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Lab Chemical

SODIUM COBALTINITRITE LR

Part number
RXSOL-60-6605-494
Category
Lab Chemical
Brand
RXSOL
RXSOL

Overview

Sodium Cobaltinitrite LR  is a water-soluble compound which is most commonly utilized for determination of potassium, ammonium, & thallium ions. It is known to have molecular formula CoN6Na3O12 with a molar mass of 403.933 g/mol.

Applications

A new qualitative test for potassium was described by Kamm and Burgess1:- By the addition of sodium cobaltinitrite to a potassium solution containing silver ions an extremely insoluble orange-yellow precipitate of potassium silver cobalti- nitrite is produced.

Dosage and directions

Dissolve 1.583 g of potassium chloride in water, and dilute with water to 500 mL. To 10.0 mL of this solution (20 mg of K2O) in a 50 mL beaker, add 2 mL of 1 N nitric acid and 8 mL of water. Dissolve 5 g of the sodium cobaltinitrite in water, dilute with water to 25 mL, and filter.

Characteristics and notes

In geochemical analysis, sodium cobaltinitrite is used to distinguish alkali feldspars from plagioclase feldspars in thin section.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product Name RXSOL-60-6605-494
Product Type SODIUM COBALTINITRITE LR
Revised date  

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
2.1. Substance : SODIUM COBALTINITRITE
CAS No : 13600-98-1
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Skin corrosion/irritation, H315
Category 2
Serious eye damage/eye H319
irritation, Category 2
Sensitisation — H334
Respiratory, category 1 H317
Sensitisation — Skin,
category 1
Specific target organ
toxicity — Single
exposure, Category 3,
Respiratory tract irritation
H335
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Carc.Cat.3; R40
O; R8
R42
Xi; R36/37/38
R43
Full text of R-phrases: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to
displayExtra classification(s) to display
Symbol(s) : O : Oxidizing
Xn : Harmful
R Phrase(s) : R8 : Contact with combustible material may cause fire
R36/37/38 : Irritating to eyes, respiratory system and skin.
R40 : Limited evidence of a carcinogenic effect.
R42/43 : May cause sensitization by inhalation and skin contact.
S Phrase(s) : S17 : Keep away from combustible material.
S25 : Avoid contact with eyes.
S36/37 : Wear suitable protective clothing and gloves.
Hazard pictograms
Signal word : Danger
Hazard statements (CLP) : H272 - May intensify fire; oxidiser
H315 - Causes skin irritation
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335 - May cause respiratory irritation
Precautionary statements (CLP) : P220 - Keep/Store away from clothing/…/combustible
materials
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or
doctor/physician
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice. First-aid measures after skin contact : Gently wash with plenty of soap
and water. If skin irritation occurs: Get medical advice/attention. First-aid measures after
eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse
cautiously with water for several minutes. If eye irritation persists: Get medical
advice/attention. First-aid measures after ingestion : Rinse mouth out with water. If you
feel unwell, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing
difficulties if inhaled. May cause respiratory irritation. Symptoms/injuries after skin
contact : Causes skin irritation. May cause an allergic skin reaction. Symptoms/injuries
after eye contact : Causes serious eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2). Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May intensify fire; oxidiser.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Stop release.
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Clear up rapidly by scoop or vacuum.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Do not get in eyes, on skin, or on clothing.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before
eating, drinking or smoking and when leaving work.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Store in original container. Keep container tightly closed. Store in a
dry place. Protect from moisture.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 220 °C
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Soluble in water
Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : The substance or mixture is classified as oxidizing with the
subcategory 2.
Explosive limits : No data available
9.2. Other information
No additional information available
10.1. Reactivity
May cause or intensify fire; oxidizer.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No additional information available
10.4. Conditions to avoid
Direct sunlight. Overheating. Open flame. Heat. Sparks. Air contact. Moisture.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Not classified
Skin corrosion/irritation : Causes skin irritation
.Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitisation : May cause allergy or asthma symptoms or breathing
difficulties if inhaled. May cause an allergic skin reaction.
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : May cause respiratory irritation.
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
No additional information available
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1479
UN-No. (IMDG) : 1479
UN-No.(IATA) : 1479
UN-No.(ADN) : 1479
UN-No. (RID) : 1479
14.2. UN proper shipping name
Proper Shipping Name (ADR) : OXIDIZING SOLID, N.O.S
Proper Shipping Name (IMDG) : OXIDIZING SOLID, N.O.S
Proper Shipping Name (IATA) : OXIDIZING SOLID, N.O.S
Proper Shipping Name (ADN) : OXIDIZING SOLID, N.O.S.
Proper Shipping Name (RID) : OXIDIZING SOLID, N.O.S.
Transport document description (ADR) : UN 1479 OXIDIZING SOLID, N.O.S., 5.1, II,
(E) Transport document description (IMDG) : UN 1479 OXIDIZING SOLID, N.O.S., 5.1, II
Transport document description (IATA) : UN 1479 OXIDIZING SOLID, N.O.S., 5.1, II
Transport document description (ADN) : UN 1479 OXIDIZING SOLID, N.O.S., 5.1, II
Transport document description (RID) : UN 1479 OXIDIZING SOLID, N.O.S., 5.1, II
14.3. Transport hazard class(es) ADR : Transport hazard class(es) (ADR) : 5.1
Danger labels (ADR) : 5.1
IMDG :Transport hazard class(es) (IMDG) : 5.1
Danger labels (IMDG) : 5.1
IATA : Transport hazard class(es) (IATA) : 5.1
Hazard labels (IATA) : 5.1
AND : Transport hazard class(es) (ADN) : 5.1
Danger labels (ADN) : 5.1
RID :Transport hazard class(es) (RID) : 5.1
Dang er labels (RID) : 5.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards Dangerous for the environment : No
Marine pollutant : No Other information : No
supplementary information available
14.6. Special precautions for user
- Overland transport Classification code (ADR) : O2
Special provision (ADR) : 274
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP2
Portable tank and bulk container
instructions (ADR) : T3
Portable tank and bulk container special
provisions (ADR) : TP33
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR) : V11
Special provisions for carriage - Loading, unloading and handling (ADR) : CV24
Hazard identification number (Kemler No.) : 50
Orange plates :Tunnel restriction code (ADR) : E
EAC code : 1Y
- Transport by sea
Special provision (IMDG) : 274, 900
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : B
Segregation (IMDG) : SG38, SG49, SG60, SG61
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y544
PCA limited quantity max net quantity
(IATA) : 2.5kg
PCA packing instructions (IATA) : 558
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 562
CAO max net quantity (IATA) : 25kg
Special provision (IATA) : A3
ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : O2
Special provisions (ADN) : 274
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : O2
Special provision (RID) : 274
Limited quantities (RID) : 1kg
Excepted quantities (RID) : E2
Packing instructions (RID) : P002,
IBC08 Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP2
Portable tank and bulk container
instructions (RID) : T3
Portable tank and bulk container special
provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 2
Special provisions for carriage – Packages (RID) : W11
Special provisions for carriage – Loading and unloading (RID) : CW24
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 50
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable 
15.1. Safety, health and environmental regulations/legislation specific for
the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
SODIUM COBALTINITRITE is not on the REACH Candidate List
SODIUM COBALTINITRITE is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product Pregnant/breastfeeding women working with the product must
not be in direct contact with the product
The requirements from the Danish Working Environment Authorities regarding work
with carcinogens must be followed during use and disposal
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was
obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its
correctness. The conditions or methods of handling,storage, use or disposal of the product
are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense
arising out of or in any way connected with the handling, storage, use or disposal of the
product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be
applicable.
8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or safety glasses Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection
8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or safety glasses Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection

 

Product Name RXSOL-60-6605-488
Product Type SODIUM CHLORITE FLAKES 80%
Revised date  

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
2.1. Substance : SODIUM CHLORITE 80%
CAS No : 7758-19-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
2.2. Mixture
Not applicable
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Acute toxicity (oral), H301
Category 3
Acute toxicity (dermal), H310
Category 1
Acute toxicity H330
(inhalation:dust,mist)
Category 1
Skin corrosion/irritation, H314
Category 1
Hazardous to the aquatic H400
environment — Acute
Hazard, Category 1
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Symbol(s) : O : Oxidizing
T : Very toxic
C: Corrosive
N : Dangerous for the environment
R Phrase(s) :R8 : Contact with combustible material may cause fire.
R20: Harmful by inhalation.
R24/25: Toxic in contact with skin and if swallowed.
R32: Contact with acids librates very toxic gas.
R36/37/38: Irritating to eyes, respiratory system and skin.
S Phrase(s) : S17 : Keep away from combustible material.
S26 : In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise
S27: Take off immediately all contaminated clothing
S36 : Wear suitable protective clothing.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Extra labelling to displayExtra classification(s) to display
Hazard pictograms
Signal word : Danger
Hazard statements : H272 - May intensify fire; oxidiser
H301 - Toxic if swallowed
H310+H330 - Fatal in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
H400 - Very toxic to aquatic life
Precautionary statements : P220 - Keep/Store away from clothing/…/combustible
materials
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
3.3. Other hazards
 No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice. First-aid measures after skin contact : Take off contaminated clothing.
Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation
persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth.
Do not induce vomiting. If you feel unwell, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after inhalation : Fatal if inhaled.
Symptoms/injuries after skin contact : Fatal in contact with skin.
Symptoms/injuries after ingestion : Toxic if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May intensify fire; oxidiser.
Explosion hazard : Explosive when mixed with combustible material. Heating may cause
an explosion. Hazardous decomposition products in
case of fire : Thermal decomposition generates : Toxic fumes may be released.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Very toxic to aquatic life.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Large spills: scoop solid spill into closing containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin, eyes and clothing.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ...
thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in original container. Store in a
dry place. Incompatible products : Oxidizing agent. Strong bases. Strong acids.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : 10 - 11
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Appreciable (> 10%) Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : ≥ 0.07 vol %
9.2. Other information
No additional information available
10.1. Reactivity
May cause or intensify fire; oxidizer.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Highly reactive material. Contact with acids liberates very toxic gas.
10.4. Conditions to avoid
Direct sunlight. Heat. Water, humidity.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed. Dermal: Fatal in contact with skin.
Inhalation:dust/mist: Fatal if inhaled.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 10 - 11
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 10 - 11
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms
: Harmful if swallowed. Toxic in contact with skin.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1496
UN-No. (IMDG) : 1496
UN-No.(IATA) : 1496
UN-No.(ADN) : 1496
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM CHLORITE
Proper Shipping Name (IMDG) : SODIUM CHLORITE
Proper Shipping Name (IATA) : SODIUM CHLORITE
Proper Shipping Name (ADN) : SODIUM CHLORITE
Proper Shipping Name (RID) : SODIUM CHLORITE
Transport document description (ADR) : UN 1496 SODIUM CHLORITE, 5.1, II, (E)
, ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 1496 SODIUM CHLORITE, 5.1, II, MARINE POLLUTANT/ENVIRONMENTALLY
HAZARDOUS
Transport document description (IATA) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR : Transport hazard class(es) (ADR) : 5.1
Danger labels (ADR) : 5.1
IMDG :Transport hazard class(es) (IMDG) : 5.1
Danger labels (IMDG) : 5.1
IATA : Transport hazard class(es) (IATA) : 5.1
Hazard labels (IATA) : 5.1
ADN : Transport hazard class(es) (ADN) : 5.1
Danger labels (ADN) : 5.1
RID : Transport hazard class(es) (RID) : 5.1
Danger labels (RID) : 5.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No
supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : O2
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP2
Portable tank and bulk container
instructions (ADR) : T3
Portable tank and bulk container special
provisions (ADR) : TP33
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR) : V11
Special provisions for carriage - Loading,
unloading and handling (ADR) : CV24
Hazard identification number (Kemler No.) : 50
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 1Y
- Transport by sea
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : A
Segregation (IMDG) : SG38, SG49
MFAG-No : 143
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y544
PCA limited quantity max net quantity
(IATA) :
2.5kg
PCA packing instructions (IATA) : 558
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 562
CAO max net quantity (IATA) : 25kg
ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : O2
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : O2
Limited quantities (RID) : 1kg
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP2
Portable tank and bulk container
instructions (RID) : T3
Portable tank and bulk container special
provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID) : W11
Special provisions for carriage – Loading
and unloading (RID) : CW24
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 50
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for
the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Sodium chlorite is not on the REACH Candidate List
Sodium chlorite is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water
(Classification according to VwVwS, Annex 2; WGK No 487)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product Pregnant/breastfeeding women working with the product must
not be in direct contact with the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was
obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its
correctness. The conditions or methods of handling,storage, use or disposal of the product
are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense
arising out of or in any way connected with the handling, storage, use or disposal of the
product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be
applicable.
8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or safety glasses Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection
8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or safety glasses Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection

 

Product Name RXSOL-60-6605-488
Product Type SODIUM CHLORITE FLAKES 80%
Revised date  

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka

Phone +91 22 27815541 / 42
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
2.1. Substance : SODIUM CHLORITE 80%
CAS No : 7758-19-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
2.2. Mixture
Not applicable
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Acute toxicity (oral), H301
Category 3
Acute toxicity (dermal), H310
Category 1
Acute toxicity H330
(inhalation:dust,mist)
Category 1
Skin corrosion/irritation, H314
Category 1
Hazardous to the aquatic H400
environment — Acute
Hazard, Category 1
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Symbol(s) : O : Oxidizing
T : Very toxic
C: Corrosive
N : Dangerous for the environment
R Phrase(s) :R8 : Contact with combustible material may cause fire.
R20: Harmful by inhalation.
R24/25: Toxic in contact with skin and if swallowed.
R32: Contact with acids librates very toxic gas.
R36/37/38: Irritating to eyes, respiratory system and skin.
S Phrase(s) : S17 : Keep away from combustible material.
S26 : In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise
S27: Take off immediately all contaminated clothing
S36 : Wear suitable protective clothing.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Extra labelling to displayExtra classification(s) to display
Hazard pictograms
Signal word : Danger
Hazard statements : H272 - May intensify fire; oxidiser
H301 - Toxic if swallowed
H310+H330 - Fatal in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
H400 - Very toxic to aquatic life
Precautionary statements : P220 - Keep/Store away from clothing/…/combustible
materials
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
3.3. Other hazards
 No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice. First-aid measures after skin contact : Take off contaminated clothing.
Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation
persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth.
Do not induce vomiting. If you feel unwell, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after inhalation : Fatal if inhaled.
Symptoms/injuries after skin contact : Fatal in contact with skin.
Symptoms/injuries after ingestion : Toxic if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May intensify fire; oxidiser.
Explosion hazard : Explosive when mixed with combustible material. Heating may cause
an explosion. Hazardous decomposition products in
case of fire : Thermal decomposition generates : Toxic fumes may be released.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Very toxic to aquatic life.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Large spills: scoop solid spill into closing containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin, eyes and clothing.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ...
thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in original container. Store in a
dry place. Incompatible products : Oxidizing agent. Strong bases. Strong acids.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : 10 - 11
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Appreciable (> 10%) Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : ≥ 0.07 vol %
9.2. Other information
No additional information available
10.1. Reactivity
May cause or intensify fire; oxidizer.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Highly reactive material. Contact with acids liberates very toxic gas.
10.4. Conditions to avoid
Direct sunlight. Heat. Water, humidity.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed. Dermal: Fatal in contact with skin.
Inhalation:dust/mist: Fatal if inhaled.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 10 - 11
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 10 - 11
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms
: Harmful if swallowed. Toxic in contact with skin.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1496
UN-No. (IMDG) : 1496
UN-No.(IATA) : 1496
UN-No.(ADN) : 1496
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM CHLORITE
Proper Shipping Name (IMDG) : SODIUM CHLORITE
Proper Shipping Name (IATA) : SODIUM CHLORITE
Proper Shipping Name (ADN) : SODIUM CHLORITE
Proper Shipping Name (RID) : SODIUM CHLORITE
Transport document description (ADR) : UN 1496 SODIUM CHLORITE, 5.1, II, (E)
, ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 1496 SODIUM CHLORITE, 5.1, II, MARINE POLLUTANT/ENVIRONMENTALLY
HAZARDOUS
Transport document description (IATA) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR : Transport hazard class(es) (ADR) : 5.1
Danger labels (ADR) : 5.1
IMDG :Transport hazard class(es) (IMDG) : 5.1
Danger labels (IMDG) : 5.1

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