Serious eye damage/eye irritation, Category 2 H319 Skin corrosion/irritation, Category 2 H315 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation H335 Sensitisation — Skin, category 1 H317 Hazardous to the aquatic environment — Acute Hazard, Category 1 H400 |
| Classification according to Directive 67/548/EEC or 1999/45/EC |
Carc.Cat.2; R45 Muta.Cat.3; R68 T; R23/24/25 T; R48/23/24/25 Xi; R36/38 R43 N; R50 Full text of R-phrases: see section 16 |
| Adverse physicochemical, human health and environmental effects |
No additional information available |
| statements Statements | NoneH301+H311+H331 - Toxic if swallowed, in contact with skin or if inhaled H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation H341 - Suspected of causing genetic defects H350 - May cause cancer H372 - Causes damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life |
| Precautionary statements (CLP) | P201 - Obtain special instructions before use P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protectionP301+P310 - IF SWALLOWED: immediately call a POISON CENTER or doctor/physician P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing |
| First-aid measures after inhalation | Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell |
| First-aid measures after skin contact | Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. Specific measures (see ... on this label). Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). If skin irritation or rash occurs: |
| First-aid measures after eye contact | RRinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. emove contaminated clothing Flush exposed area with water and follow by washing with soap if available. |
| First-aid measures after ingestion | Rinse mouth. Obtain emergency medical attention. Immediately call a POISON CENTER or doctor/physician. Specific treatment (see ... on this labe) |
| Symptoms/injuries | Suspected of causing genetic defects. May cause cancer. Causes damage to organs through prolonged or repeated exposure |
| Symptoms/injuries after inhalation | May cause an allergic skin reaction. May cause respiratory irritation |
| Symptoms/injuries after skin contact | Repeated exposure to this material can result in absorption through skin causing significant health hazard. Toxic in contact with skin. Causes skin irritation |
| Symptoms/injuries after eye contact | Causes serious eye irritation. |
| Symptoms/injuries after ingestion | Toxic if swallowed. Swallowing a small quantity of this material will result in serious health hazard |
| Extinguishing media | Dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2). |
| Unsuitable extinguishing media | Do not use a heavy water stream. |
| Protection during firefighting | Do not attempt to take action without suitable protective equipment. |
| Special hazards arising from the substance or mixture | No additional information available |
| Advice for firefighters | Do not attempt to take action without suitable protective equipment. |
| Emergency procedures | Evacuate unnecessary personnel. |
| Protective equipment | Use personal protective equipment as required. |
| Personal Protection | NA |
| Enviromental Precaution | Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Clear up rapidly by scoop or vacuum. |
| Precautions for safe handling | Avoid breathing dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Use personal protective equipment as required. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a wellventilated area. Do not breathe dust/fume/gas/mist/vapours/spray |
| Hygiene measures |
Do not eat, drink or smoke when using this product. Wash ... thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. |
| Storage conditions | Keep container tightly closed. Store in original container. Store in a dry place. Protect from moisture. |
| Hand protection | Protective gloves |
| Eye protection | Chemical goggles or safety glasses |
| Skin and body protection | Wear suitable protective clothing |
| Respiratory protection | Wear respiratory protection |
Gloves Suit
| Physical state | Solid |
| Colour | Pale yellow. |
| Odour | faint aromatic odor |
| Odor Threshold | No data available |
| pH | Not determined |
| Melting Point | 18 - 21 |
| Freezing point | No data available |
| Boiling Point | 238 - 241 |
| Flash Point | 89 °C |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No Data Available |
| Density | 1.098 g/cm³ |
| Vapour Density | No Data Available |
| Relative vapour density at 20 °C | 3.7 |
| Upper/lower flammability or explosive limits |
Upper explosion limit: 10 %(V) Lower explosion limit: 1.2 %(V) |
| Vapour density | NA |
| Relative density | NA |
| Vapour pressure | 1 mm Hg at 71.80C |
| Partition coefficient | NA |
| Auto-ignition emperature | NA |
| Explosive properties | ≥ 0.011 vol % |
| Solubility | DMSO (Slightly), Water (Slightly) |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | No additional information availablee |
| Stability | Stable under normal conditions.. |
| Possibility of hazardous reactions | No additional information available |
| Conditions to avoid | Direct sunlight. Air contact. Moisture. |
| Incompatible materials | No additional information available |
| Hazardous decomposition products | No additional information available |
| Acute toxicity | Dermal: Toxic in contact with skin. Inhalation: Toxic if inhaled. Oral: Toxic if swallowed. |
| Skin corrosion/irritation | Causes skin irritation |
| Serious eye damage/irritation | Causes serious eye irritation |
| Respiratory or skin sensitisation | May cause an allergic skin reaction. |
| Germ cell mutagenicity | Suspected of causing genetic defects. |
| Carcinogenicity | May cause cancer |
| Reproductive toxicity | Not classified |
| Specific target organ toxicity (single exposure) | May cause respiratory irritation. |
| Specific target organ toxicity (repeated exposure) | Causes damage to organs through prolonged or repeated exposure |
| Aspiration hazard | Not classified |
| Potential adverse human health effects and symptoms | Toxic if swallowed. Toxic in contact with skin |
| Bioaccumulative potential | No additional information available |
| Mobility in soil | No additional information available |
| Results of PBT and vPvB assessment | No additional information available |
| Other adverse effects | No additional information available |
| Product/Packaging disposal recommendations | Dispose of contents/container to |
| Ecology - waste materials | Hazardous waste due to toxicity. |
| In accordance with ADR / RID / IMDG / IATA / ADN |
| UN number | UN-No. (ADR) : 2572 UN-No. (IMDG) : 2572 UN-No.(IATA) : 2572 UN-No.(ADN) : 2572 UN-No. (RID) : 2572o |
| UN proper shipping name |
Proper Shipping Name (ADR) : PHENYLHYDRAZINE Proper Shipping Name (IMDG) : PHENYLHYDRAZINE Proper Shipping Name (IATA) : PHENYLHYDRAZINE Proper Shipping Name (ADN) : PHENYLHYDRAZINE Proper Shipping Name (RID) : PHENYLHYDRAZINE Transport document description (ADR) : UN 2572 PHENYLHYDRAZINE, 6.1, II, (D/E), ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 2572 PHENYLHYDRAZINE, 6.1, II, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS Transport document description (IATA) : UN 2572 PHENYLHYDRAZINE, 6.1, II, ENVIRONMENTALLY HAZARDOUS Transport document description (ADN) : UN 2572 PHENYLHYDRAZINE, 6.1, II, ENVIRONMENTALLY HAZARDOUS Transport document description (RID) : UN 2572 PHENYLHYDRAZINE, 6.1, II, ENVIRONMENTALLY HAZARDOUS |
| Transport hazard class(es) |
Transport hazard class(es) (ADR) : 6.1 Danger labels (ADR) : 6.1 IMDG Transport hazard class(es) (IMDG) : 6.1 Danger labels (IMDG) : 6.1 IATA Transport hazard class(es) (IATA) : 6.1 Hazard labels (IATA) : 6.1 ADN Transport hazard class(es) (ADN) : 6.1 Danger labels (ADN) : 6.1 RID Transport hazard class(es) (RID) : 6.1 Danger labels (RID) : 6.1 |
| Packing group | Packing group (ADR) : II Packing group (IMDG) : II Packing group (IATA) : II Packing group (ADN) : II Packing group (RID) : II |
| Environmental hazards | Dangerous for the environment : Yes Marine pollutant : Yes Other information : No supplementary information available |
| Special precautions for user | Overland transport Classification code (ADR) : T1 Limited quantities (ADR) : 100ml Excepted quantities (ADR) : E4 Packing instructions (ADR) : P001, IBC02 Mixed packing provisions (ADR) : MP15 Portable tank and bulk container instructions (ADR) : T7 Portable tank and bulk container special provisions (ADR) : TP2 Tank code (ADR) : L4BH Tank special provisions (ADR) : TU15, TE19 Vehicle for tank carriage : AT Transport category (ADR) : 2 Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28 Special provisions for carriage - Operation (ADR) : S9, S19 Hazard identification number (Kemler No.) : 60 Tunnel restriction code (ADR) : D/E EAC code : •3X |
| - Air transport | PCA Excepted quantities (IATA) : E4 PCA Limited quantities (IATA) : Y641 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 654 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 662 CAO max net quantity (IATA) : 60L ERG code (IATA) : 6L |
| -Inland waterway transport | Classification code (ADN) : T1 Special provisions (ADN) : 802 Limited quantities (ADN) : 100 ml Excepted quantities (ADN) : E4 Equipment required (ADN) : PP, EP, TOX, A Ventilation (ADN) : VE02 Number of blue cones/lights (ADN) : 2 |
| - Rail transport | Classification code (RID) : T1 Limited quantities (RID) : 100ml Excepted quantities (RID) : E4 Packing instructions (RID) : P001, IBC02 Mixed packing provisions (RID) : MP15 Portable tank and bulk container instructions (RID) : T7 Portable tank and bulk container special provisions (RID) : TP2 Tank codes for RID tanks (RID) : L4BH Special provisions for RID tanks (RID) : TU15 Transport category (RID) : 2 Special provisions for carriage – Loading and unloading (RID) : CW13, CW28, CW31 Colis express (express parcels) (RID) : CE5 Hazard identification number (RID) : 60 |
| No REACH Annex XVII restrictions |
| PHENYL HYDRAZINE FOR SYNTHESIS is not on the REACH Candidate List |
| PHENYL HYDRAZINE FOR SYNTHESIS is not on the REACH Annex XIV List |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
