RXSOL CHEMO PHARMA International Navi Mumbai, India

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SALICYLIC ACID

Part number
RXSOL-19-3720-025
Brand
RXSOL
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Overview

Salicylic acid is an important organic synthetic raw material.

Technical specifications

Physical Properties:

Melting Point  158-161 °C(lit.)
Boiling Point 211 °C(lit.)
Density 1.44
Vapour density 4.8 (vs air)
Vapour pressure 1 mm Hg ( 114 °C)
Refractive index 1,565
Flash point 157 °C
Storage temprature 2-8°C
Solublity Ethanol 1 M at 20 °C, clear, colorless
pKa 2.98(at 25℃)
Form Solid
Colour White to off-white
PH 3.21(1 mM solution);2.57(10 mM solution);2.02(100 mM solution)
Water solublity 1.8 g/L (20 ºC)
Sensitive Light sensitive
Stability Stable. Substances to be avoided include oxidizing agents, strong bases, iodine, fluorine. Combustible. Sensitive to light.
 

Applications

Salicylic acid is widely used, eczema, psoriasis, salicylic acid can be used in acne, dandruff. The concentration of 3%~6%  can be used to horny, higher than 6% of salicylic acid can damage to tissue . Below 40% of concentration is suitable for the treatment of thick cocoon, corns and warts.
  • Salicylic acid can also be added in the treatment of acne and dandruff. Nowadays many famous cosmetic ingredients: in 1993, Clinique CLINIQUE first launched 1% salicylic acid in soft water cream, immediately became one of Clinique's most successful products; In 1998, SK-II crystal induced skin cream added 1.5%BHA ingredients to the original, and salicylic acid has effect of treatment pores and cutin like the egg peeling analogy that caused the market boom; open access Olay popular products activating cream also contains 1.5% BHA components. However, due to the high concentration of salicylic acid, it has a certain degree of damage, cosmetics containing salicylic acid concentration has generally been limited between 0.2%~1.5%, containing salicylic acid cosmetics shall be added to the note of warning signs to determine the safety of long-term use and children under 3 years of age also shall not be used.
  • Salicylic acid is an FDA approved skin care ingredient used for the topical treatment of acne, and it's the only beta hydroxy acid (BHA) used in skin care products. Perfect for oily skin, salicylic acid is best known for its ability to deep clean excess oil out of pores and reduce oil production moving forward. Because salicylic acid keeps pores clean and unclogged, it prevents future whiteheads and blackheads from developing. Salicylic acid also exfoliates dead skin, and its anti-inflammatory properties make it a prime ingredient for those with psoriasis. Salicylic acid naturally occurs in willow bark, sweet birch bark, and wintergreen leaves, but synthetic versions are also used in skin care products.

Dosage and directions

widely used in medicine, pesticides, dyes, rubber, food and perfumes. In the pharmaceutical industry, the main drug productions of salicylic acid are sodium salicylate, wintergreen oil (methyl salicylate), aspirin (acetylsalicylic acid), salicylic acid amine, phenyl salicylate. In dye industry, it is used for production mordant pure yellow , direct yellow 3GN, direct yellow GR, direct brown 3GN, acid mordant brown G, acid mordant yellow GG, acid yellow dye complex. In pesticide production, salicylic acid is used for the synthesis of organic phosphorus pesticide Isocarbophos, intermediate isopropyl salicylate isofenphos methyl and Rodenticide warfarin, coumatetralyl intermediate 4-hydroxycoumarin. In rubber industry, it is used as anti scorching agent and production of ultraviolet absorbent and foaming agent. It is perfume material, used for the preparation of methyl salicylate, salicylic acid ethyl ester; food preservatives, its sodium Salt is mostly used, now a number of countries have been banned; methyl salicylate can be used as oral cleaning agents, such as toothpaste flavor.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Porduct Name               SALICYLIC ACID
Part Number   RXSOL-19-3720-025

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
Website www.rxmraine.com
Chemical Name                 Cas No                        EC No              Whight                          Formula                   
Salicylic acid 69-72-7 200-712-3 138,12 g/mol C7H6O3
Signal Word  Danger
Hazard Statements H302 Harmful if swallowed. H318 Causes serious eye damage. H361d Suspected of damaging the unborn child.
Precautionary statements   P202 Do not handle until all safety precautions have been read and understood. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. 
Classification of the substance or mixture No data available
Supplemental Hazard      Statements No data available
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
General advice Show this material safety data sheet to the doctor in attendance.  
If inhaled After inhalation fresh air. Call in physician.
Eye Contact  After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.
Skin Contact   In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
Inhalation No data available
Ingestion No data available
Most important symptoms and effects, both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed  No data available
Flammability                                                  May be combustible at high temperature.
Suitable extinguishing media  Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 
Special hazards arising from the substance or mixture  Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire
Further information Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion
products		 Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.. 
Protective Equipment Use personal protective equipment.
Specific Hazards Arising from the Chemical Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours.
Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8
Spillage No data available
Personal Protection No data available
Enviromental Precaution Do not let product enter drains. Risk of explosion. 
Methods and materials for
containment and cleaning		 Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. 
Reference to other sections    For disposal see section 13.
Advice on protection against fire and explosion No data available
Incompatible materials  No data available
Hygiene measures No data available
Advice on safe handling No data available
Conditions for safe storage, including any incompatibilities  Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Moisture sensitive.
Storage conditions Tightly closed. Dry. Light sensitive. 
Storage class Storage class (TRGS 510) 11 Combustible Solids
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated 
Exposure controls  Personal Protective equipment
Engineering Control No data available
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection  Protective clothing. 
Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L
Respiratory protection
Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P3 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly docum
Other Protection  Measure No data available
Control of    environmental exposure Do not let product enter drains. Risk of explosion. 
Physical state Crystalline powder 
Colour White
Odour Odourless
Odor Threshold No data available 
pH 2,4 at 20 °C
Melting Point 158 - 161 °C - lit
Boiling Point 211 °C - lit.
Flash Point 157 °C - closed cup 
Evaporation Rate Not Applicable
Flammability (solid, gas) No data available
Explosive limits No Data Available
Upper/lower flammability or explosive limits Lower explosion limit 1,1 %(V) 
Autoignition temperature No data available 
Decomposition temperature  No data available
Vapour pressure 1 hPa at 114 °C                                           
Viscosity No data available 
Density 1,44 g/cm3 at 20 °C
Relative Density No data available  
Specific Gravity No data available 
Partition coefficient Log Pow 2,25 at 25 °C - Bioaccumulation is not expected.
Explosive properties No data available 
Solubility 1.000 g/l at 20 °C
Ignition temperature No information available.
Particle characteristics No data available 
Reactivity                        Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed.
Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . 
Possibility of hazardous reactions Risk of ignition or formation of inflammable gases or vapours with: Fluorine iodine Violent reactions possible with Strong oxidizing agents iron/iron-containing compounds
Conditions to avoid Light. Strong heating.        
Incompatible materials
No data available
Hazardous decomposition products In the event of fire: see section 5
Acute toxicity  LD50 Oral - Rat - male - 891 mg/kg (OECD Test Guideline 401) Oral: Behavioral:Muscle weakness. Acute toxicity estimate Oral - 891 mg/kg (ATE value derived from LD50/LC50 value) Inhalation: No data available LD50 Dermal - Rat - male and female - > 2,000 mg/kg (OECD Test Guideline 402             
Skin corrosion/irritation Skin - Rabbit No skin irritation - 4 h (OECD Test Guideline 404)
Serious eye      damage/irritation Eyes - Rabbit Result: Risk of serious damage to eyes. (Draize Test)  Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Respiratory or skin  sensitization  No data available
Carcinogenicity No data available
Germ cell        mutagenicity  Test Type In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Chromosome aberration test Species: Mouse Cell type: Bone marrow Application Route: Intraperitoneal Method: OECD Test Guideline 475 Result: negative Test Type: sister chromatid exchange assay Species: Mouse Cell type: Bone marrow Application Route: Oral Method: US-EPA
Reproductive toxicity  Suspected of damaging the unborn child.
Specific target organ toxicity - single  exposure
No data available
Additional Information The substance/mixture does not contain components considered to have endocrine Sigma-Aldrich- 247588 Page 10 of 14 The life science business of Merck operates as MilliporeSigma in the US and Canada disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 2 yr - NOAEL (No observed adverse effect level) - 50 mg/kg Remarks: (ECHA) The value is given in analogy to the following substances: methyl salicylate RTECS: VO0525000 Cough, Shortness of breath, Headache, Nausea, Vomiting Mild chronic salicylate intoxication is termed salicylism. Symptoms include: headache, dizziness, ringing in the ears, difficulty in hearing, dimness of vision, mental confusion, lassitude, drowsiness, sweating, thirst, hyperventilation, nausea, vomiting, and occasionally diarrhea. A more severe degree of salicylate intoxication is characterized by more pronounced CNS disturbances (including generalized convulsions and coma), skin eruptions, and marked alterations in acid-base balance. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Persistence and degradability Biodegradability aerobic - Exposure time 4 d Result: > 90 % - Inherently biodegradable.(Regulation (EC) No. 440/2008, Annex, C.9)
Toxicity to fish  Flow-through test LC50 - Pimephales promelas (fathead minnow) - 1.370 mg/l - 96 h (OECD Test Guideline 203) Remarks: The value is given in analogy to the following substances: Sodium salicylate
Toxicity to daphnia and other aquatic invertebrates Static test EC50 - Daphnia magna (Water flea) - 870 mg/l - 48 h (OECD Test Guideline 202)
Toxicity No data available
Toxicity to bacteria  Static test EC50 - Pseudomonas putida - 380 mg/l - 16 h Remarks: (ECHA) The value is given in analogy to the following substances: methyl salicylate
Toxicity to algae Growth inhibition ErC50 - Desmodesmus subspicatus (green algae) - > 100 mg/l - 72 h (OECD Test Guideline 201)
Products Biodegradation No data available
Mobility in soil No data availalble
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects No data available .
Waste treatment      Method No data available
UN number ADR/RID:-  IMDG:-   IATA:-
UN proper shipping name  ADR/RID:Not dengerous goods  IMDG:Not dengerous goods  IATA:Not dengerous goods
Transport hazard class(es)      ADR/RID:-  IMDG:-  IATA:-
Packaging group ADR/RID:-  IMDG:-  IATA:-
Environmental hazards ADR/RID:No  IMDG:No  IATA:No
Special precautions for user No data available    
Further information No data available    
Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment A Chemical Safety Assessment has been carried out for this substance. 
Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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