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Product Name |
Potassium Permagnate (50 ML Pkg) |
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Part Number |
RXSOL-60-6110-001 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.comA |
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Chemical Name |
CAS |
EC numbe |
Weight |
Formula |
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Potassium permanganate |
7722-64-7 |
231-760-3 |
<= 100 % |
KMnO4 |
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Signal Word |
Danger |
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Hazard Statements |
H272 May intensify fire; oxidizer. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Brain) through prolonged or repeated exposure if inhaled. H410 Very toxic to aquatic life with long lasting effects. |
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Precautionary statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None. |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air. Call in physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Not flammable or combustible. |
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Flash Point |
Dry powder Dry sand |
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Suitable extinguishing media |
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Potassium oxides Manganese/manganese oxides Not combustible. Has a fire-promoting effect due to release of oxygen. Ambient fire may liberate hazardous vapours. |
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Further information |
Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx) |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.. |
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Precautions for safe handling |
For precautions see section 2.2. |
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Storage conditions |
Tightly closed. Do not store near combustible materials. |
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Storage class |
Storage class (TRGS 510): 5.1B: Oxidizing hazardous materials |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Storage stability |
Recommended storage temperature -20 °C |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
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Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Control parameters |
Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
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Skin Protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
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Body Protection |
Protective clothing |
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Respiratory protection |
Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Hygiene measures |
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. |
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Control of environmental exposure |
Do not let product enter drains. |
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Physical state |
Solid |
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Colour |
No data available |
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Odour |
No data available |
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Odor Threshold |
Not Applicable |
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pH |
No data available |
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Melting Point |
No data available |
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Boiling Point |
No data available |
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Flash Point |
No data available |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
No data available |
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Vapour pressure |
No data available |
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Density |
2,70 g/cm3 at 20 °C |
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Relative Vapour Density |
No data available |
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Freezing point |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
No data available |
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Solubility |
No data available |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
No data available |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
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Possibility of hazardous reactions |
Risk of explosion with: powdered aluminium Ammonia ammonium compounds arsenic Dimethylformamide acetic acid Acetic anhydride formaldehyde oxidisable substances Nitro compounds phosphorus pyridine strong reducing agents hydrochloric acid sulfur Titanium sugars ammonium nitrate sulfuric acid Combustible Liquids Organic Substances mineral acids anhydrides mineral wool Alcohols with sulfuric acid alkali salts with sulfuric acid Risk of ignition or formation of inflammable gases or vapours with: Acetaldehyde Alcohols antimony Aldehydes silanes dimethyl sulfoxide Ethylene glycol ethanol Hydrogen fluoride organic solvent glycerol hydroxylamine Organic Substances oxalic acid sulfuric acid hydrogen sulphide hydrogen peroxide triethanolamine Esters glycerol with sulfuric acid sulfuric acid with Organic Substances Exothermic reaction with: Reducing agents Nitric acid carbides Generates dangerous gases or fumes in contact with: Hydrogen chloride gas |
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Conditions to avoid |
No data available |
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Incompatible materials |
No data available |
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - 750 mg/kg Remarks: (RTECS) Inhalation: No data available LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402) |
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Skin corrosion/irritation |
Skin - Rabbit Result: Corrosive after 4 hours or less of exposure (OECD Test Guideline 404) |
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Serious eye damage/eye irritation |
Remarks: Causes serious eye damage. |
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Respiratory or skin sensitization |
Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
Remarks: No data available |
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Germ cell mutagenicity |
Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Mouse lymphoma test Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: In vivo micronucleus test Species: Rat Cell type: Bone marrow Application Route: Oral Method: OECD Test Guideline 474 Result: negative |
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Reproductive toxicity |
Suspected of damaging the unborn child. |
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Specific target organ toxicity - single exposure |
Inhalation - May cause damage to organs through prolonged or repeated exposure. - Brain |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. RTECS: SD6475000 Contact with skin can cause:, Edema, Necrosis, Effects due to ingestion may include:, methemoglobinema, psychological disturbances, Vomiting, Nausea, Diarrhea To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
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Bioaccumulative potential |
No data available |
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Persistence and degradability |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Toxicity to fish |
Semi-static test LC50 - Poecilia reticulata (guppy) - 0,47 mg/l - 96 h (OECD Test Guideline 203) |
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Toxicity to daphnia and other aquatic invertebrates |
Semi-static test EC50 - Daphnia magna (Water flea) - 0,06 mg/l - 48 h (OECD Test Guideline 202) |
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Toxicity to algae |
Static test ErC50 - Desmodesmus subspicatus (green algae) - 0,8 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Desmodesmus subspicatus (green algae) - 0,32 mg/l - 72 h (OECD Test Guideline 201) |
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Toxicity to bacteria |
Static test EC50 - activated sludge - 164 mg/l - 180 min (OECD Test Guideline 209) |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
No data available |
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Disposal methods |
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID: 1490 IMDG: 1490 IATA: 1490 |
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UN proper shipping name |
ADR/RID:POTASSIUMPERMANGANATE,IMDG:POTASSIUMPERMANGANATE IATA:POTASSIUMPERMANGANATE |
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Transport hazard class |
ADR/RID: 5.1 IMDG: 5.1 IATA: 5.1 |
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Packaging group |
ADR/RID: II IMDG: II IATA: II |
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Environmental hazards |
ADR/RID: yes IMDG: yes IATA: NO |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : OXIDISING LIQUIDS AND SOLIDS : ENVIRONMENTAL HAZARDS : OXIDISING LIQUIDS AND SOLIDS : ENVIRONMENTAL HAZARDS |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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