RXSOL CHEMO PHARMA International Navi Mumbai, India

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Lab Chemical

SODAMIDE

Part number
RXSOL-60-6605-451
Category
Lab Chemical
Brand
RXSOL
RXSOL

Overview

sodamide a white crystalline compound used as a dehydrating agent, as a chemical reagent, and in making sodium cyanide. Formula NaNH 2Also called sodium amide.

Applications

Sodium amide is used in the industrial production of indigo, hydrazine, and sodium cyanide. It is the reagent of choice for the drying of ammonia (liquid or gaseous) and is also widely used as a strong base in organic chemistry, often in liquid ammonia solution.

Dosage and directions

Sodium amide can be prepared by the reaction of sodium with ammonia gas, but it is usually prepared by the reaction in liquid ammonia using iron(III) nitrate as a catalyst. The reaction is fastest at the boiling point of the ammonia, c. −33 °C. An electride, [Na(NH3)6]+e−, is formed as a reaction intermediate.

Characteristics and notes

sodamide. / (ˈsəʊdəˌmaɪd) / noun. a white crystalline compound used as a dehydrating agent, as a chemical reagent, and in making sodium cyanide. Formula: NaNH 2Also called: sodium amide.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Porduct Name               SODAMIDE
Part Number   RXSOL-60-6605-451 

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
Website www.rxmraine.com
Chemical Name                 Cas No                        EC No              Whight                          Formula                   
SODAMIDE       7782-92-5 231-971-0 <= 100 % H2NNa 
Signal Word  Danger
Hazard Statements H314 Causes severe skin burns and eye damage. H412 Harmful to aquatic life with long lasting effects.
Precautionary statements   P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard      information (EU) EUH014 Reacts violently with water. EUH019 May form explosive peroxides. EUH029 Contact with water liberates toxic gas.
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. May form explosive peroxides.
General advice First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled After inhalation: fresh air. Call in physician.
Eye Contact  After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
Swallowed After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.
Skin Contact   In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
Most important symptoms and effects, both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed  No data available
Suitable extinguishing media  Carbon dioxide (CO2) Dry powder Cover with dry sand or cement.
Unsuitable extinguishing media Foam Water
Special hazards arising from the substance or mixture  Sodium oxides Combustible. May not get in touch with: Water Development of hazardous combustion gases or vapours possible in the event of fire.
Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Enviromental Precaution Do not let product enter drains. Risk of explosion.
Methods and materials for
containment and cleaning
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Reference to other sections    For disposal see section 13.
Advice on    safe handling Keep workplace dry. Do not allow product to come into contact with water.
Storage conditions Tightly closed. Keep away from heat and sources of ignition. Never allow product to get in contact with water during storage. Air sensitive. Handle and store under inert gas. Test for peroxide formation periodically and before distillation.
Storage class Storage class (TRGS 510): 4.3: Hazardous materials, which set free flammable gases upon contact with water
Specific end     use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Body Protection protective clothing
Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L
Respiratory protection
required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Control of    environmental exposure Do not let product enter drains. Risk of explosion.
Physical state Solid
Colour Light gray
Odour No data available
pH No data available
Melting Point 210 °C - lit.
Boiling Point 400 °C - lit.
Flash Point Not applicable
Flammability (solid, gas) No data available
Upper/lower flammability or explosive limits No data available
Autoignition temperature No data available
Decomposition temperature  No data available
Vapour pressure No data available                                                       
Viscosity No data available      
Density 1,39 g/cm3 at 20 °C
Relative Density No data available
Partition coefficient Not applicable for inorganic substances
Explosive properties No data available 
Particle characteristics No data available 
Reactivity                        Formation of peroxides possible. The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed. Reacts violently with water. Contact with water liberates toxic gas.
Chemical stability sensitive to moisture Test for peroxide formation before using or discard after 3 months.
Possibility of hazardous reactions No data available
Conditions to avoid Moisture.                                                                                         
Incompatible materials
No data available
Hazardous decomposition products Peroxides In the event of fire: see section 5
Acute toxicity  Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach., Nausea, Vomiting, Diarrhea Symptoms: mucosal irritations, Cough, Shortness of breath, Possible damages:, damage of respiratory tract Dermal: No data available                     
Skin corrosion/irritation Causes severe burns.
Serious eye      damage/irritation Causes serious eye damage. Risk of blindness!
Respiratory or skin    sensitization  No data available
Carcinogenicity No data available
Germ cell        mutagenicity  No data available
Reproductive toxicity  No data available
Specific target organ toxicity - single      exposure
No data available
Additional Information Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Cough, Shortness of breath, Headache, Nausea, Vomiting To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Decomposition of the substance with tissue moisture. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.
Persistence and degradability The methods for determining biodegradability are not applicable to inorganic substances.
Toxicity Toxicity to fish semi-static test LC50 - Danio rerio (zebra fish) - 45 mg/l - 96 h (OECD Test Guideline 203) Remarks: The value is given in analogy to the following substances: Lithium amide Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 22 mg/l - 48 h (OECD Test Guideline 202) Remarks: The value is given in analogy to the following substances: Lithium amide Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 43 mg/l - 72 h (OECD Test Guideline 201) Toxicity to bacteria static test EC50 - activated sludge - 440 mg/l - 3 h (OECD Test Guideline 209) Remarks: The value is given in analogy to the following substances: Lithium amide
Mobility in soil No data available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties Assessment : The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects May be harmful to aquatic organisms due to the shift of the pH. Harmful effect due to pH shift. Forms toxic and corrosive mixtures with water even if diluted. Discharge into the environment must be avoided.
Waste treatment   Method   No data available
UN number ADR/RID:1390                 IMDG:1390           IATA: 1390
UN proper shipping name  ADR/RID:ALKALI METAL AMIDES    IMDG:ALKALI METAL AMIDES  IATA:ALKALI METAL AMIDES 
Transport hazard class(es)      ADR/RID: 4.3        IMDG: 4.3        IATA: 4.3 
Packaging group ADR/RID: II                 IMDG:     II      IATA:II
Environmental hazards ADR/RID: No                     IMDG: No                IATA: No
Special precautions for user No data available
Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out
Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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