Potassium Ferricyanide NOT FOR SALE
Potassium Ferricyanide
- Part number
- RXSOL-60-6126-025
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Potassium Ferricyanide laboratory grade manufacturer, supplier and exporter.
NOT FOR SALE, EDUCATIONAL PURPOSES ONLY
Technical specifications
| Physical state and appearance | Solid. (crystalline powder.) |
| Odor | Not available |
| Taste | Not available |
| Molecular Weight | 329.25 g/mole |
| Color | Red |
| pH (1% soln/water) | Not available |
| Boiling Point | Not available |
| Melting Point | Decomposes |
| Critical Temperature | Not available |
| Specific Gravity | 1.85 (Water = 1) |
| Vapor Pressure | Not applicable |
| Vapor Density | Not available |
| Volatility | Not available |
| Odor Threshold | Not available |
| Water/Oil Dist. Coeff | Not available |
| Ionicity (in Water) | Not available |
| Dispersion Properties | See solubility in water |
| Solubility | Soluble in cold water |
| Stability | The product is stable |
| Instability Temperature | Not available |
| Conditions of Instability | Heat, light, incompatible materials |
| Incompatibility with various substances | Reactive with acids |
| Corrosivity | Non-corrosive in presence of glass |
Applications
Potassium ferricyanide is also one of two compounds present in ferroxyl indicator solution (along with phenolphthalein) which turns blue (Prussian blue) in the presence of Fe2+ ions, and which can therefore be used to detect metal oxidation that will lead to rust. It is possible to calculate the number of moles of Fe2+ ions by using a colorimeter, because of the very intense color of Prussian blue Fe4[Fe(CN)6]3.
SAFETY :
Potassium ferricyanide has very low toxicity, its main hazard being that it is a mild irritant to the eyes and skin. However, under very strongly acidic conditions, highly toxic hydrogen cyanide gas is evolved, according to the equation:
6 H+ + [Fe(CN)6]3− → 6 HCN + Fe3+[9]
The reaction with hydrochloric acid is as follows:
6 HCl + K3[Fe(CN)6] → 6 HCN + FeCl3 + 3 KCl
Dosage and directions
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NOT FOR SALE, EDUCATIONAL PURPOSES ONLY
Characteristics and notes
IUPAC name : Potassium hexacyanoferrate(III)
Identifiers
CAS number 13746-66-2 Y
PubChem 26250
RTECS number LJ8225000
Properties
Molecular formula C6N6FeK3
Molar mass 329.24 g/mol
Appearance deep red crystals
Density 1.89 g/cm3, solid
Melting point 300 °C, 573 K, 572 °F
Boiling point : decomp.
Solubility in water 330 g/L ("cold water")
464 g/L (20°C)
775 g/L ("hot water")[1]
Solubility slightly soluble in alcohol
soluble in acid
soluble in water
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Potassium Ferricyanide |
| Part Number | RXSOL-60-6126-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmarine.com |
| Chemical Name | CAS | EC .NO | Weight | Formula |
| Potassium hexacyanoferrate | 13746-66-2 | 237-323-3 | 329,25 g/mol | K3Fe(CN)6 |
| Signal Word | Warning |
| Hazard Statements |
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
|
| Precautionary statements - response |
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do Continuerinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P391 Collect spillage.
|
| Response | NA |
| Disposal | NA |
| Storage | NA |
| Prevention | NA |
| Supplemental Hazard Statements | EUH032 Contact with acids liberates very toxic gas. |
| Other hazards |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher
|
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| Eye Contact |
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact
lenses.
|
| Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
|
| Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with
water/ shower.
|
| Inhalation | NA |
| Ingestion | NA |
| Notes to Physician | NA |
| If swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
|
| Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
|
| Indication of any immediate medical attention and special treatment needed | No data available |
| Extinguishing media | NA |
| Flammability | NA |
| Flash Point | NA |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Specific hazards arising from the chemical | NA |
| Special hazards arising from the substance or mixture | Carbon oxides,Nitrogen oxides (NOx),Potassium oxides,Iron oxides,Not combustible.Ambient fire may liberate hazardous vapours |
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fireextinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
NA |
| Advice for firefighters | In the event of fire, wear self-contained breathing apparatus |
| Protective Equipment | NA |
| Hazardous thermal decomposition products | NA |
| Special protective actions for fire-fighters | NA |
| Personal precautions, protective equipment and emergency procedures,For non-emergency personnel |
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact.
Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures,
consult an expert.
|
| For emergency responders | NA |
| Spillage | NA |
| Personal Protection | NA |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions
(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid
generation of dusts.
|
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | NA. |
| Advice on protection against fire and explosion | NA |
| Hygiene measures | NA |
| Precautions fo safe handling | For precautions see section 2.2. |
| Protective measures | NA |
| Conditions for safe storage, including any incompatibilities | NA |
| Storage conditions |
Tightly closed. Dry.Do not store near acids.
Do not store near acids.Tightly closed. Dry.
Do not store near acids.
|
| Storage class | Storage class (TRGS 510): 13: Non Combustible Solids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling | NA |
| Advice on general occupational hygiene | NA |
| Ingredient name | NA |
| Exposure limits | NA |
| Biological limit values | NA |
| Exposure controls | NA |
| Engineering Control | NA |
| Eye/face protection |
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Safety glasses
|
| Body Protection | protective clothing |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).Full contactMaterial: Nitrile rubberMinimum layer thickness: 0,11 mm Break through time: 480 minMaterial tested:KCL 741 Dermatril® L
This recommendation applies only to the product stated in the safety data sheet,
supplied by us and for the designated use. When dissolving in or mixing with other
substances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,Internet: www.kcl.de).Splash contactMaterial: Nitrile rubberMinimum layer thickness: 0,11 mm
Break through time: 480 minMaterial tested:KCL 741 Dermatril® L
|
| Respiratory protection |
required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.Recommended Filter type: Filter type P2
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory
protective devices are carried out according to the instructions of the producer.
These measures have to be properly documented.
|
| Hygiene measures | NA |
| Control of environmental exposure | Do not let product enter drains |
| Thermal hazards | NA |
| Physical state | Powder |
| Colour | Red. |
| Odour | No data available |
| Odor Threshold | Not Applicable |
| pH | Not Applicable |
| Melting Point |
Regulation (EC) No. 440/2008, Annex, A.1Decomposes before
melting.Regulation (EC) No. 440/2008, Annex, A.1Decomposes before
melting.
|
| Boiling Point |
Regulation (EC) No. 440/2008, Annex, A.2Decomposes below
the boiling point.
|
| Flash Point | Not applicable |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | The product is not flammable. |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | Not auto-flammable |
| Decomposition temperature | No data available |
| PH | 6,0 - 9 at 329 g/l at 25 °C |
| Viscosity |
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
|
| Water solubility | 363 g/l - Regulation (EC) No. 440/2008, Annex, A.6 |
| Relative density | 1,893 at 20 °C - Regulation (EC) No. 440/2008, Annex, A.3 |
| Vapour pressure | <0.067 kPa (<0.5 mm Hg) [room temperature] |
| Density | 1,822 g/cm3 |
| Vapour Density | No Data Available |
| Specific Gravity | no data available |
| Partition coefficient | Not applicable for inorganic substances |
| Explosive properties | None |
| Solubility | Insoluble in the following materials: cold water |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Viscosity | Kinematic (40°C (104°F)): 1 to 3 cm2 /s (100 to 300 cSt) |
| Oxidizing properties | None |
| Other safety information | No data available |
| Reactivity | Contact with acids liberates very toxic gas. |
| Stability | NA |
| Possibility of hazardous reactions | A risk of explosion and/or of toxic gas formation exists with the following substances chromium(VI) oxideacids Ammonia hydrochloric acid nitrites Violent reactions possible with: Oxidizing agents Fluorine Hydrogen halides nitratesGenerates dangerous gases or fumes in contact with:Acids. |
| Conditions to avoid | Exposure to light. Exposure to moisture. no information available |
| Incompatible materials | Strong oxidizing agents |
| Hazardous Polymerization | NA |
| Hazardous decomposition products | In the event of fire: see section 5 |
| Acute toxicity | No data available LD50 Oral - Rat - > 5.110 mg/kg (OECD Test Guideline 401) Inhalation: No data available LD50 Dermal - Rat - male and female - > 2.000 mg/kg(OECD Test Guideline 402) |
| Skin corrosion/irritation |
Skin - Human
Result: No skin irritation
(OECD Test Guideline 439)
|
| Serious eye damage/eye irritation | Eyes - Rabbit,Result: Eye irritation,(OECD Test Guideline 405) |
| Respiratory or skin sensitization | Local lymph node assay (LLNA) - Mouse,Result: negative,(OECD Test Guideline429) |
| Rout Of Entry | NA |
| Toxicity to Animal | NA |
| Toxic Effects on Human | NA |
| Germ cell mutagenicity |
Test Type: Ames test Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471 Result: negative
|
| Carcinogenicity | No evidence of carcinogenicity in animal studies. Based on data from similar materials |
| Reproductive toxicity | No toxicity to reproduction Based on data from similar materials |
| Specific target organ toxicity - single exposure | No data available |
| Specific target organ toxicity - repeated exposure | No data available |
| Special Remarks on other Toxi Effects on Humans: |
NA |
| Aspiration hazard | No data available |
| Additional Information | Endocrine disrupting properties |
| Assessment | Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.Repeated dose toxicity - female - Oral - NOAEL (No observed adverse effect level) - >=630 mg/kg Repeated dose toxicity - male - Oral - NOAEL (No observed adverse effect level) ->= 450mg/kg RTECS: LJ8225000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
| Endocrine disrupting properties | NA |
| Persistence and degradability | NA |
| Bioaccumulative potential | No data available |
| Toxicity to fish |
static test LC50 - Cyprinus carpio (Carp) - > 100 mg/l - 96 h
(OECD Test Guideline 203)
|
| Toxicity to daphnia and other aquatic invertebrates |
static test EC50 - Daphnia magna (Water flea) - 59 mg/l - 48 h
(OECD Test Guideline 202)
|
| Toxicity to algae |
static test ErC50 - Pseudokirchneriella subcapitata - 3,1 mg/l - 72 h
(OECD Test Guideline 201)
|
| Eco Toxicity | NA |
| COD and BOD 5 | NA |
| Products Biodegradation: | NA |
| Mobility in soilNo data available | No data available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | NA |
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission
Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
| Other adverse effects | No data available |
| Disposal methods | NA |
| Contaminated packaging | NA |
| Waste treatment Method | No data available |
| UN number |
ADR/RID: 3077 IMDG: 3077 IATA: 3077 |
| UN proper shipping name |
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (tripotassium
hexacyanoferrate(III)) (tripotassium hexacyanoferrate(III))
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (tripotassium
hexacyanoferrate(III)) (tripotassium hexacyanoferrate(III))
IATA: Environmentally hazardous substance, solid, n.o.s. (tripotassiumADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (tripotassium
hexacyanoferrate(III)) (tripotassium hexacyanoferrate(III))
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (tripotassium
hexacyanoferrate(III)) (tripotassium hexacyanoferrate(III))
IATA: Environmentally hazardous substance, solid, n.o.s. (tripotassium
|
| Transport hazard class(es) |
ADR/RID: 9 IMDG: 9 IATA: 9 |
| Packaging group |
ADR/RID: III IMDG: III IATA: III |
| Environmental hazards |
ADR/RID: yes IMDG Marine pollutant: yes IATA: yes |
| Special precautions for user |
Tunnel restriction code : (-)
Further information : No data available
|
| Further information | NA |
| Transport in bulk according to IMOinstruments | NA |
| U.S. Federal regulations | NA |
| Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006
|
| National legislation |
Seveso III: Directive 2012/18/EU of the European
Parliament and of the Council on the control of
major-accident hazards involving dangerous
substances.
ENVIRONMENTAL HAZARDS
|
| DSCL (EEC) | NA |
| Other regulations | Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. |
| Full text of H-Statements referred to under sections 2 and 3. |
EUH032 Contact with acids liberates very toxic gas.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
|
Availability
NOT FOR SALE, EDUCATIONAL PURPOSES ONLY
