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Product Name |
PROPIONIC ACID |
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Part Number |
RXSOL-19-1429-210 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.comA |
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Chemical Name |
CAS |
EC number |
Weight |
Formula |
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Propionic acid |
79-09-4 |
201-176-3 |
<= 100 % |
C3H6O2 |
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Signal Word |
Danger |
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Hazard Statements |
H226 Flammable liquid and vapor. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. |
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Precautionary statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None. |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Rapidly absorbed through skin. |
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General advice |
First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air. Call in physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
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Suitable extinguishing media |
Water Foam Carbon dioxide (CO2) Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Nature of decomposition products not known. Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire. |
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Further information |
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Enviromental Precaution |
Do not let product enter drains. Risk of explosion. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595). Dispose of properly. Clean up affected area. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
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Precautions for safe handling |
Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. |
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Storage conditions |
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. |
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Storage class |
Storage class (TRGS 510): 3: Flammable liquids |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
Derived No Effect Level (DNEL)
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Application Area |
Routes of exposure |
Health effect |
Value |
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Workers |
Inhalation |
Acute local effects, Acute systemic effects |
62 mg/m3 |
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Workers |
Inhalation |
Long-term local effects, Long-term systemic effects |
31 mg/m3 |
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Workers |
Skin contact |
Long-term systemic effects |
132mg/kg BW/d |
Predicted No Effect Concentration (PNEC)
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Compartment |
Value |
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Soil |
0,1258 mg/kg |
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Sea water |
0,05 mg/l |
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Fresh water |
0,5 mg/l |
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Sea sediment |
0,186 mg/kg |
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Fresh water sediment |
1,86 mg/kg |
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Aquatic intermittent release |
5 mg/l |
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Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Control parameters |
Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
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Body Protection |
Flame retardant antistatic protective clothing. |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 120 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) |
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Respiratory protection |
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Control of environmental exposure |
Do not let product enter drains. Risk of explosion. |
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Physical state |
Clear, liquid |
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Colour |
Colorless |
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Odour |
No data available |
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Odor Threshold |
No data available |
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pH |
2,5 at 100 g/l at 20 °C |
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Melting Point |
24 °C - lit. |
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Boiling Point |
141 °C - lit. |
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Flash Point |
54 °C - closed cup |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
12,1 %(V) / 2,9 %(V) |
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Autoignition temperature |
440 °C at 1.013 hPa |
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Decomposition temperature |
No data available |
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Vapour pressure |
3,2 hPa at 20 °C |
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Density |
0,993 g/mL at 25 °C - lit. |
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Relative Density |
No data available |
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Relative vapor density |
2,56 - (Air = 1.0) |
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Freezing point |
No data available |
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Viscosity dynamic |
10 mPa.s at 25 °C |
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Partition coefficient |
log Pow: 0,25 |
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Explosive properties |
No data available |
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Solubility |
No data available |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Vapor/air-mixtures are explosive at intense warming. |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
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Possibility of hazardous reactions |
Exothermic reaction with: Oxidizing agents Reducing agents alkalines Risk of ignition or formation of inflammable gases or vapours with: Iron Zinc magnesium Lead |
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Conditions to avoid |
Heating. |
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Incompatible materials |
Various plastics |
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - male and female - 3.455,1 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - male and female - 4 h - > 20 mg/l - vapor (OECD Test Guideline 403) LD50 Dermal - Rat - female - 3.235 mg/kg (OECD Test Guideline 402) LD50 Parenteral - Rat - 3.500 mg/kg |
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Skin corrosion/irritation |
Skin - Rabbit Result: Causes burns. |
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Serious eye damage/eye irritation |
Eyes - Rabbit Result: Risk of serious damage to eyes. |
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Respiratory or skin sensitization |
No data available |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
No data available |
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Germ cell mutagenicity |
Test Type: reverse mutation assay Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Chromosome aberration test in vitro Species: Hamster Method: OECD Test Guideline 474 Result: negative |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
Mixture may cause respiratory irritation. |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Additional Information |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Mouse - female - LOAEL (Lowest observed adverse effect level) - 136,9 mg/kg RTECS: UE595000 May cause an asthmatic-like bronchitis., Nausea, Dizziness, Headache, Blood disorders, May cause irritation to eyes and respitatory passages to workers briefly exposed to high concentrations To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Liver - Irregularities - Based on Human Evidence . |
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Bioaccumulative potential |
No data available |
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Persistence and degradability |
Biodegradability aerobic - Exposure time 20 d Result: 93 % - Readily biodegradable. |
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Toxicity to fish |
LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h |
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Toxicity to daphnia and other aquatic invertebrates |
EC50 - Daphnia magna (Water flea) - 4,7 mg/l - 48 h |
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Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 123 mg/l - 72 h (OECD Test Guideline 201) |
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Toxicity to bacteria |
Static test IC50 - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209) |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
No data available |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID: 3463 IMDG:3463 IATA:3463 |
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UN proper shipping name |
ADR/RID:Propionic acid IMDG: Propionic acid IATA:Propionic acid |
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Transport hazard class(es) |
ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3) |
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Packaging group |
ADR/RID: II IMDG: II IATA: II |
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Environmental hazards |
ADR/RID: NO IMDG: NO IATA: NO |
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Further information |
No data available |
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Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : FLAMMABLE LIQUIDS |
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Other regulations |
Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
A Chemical Safety Assessment has been carried out for this substance. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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