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Product Name |
RXSOL-60-6605-361 |
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Product Type |
PYROGALLOL FOR SYNTHESIS |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
2.1. Substance : Pyrogallol
CAS No : 87-66-1
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Acute toxicity (dermal), H312
Category 4
Acute toxicity (inhal.), H332
Category 4
Acute toxicity (oral), H302
Category 4
Germ cell mutagenicity, H341
Category 2
Hazardous to the aquatic H412
environment — Chronic Hazard,
Category 3
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Muta.Cat.3; R68
Xn; R20/21/22
R52/53
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : Xn: Harmful
N : Dangerous for the environment
R Phrase(s):R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R68: Possible risk of irreversible effects.
S Phrase(s) :S36/37 : Wear suitable protective clothing and gloves.
S61: avoid release to the environment . refer to special instruction/safety data sheets.
Hazard pictograms
Signal word : Danger
Hazard statements : H302+H312+H332 - Harmful if swallowed, in contact with skin or
if inhaled
H341 - Suspected of causing genetic defects
H412 - Harmful to aquatic life with long lasting effects
Precautionary statements : P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice.
First-aid measures after skin contact : Immediately call a POISON CENTER or
doctor/physician. Specific measures (see ... on this label). Wash with plenty of soap and
water. Wash contaminated clothing before reuse.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation
persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Call a POISON CENTER or
doctor/physician if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Suspected of causing genetic defects.
Symptoms/injuries after skin contact : Repeated exposure to this material can result in
absorption through skin causing significant health hazard. Harmful in contact with skin.
Symptoms/injuries after ingestion : Swallowing a small quantity of this material will
result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
No additional information available
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Obtain special instructions before use. Use personal
protective equipment as required. Do not handle until all safety precautions have been
read and understood.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ...
thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in original container. Store in a dry place. Protect from
moisture. Keep container tightly closed.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : 5.8 at 10 g/l
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 133 - 134
Freezing point : No data available
Boiling point : 309 °C
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : 4.4
Relative density : No data available
Density : 1.45 g/cm³
Solubility : Water: 60 g/100ml @ 200C
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
No additional information available
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Air contact. Moisture.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Dermal: Harmful in contact with skin. Inhalation: Harmful if inhaled.
Oral: Harmful if swallowed.
Skin corrosion/irritation : Not classified
pH: 5.8 at 10 g/l
Serious eye damage/irritation : Not classified
pH: 5.8 at 10 g/l
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Suspected of causing genetic defects.
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms : Harmful if swallowed. Harmful in
contact with skin.
12.1. Toxicity
Ecology - water : Harmful to aquatic life with long lasting effects.
12.2. Persistence and degradability
PYROGALLOL FOR SYNTHESIS (87-66-1)
Persistence and degradability May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal recommendations : Dispose of contents/container to ...
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 2811
UN-No. (IMDG) : 2811
UN-No.(IATA) : 2811
UN-No.(ADN) : 2811
UN-No. (RID) : 2811
14.2. UN proper shipping name
Proper Shipping Name (ADR) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (IMDG) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (IATA) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (ADN) : TOXIC SOLID, ORGANIC, N.O.S.
Proper Shipping Name (RID) : TOXIC SOLID, ORGANIC, N.O.S.
Transport document description (ADR) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S.,
6.1, III, (E)
Transport document description (IMDG) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S.,
6.1, III
Transport document description (IATA) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S.,
6.1, III
Transport document description (ADN) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S.,
6.1, III
Transport document description (RID) : UN 2811 TOXIC SOLID, ORGANIC, N.O.S.,
6.1, III
14.3. Transport hazard class(es)
ADR : Transport hazard class(es) (ADR) : 6.1
Danger labels (ADR) : 6.1
IMDG : Transport hazard class(es) (IMDG) : 6.1
Danger labels (IMDG) : 6.1
IATA : Transport hazard class(es) (IATA) : 6.1
Hazard labels (IATA) : 6.1
AND : Transport hazard class(es) (ADN) : 6.1
Danger labels (ADN) : 6.1
RID : Transport hazard class(es) (RID) : 6.1
Danger labels (RID) : 6.1
14.4. Packing group
Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards
Dangerous for the environment : No
Marine pollutant : No
Other information : No supplementary information available
14.6. Special precautions for user
- Overland transport Classification code (ADR) : T2
Special provision (ADR) : 274, 614
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Special packing provisions (ADR) : B3
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T1
Portable tank and bulk container special provisions (ADR) : TP33
Tank code (ADR) : SGAH, L4BH
Tank special provisions (ADR) : TU15, TE19
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage – Bulk (ADR) : VC1, VC2, AP7
Special provisions for carriage - Loading, unloading and handling (ADR) : CV13, CV28
Special provisions for carriage – Operation (ADR) : S9
Hazard identification number (Kemler No.) : 60
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 2X
- Transport by sea
Special provision (IMDG) : 223, 274
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-A
Stowage category (IMDG) : A
MFAG-No : 154
- Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y645
PCA limited quantity max net quantity (IATA) : 10kg
PCA packing instructions (IATA) : 670
PCA max net quantity (IATA) : 100kg
CAO packing instructions (IATA) : 677
CAO max net quantity (IATA) : 200kg
Special provision (IATA) : A3, A5
ERG code (IATA) : 6L
- Inland waterway transport
Classification code (ADN) : T2
Special provisions (ADN) : 274, 614, 802
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T
Equipment required (ADN) : PP, EP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : T2
Special provision (RID) : 274, 614
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container instructions (RID) : T1
Portable tank and bulk container special provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAH, L4BH
Special provisions for RID tanks (RID) : TU15
Transport category (RID) : 2
Special provisions for carriage – Bulk (RID) : VC1, VC2, AP7
Special provisions for carriage –
Loading and unloading (RID) : CW13, CW28, CW31
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 60
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
PYROGALLOL FOR SYNTHESIS is not on the REACH Candidate List
PYROGALLOL FOR SYNTHESIS is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water
(Classification according to VwVwS, Annex 3; WGK No 2943)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product
Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.