Perchloric Acid 70%
Perchloric acid, is a clear colorless odorless aqueous solution.
- Part number
- RXSOL-19-6098-025
- Category
- Metal Treatment
- Brand
- RXSOL
Overview
Perchloric acid is a mineral acid with the formula HClO4. Usually found as an aqueous solution, this colorless compound is a stronger acid than sulfuric acid, nitric acid and hydrochloric acid. It is a powerful oxidizer when hot, but aqueous solutions up to approximately 70% by weight at room temperature are generally safe, only showing strong acid features and no oxidizing properties.
Applications
Perchloric acid (HClO4), an oxygen acid of chlorine, is strongly acidic in nature. Hydrates of perchloric acid are obtained on its dissolution in water.
Dosage and directions
Perchloric acid up to concentrations of 72% has properties similar to other strong mineral acids. It is a highly corrosive substance and causes severe burns on contact with the eyes, skin, and mucous membranes.
Characteristics and notes
This corrosive chemical carries hazards typical of most acids; it is harmful if swallowed, causing digestive and respiratory tract burns, and if exposed to the outside of your body can cause eye and skin burns.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Porduct Name | Perchloric Acid 70% |
| Part Number | RXSOL-19-6098-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Product name | Cas No | EC No | Weight | Formula |
| Perchloric acid 70% for analysis | 7601-90-3 | 231-512-4 | >= 70 - < 90 % | HClO4 |
| Signal Word | Danger |
| Hazard Statements | H271 May cause fire or explosion; strong oxidizer. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H373 May cause damage to organs (Thyroid) through prolonged or repeated exposure. |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice/ attention if you feel unwell |
| Classification of the substance or mixture | No data available |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact | After eye contact rinse out with plenty of water. Remove contact lenses. |
| Swallowed | After swallowing make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | No data available |
| Ingestion | No data available |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | No data available |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given |
| Special hazards arising from the substance or mixture |
Not combustible. Fire may cause evolution of: Hydrogen chloride gas Has a fire-promoting effect due to release of oxygen. Ambient fire may liberate hazardous vapours. |
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
No data available |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | No data available |
| Specific Hazards Arising from the Chemical | No data available |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | No data available |
| Personal Protection | No data available |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Reference to other sections | For disposal see section 13. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | No data available |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Conditions for safe storage including any incompatibilities |
No data available |
| Storage conditions | No metal or light-weight-metal containers. No metal containers. Tightly closed. Separately or together with other oxidising substances only and away from sources of ignition and heat.Because of their oxidation potential these products can raise the burning rate of combustible substances substantially or ignite combustible substances on contact with them. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510) 5.1A Strongly oxidizing hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | No data available |
| Exposure controls | Personal protective equipment |
| Engineering Control | No data available |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material butyl-rubber Minimum layer thickness 0,7 mm Break through time 480 min Material tested:Butoject® (KCL 898) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet www.kcl.de). Splash contact Material: Viton® Minimum layer thickness 0,7 mm Break through time: 120 min Material tested Vitoject® (KCL 890 / Aldrich Z677698, Size M) |
| Respiratory protection |
Recommended Filter type Filter type B The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
|
| Other Protection Measure | No data available |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | Odorless |
| Odor Threshold | No data available |
| pH | at 20 °C strongly acid |
| Melting Point | -18 °C |
| Boiling Point | 198,7 °C at 1.013 hPa |
| Flash Point | 9,7 °C - closed cup - Regulation (EC) No. 440/2008, Annex, A.9 |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No data available |
| Viscosity | No data available |
| Density | 1,68 g/cm3 at 20 °C |
| Relative Density | No data available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | No data available |
| Solubility | at 20 °C soluble |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Explosive |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Possibilityof hazardous reactions | Risk of explosion with: semimetals Antimony oxide Metals Hydrogen Impurities organic combustible substances acetic acid Halogenated hydrocarbon Hydrogen halides Fluorine Ether sulfoxides metallic oxides Alcohols acetonitrile Lead oxides Hydrogen chloride gas chromium(VI) oxide dimethyl sulfoxide Iron ferric oxide Acetic anhydride ethanol glycerol Methanol dichloromethane phenol phosphine Oxides of phosphorus pyridine Reducing agents sulfuric acid Sulfur trioxide Halogenated compoundsiron/iron-containing compounds Mild steel carbon Nitric acid with Organic Substances Acetylene with Formaldehyde acetic acid with Acetic anhydride sulfuric acid with Organic Substances Exothermic reaction with: Ketones phosphides Bases Risk of ignition or formation of inflammable gases or vapours with: hydrogen iodide anilines with Formaldehyde |
| Conditions to avoid | No data available |
| Incompatible materials |
Rubber, Light metals, Metals, fatsMetals
|
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | Acute toxicity estimate Oral - 1.572 mg/kg (Calculation method) Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract |
| Skin corrosion/irritation | Mixture causes severe burns. |
| Serious eye damage/irritation | Mixture causes serious eye damage. Risk of blindness! |
| Respiratory or skin sensitization | Sensitisation test - Guinea pig Result negative (OECD Test Guideline 406) |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Test Type Ames test Test system: Salmonella typhimurium |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure |
No data available
|
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. |
| Persistence and degradability | No data available |
| Toxicity to fish | Flow-through test EC50 - Lepomis macrochirus (Bluegill sunfish)- 1.470 mg/l - 96 h (US-EPA) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium perchlorate monohydrat |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202) |
| Toxicity | No data available |
| Toxicity to bacteria | Static test EC50 - activated sludge - > 1.000 mg/l - 3 h (ISO 8192) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium perchlorate |
| Toxicity to algae | Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - > 435,7 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium perchlorate |
| Products Biodegradation | No data available |
| Mobility in soil | Will not adsorb on soil. |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
| Other adverse effects | No data available |
| Product | No data available |
| Contaminated packaging | No data available |
| Waste treatment Method | No data available |
| UN number | ADR/RID:1873 | IMDG:1873 | IATA:1873 |
| UN proper shipping name | ADR/RID:PERCHLORIC ACID | IMDG:PERCHLORIC ACID | IATA:PERCHLORIC ACID |
| Transport hazard class(es) | ADR/RID:5.1 (8) | IMDG:5.1 (8) | IATA:5.1 (8) |
| Packaging group | ADR/RID:l | IMDG:l | IATA:l |
| Environmental hazards | ADR/RID:No | IMDG:No | IATA:No |
| Special precautions for user | Tunnel restriction code (B/E) | ||
| Further information | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | A Chemical Safety Assessment was not carried out for this substance. |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
Availability
PERCHLORIC ACID manufacturers, suppliers, exporters in Mumbai, Gandhidham, Kolkata, Varanasi, Visakhapatnam, Chennai, Fujairah, Dubai, Canada BC, Barka, Sohar, Muscat, Oman.
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