SODIUM DICHROMATE DIHYDRATE LR
- Part number
- RXSOL-60-6605-496
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Sodium Dichromate is an odorless, red or red-orange, crystalline (sand-like) solid. It is used as a corrosion inhibitor and to make other chemicals.
Applications
Sodium dichromate is highly corrosive in nature and is a strong oxidizing agent. This substance is usually used to produce other chromium compounds but is also used for drilling muds, metal treatments, wood preservatives, production of dyes and organic chemicals, and as a corrosion inhibitor.
Dosage and directions
Dichromate and chromate salts are oxidizing agents. For the tanning of leather, sodium dichromate is first reduced with sulfur dioxide. In the area of organic synthesis,[2] this compound oxidizes benzylic and allylic C-H bonds to carbonyl derivatives.
Characteristics and notes
Sodium dichromate is the inorganic compound with the formula Na2Cr2O7. Usually, however, the salt is handled as its dihydrate Na2Cr2O7·2H2O. Virtually all chromium ore is processed via conversion to sodium dichromate and virtually all compounds and materials based on chromium are prepared from this salt.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | RXSOL-60-6605-496 |
| Product Type | SODIUM DICHROMATE (DIHYDRATE) |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : Sodium dichromate dihydrate
CAS No :7789-12-0
Substance.
Substance name Contents CAS No
Sodium dichromate dihydrate : 100 % 7789-12-0
Contains no other components or impurities which will influence the classification of the
product
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : O; R8
Carc. Cat. 2; R45
Muta. Cat. 2; R46
Repr. Cat. 2; R60-61
T+; R26
T; R25-R48/23
Xn; R21
C; R34
Xn ; R42/43 N; R50-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Carcinogenicity - Category 1B - Danger (CLP : Carc. 1B) H350
Reproductive toxicity - Fertility - Category 1B - Danger (CLP : Repr. 1B) H360
Reproductive toxicity - Unborn Child - Category 1B - Danger (CLP : Repr. 1B) H360
Specific Target Organ Toxicity - Repeated exposure - Category 1 - Danger (CLP :
STOT RE 1) H372
Acute toxicity, Oral - Category 3 - Danger (CLP : Acute Tox. 3) H301
Skin sensitisation - Category 1 - Warning (CLP : Skin Sens. 1) H317
Serious eye damage - Category 1 - Danger (CLP : Eye Dam. 1) H318
Skin corrosion - Category 1B - Danger (CLP : Skin Corr. 1B) H314
Acute toxicity, Inhalation - Category 2 - Danger (CLP : Acute Tox. 2) H330
Respiratory sensitization - Category 1 - Danger (CLP : Resp. Sens. 1) H334
Germ cell mutagenicity - Category 1B - Danger (CLP : Muta. 1B) H340
Acute toxicity, dermal - Category 4 - Warning (CLP : Acute Tox. 4) H312
Physical hazards : Oxidizing solids - Category 1 - Danger (CLP : Ox. Sol. 1) H271
Environmental hazards : Hazardous to the aquatic environment - Acute hazard -
Category 1 - Warning (CLP : Aquatic Acute 1) H400
Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning ( CLP :
Aquatic Chronic 1) H410
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : T+ : Very toxic
N : Dangerous for the environment O :
Oxidizing
R Phrase(s) : R45 : May cause cancer.
R46 : May cause heritable genetic damage.
R60 : May impair fertility.
R61 : May cause harm to the unborn child.
R8 : Contact with combustible material may cause fire.
R21 : Harmful in contact with skin.
R25 : Toxic if swallowed.
R26 : Very toxic by inhalation.
R34 : Causes burns.
R42/43 : May cause sensitization by inhalation and skin contact.
R48/23 : Toxic : danger of serious damage to health by prolonged exposure through
inhalation.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
S Phrase(s) : S53 : Avoid exposure - obtain special instructions before use.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (show
the label when possible).
S60 : This material and its container must be disposed of as hazardous waste.
S61 : Avoid release to the environment. Refer to special instructions/Safety data
sheets.
Hazard pictograms
Signal words : Danger
Hazard statements : H271 : May cause fire or explosion; strong oxidizer.
H330 : Fatal if inhaled.
H314 : Causes severe skin burns and eye damage.
H301 : Toxic if swallowed.
H350 : May cause cancer.
H340 : May cause genetic defects.
H360F : May damage fertility.
H312 : Harmful in contact with skin.
H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 : May cause an allergic skin reaction.
H372 : Causes damage to organs through prolonged or repeated exposure.
H410 : Very toxic to aquatic life with long lasting effects.
H360D: May damage the unborn child.
Precautionary statements
• General : P201: Obtain special instructions before use.
• Prevention : P210: Keep away from heat, sparks, open flames or hot surfaces. – No
smoking.
P284: Wear respiratory protection.
P280: Wear protective gloves, protective clothing, eye protection, face protection.
P271: Use only outdoors or in a well-ventilated area.
P260: Do not breathe dust, fume, gas, mist, vapours, spray.
P273: Avoid release to the environment.
P220: Keep away from clothing - combustible materials.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
• Response : P371+P380+P375: In case of major fire and large quantities : Evacuate area.
Fight
fire remotely due to the risk of explosion.
P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P301+P330+P331: IF SWALLOWED : Rinse mouth. Do NOT induce vomiting.
P308+P313: If exposed or concerned : get medical advice.
P391: Collect spillage.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated
clothing. Rinse skin with water/shower.
P306+P360: IF ON CLOTHING : Rinse immediately contaminated clothing and skin
with plenty of water before removing clothes.
P333+P313: If skin irritation or rash occurs : Get medical advice.
P342+P311: If experiencing respiratory symptoms : Call a POISON CENTER or doctor.
P363: Wash contaminated clothing before reuse.
P314: Get medical advice if you feel unwell.
P370+P378: In case of fire: Use for extinction.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
Special labelling : Restricted to professional users. (Substances which appear in Part 3 of
Annex VI to Regulation (EC) No 1272/2008)
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing.
Immediately call a POISON CENTER or doctor. Specific treatment is urgent (see on this
label). If experiencing respiratory symptoms :
kin contact : Immediately call a POISON CENTER or doctor. If skin irritation or rash
occurs : Get medical advice. Wash with plenty of soap and water. Wash contaminated
clothing before reuse. Remove/Take off immediately all contaminated clothing. Specific
treatment (see on this label). IF ON CLOTHING : Rinse immediately contaminated
clothing and skin with plenty of water before removing clothes
. Eye contact : Rinse cautiously with water for several minutes. Immediately call a
POISON CENTER or doctor. Remove contact lenses, if present and easy to do. Continue
rinsing.
Ingestion : Do NOT induce vomiting. Rinse mouth. Specific treatment (see on this label)
. Immediately call a POISON CENTER or doctor.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : May cause cancer. May cause genetic defects.
Causes damage to organs through prolonged or repeated exposure. Fatal if inhaled.
Causes severe skin burns and eye damage. Causes serious eye damage. May damage
fertility. May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction. May damage the unborn child.
Swallowing a small quantity of this material will result in serious health hazard.
Repeated exposure to this material can result in absorption through skin causing
significant health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : P308+P313: If exposed or concerned : get medical advice. Never
give anything by mouth to an unconscious person. If exposed or concerned : get medical
advice.
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : May cause fire or explosion; strong oxidizer.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
Thermal decomposition generates : Corrosive vapours.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment. In case of major fire and large quantities :
Evacuate area. Fight fire remotely due to the risk of explosion
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Special precautions : No naked lights. No smoking.
May cause fire or explosion; strong oxidizer.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : On land, sweep or shovel into suitable containers. Minimize
generation of dust. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Obtain special instructions before use. Wash contaminated clothing before
reuse. Do not breathe dust, fume, gas, mist, vapours, spray. Contaminated work clothing
should not be allowed out of the workplace. Take any precaution to avoid mixing
with combustibles. Wash thoroughly after handling. Do not eat, drink or smoke when
using this product. Do not eat, drink or smoke when using this product. Eliminate all
ignition sources if safe to do so. Wash thoroughly after handling. Use only outdoors
or in a well-ventilated area.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep in
fireproof place. Keep container tightly closed.
Storage regulation : Comply with applicable regulations.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Heat sources. Combustible material.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear respiratory protection.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or face shield.
• Others : When using, do not eat, drink or smoke.
Wear fire, flame resistant, retardant clothing.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : Not applicable.
Melting point [°C] : 91 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flash point [°C] : N/A
Boiling point [°C] : N/A
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : N/A
Vapour density : 10
Density [g/cm3] : 2,35
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Soluble in water
(73 Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 3.5-4.0
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : May cause fire or explosion; strong oxidizer
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Heat. Sparks.
Overheating. Open flame.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
Thermal decomposition generates : Corrosive vapours.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Fatal if inhaled.
• Dermal : Harmful in contact with skin.
• Ingestion : Toxic if swallowed.
Corrosion : Causes severe skin burns and eye damage. Causes serious eye damage.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : May cause allergy or asthma symptoms or breathing difficulties if
inhaled. May cause an allergic skin reaction.
Mutagenicity : May cause genetic defects.
Carcinogenicity : May cause cancer.
Toxic for reproduction : May damage fertility. May damage the unborn child.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Causes damage to organs through prolonged or repeated
exposure.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Very toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations.
Hazardous waste due to potential risk of explosion.
Dispose of this material and its container to hazardous or special waste collection point, in
accordance with local, regional, national and/or international regulation.
Special precautions : Hazardous waste due to toxicity.
14.1. Land transport (ADR-RID)
Proper shipping name: Oxidizing solid, toxic, n.o.s.
UN N°: 3087
H.I. nr: 665
ADR - Class: 5.1 (6.1)
Labelling - Transport: 5.1 : Oxidizing substances.(6.1 : Toxic substances.)
ADR - Classification code: TO2
ADR - Group: II
ADR - Packing instructions: P002
ADR - Limited Quantity: 0
ADR - Tunnel code: C/E : Tank carriage: Passage forbidden through tunnels of category
C, D and E. Other carriage: Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name: Oxidizing solid, toxic, n.o.s.
UN N°: 3087
IMO-IMDG - Class or division: 5.1 : Oxidizing substances. (6.1 : Toxic substances.)
IMO-IMDG - Packing group: II
IMO- IMDG - Packing instructions: P002
IMO-IMDG - Limited quantities: None
IMO-IMDG - Marine pollution: Yes
EMS-Nr: F-A S-Q
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : Oxidizing solid, toxic, n.o.s.
UN N°: 3087
IATA - Class or division: 5.1 : Oxidizing substances . (6.1 : Toxic substances.)
IATA - Packing group: II
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 665
instruction - Passenger and Cargo - Maximum : 1 kg
Quantity/Packing IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 672
- Cargo only - Maximum Quantity/ : 15 kg
Packing ERG-Nr : 6X
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : With the exception of those listed below:
The components of this product are not subject to restrictions. Annex XVII
REACH Authorisation - Annex XIV : The components of this product are not subject to
authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was
obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its
correctness. The conditions or methods of handling,storage, use or disposal of the product
are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense
arising out of or in any way connected with the handling, storage, use or disposal of the
product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be
applicable.
| Product Name | RXSOL-60-6605-488 |
| Product Type | SODIUM CHLORITE FLAKES 80% |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
2.1. Substance : SODIUM CHLORITE 80%
CAS No : 7758-19-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
2.2. Mixture
Not applicable
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Acute toxicity (oral), H301
Category 3
Acute toxicity (dermal), H310
Category 1
Acute toxicity H330
(inhalation:dust,mist)
Category 1
Skin corrosion/irritation, H314
Category 1
Hazardous to the aquatic H400
environment — Acute
Hazard, Category 1
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Symbol(s) : O : Oxidizing
T : Very toxic
C: Corrosive
N : Dangerous for the environment
R Phrase(s) :R8 : Contact with combustible material may cause fire.
R20: Harmful by inhalation.
R24/25: Toxic in contact with skin and if swallowed.
R32: Contact with acids librates very toxic gas.
R36/37/38: Irritating to eyes, respiratory system and skin.
S Phrase(s) : S17 : Keep away from combustible material.
S26 : In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise
S27: Take off immediately all contaminated clothing
S36 : Wear suitable protective clothing.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Extra labelling to displayExtra classification(s) to display
Hazard pictograms
Signal word : Danger
Hazard statements : H272 - May intensify fire; oxidiser
H301 - Toxic if swallowed
H310+H330 - Fatal in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
H400 - Very toxic to aquatic life
Precautionary statements : P220 - Keep/Store away from clothing/…/combustible
materials
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice. First-aid measures after skin contact : Take off contaminated clothing.
Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation
persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth.
Do not induce vomiting. If you feel unwell, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after inhalation : Fatal if inhaled.
Symptoms/injuries after skin contact : Fatal in contact with skin.
Symptoms/injuries after ingestion : Toxic if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May intensify fire; oxidiser.
Explosion hazard : Explosive when mixed with combustible material. Heating may cause
an explosion. Hazardous decomposition products in
case of fire : Thermal decomposition generates : Toxic fumes may be released.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Very toxic to aquatic life.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Large spills: scoop solid spill into closing containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin, eyes and clothing.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ...
thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in original container. Store in a
dry place. Incompatible products : Oxidizing agent. Strong bases. Strong acids.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : 10 - 11
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Appreciable (> 10%) Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : ≥ 0.07 vol %
9.2. Other information
No additional information available
10.1. Reactivity
May cause or intensify fire; oxidizer.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
Highly reactive material. Contact with acids liberates very toxic gas.
10.4. Conditions to avoid
Direct sunlight. Heat. Water, humidity.
10.5. Incompatible materials
No additional information available
10.6. Hazardous decomposition products
No additional information available
11.1. Information on toxicological effects
Acute toxicity : Oral: Toxic if swallowed. Dermal: Fatal in contact with skin.
Inhalation:dust/mist: Fatal if inhaled.
Skin corrosion/irritation : Causes severe skin burns and eye damage.
pH: 10 - 11
Serious eye damage/irritation : Serious eye damage, category 1, implicit
pH: 10 - 11
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated exposure) : Not classified
Aspiration hazard : Not classified
Potential adverse human health effects and symptoms
: Harmful if swallowed. Toxic in contact with skin.
12.1. Toxicity
No additional information available
12.2. Persistence and degradability
No additional information available
12.3. Bioaccumulative potential
No additional information available
12.4. Mobility in soil
No additional information available
12.5. Results of PBT and vPvB assessment
No additional information available
12.6. Other adverse effects
No additional information available
13.1. Waste treatment methods
Product/Packaging disposal
Recommendations : Dispose of contents/container to ...
Ecology - waste materials : Hazardous waste due to toxicity.
In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : 1496
UN-No. (IMDG) : 1496
UN-No.(IATA) : 1496
UN-No.(ADN) : 1496
14.2. UN proper shipping name
Proper Shipping Name (ADR) : SODIUM CHLORITE
Proper Shipping Name (IMDG) : SODIUM CHLORITE
Proper Shipping Name (IATA) : SODIUM CHLORITE
Proper Shipping Name (ADN) : SODIUM CHLORITE
Proper Shipping Name (RID) : SODIUM CHLORITE
Transport document description (ADR) : UN 1496 SODIUM CHLORITE, 5.1, II, (E)
, ENVIRONMENTALLY HAZARDOUS Transport document description (IMDG) : UN 1496 SODIUM CHLORITE, 5.1, II, MARINE POLLUTANT/ENVIRONMENTALLY
HAZARDOUS
Transport document description (IATA) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (ADN) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
Transport document description (RID) : UN 1496 SODIUM CHLORITE, 5.1, II,
ENVIRONMENTALLY HAZARDOUS
14.3. Transport hazard class(es)
ADR : Transport hazard class(es) (ADR) : 5.1
Danger labels (ADR) : 5.1
IMDG :Transport hazard class(es) (IMDG) : 5.1
Danger labels (IMDG) : 5.1
IATA : Transport hazard class(es) (IATA) : 5.1
Hazard labels (IATA) : 5.1
ADN : Transport hazard class(es) (ADN) : 5.1
Danger labels (ADN) : 5.1
RID : Transport hazard class(es) (RID) : 5.1
Danger labels (RID) : 5.1
14.4. Packing group
Packing group (ADR) : II
Packing group (IMDG) : II
Packing group (IATA) : II
Packing group (ADN) : II
Packing group (RID) : II
14.5. Environmental hazards
Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No
supplementary information available
14.6. Special precautions for user
- Overland transport
Classification code (ADR) : O2
Limited quantities (ADR) : 1kg
Excepted quantities (ADR) : E2
Packing instructions (ADR) : P002, IBC08
Special packing provisions (ADR) : B4
Mixed packing provisions (ADR) : MP2
Portable tank and bulk container
instructions (ADR) : T3
Portable tank and bulk container special
provisions (ADR) : TP33
Tank code (ADR) : SGAN
Tank special provisions (ADR) : TU3
Vehicle for tank carriage : AT
Transport category (ADR) : 2
Special provisions for carriage - Packages
(ADR) : V11
Special provisions for carriage - Loading,
unloading and handling (ADR) : CV24
Hazard identification number (Kemler No.) : 50
Orange plates : Tunnel restriction code (ADR) : E
EAC code : 1Y
- Transport by sea
Limited quantities (IMDG) : 1 kg
Excepted quantities (IMDG) : E2
Packing instructions (IMDG) : P002
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B2, B4
Tank instructions (IMDG) : T3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-H EmS-No. (Spillage) : S-Q
Stowage category (IMDG) : A
Segregation (IMDG) : SG38, SG49
MFAG-No : 143
- Air transport
PCA Excepted quantities (IATA) : E2
PCA Limited quantities (IATA) : Y544
PCA limited quantity max net quantity
(IATA) :
2.5kg
PCA packing instructions (IATA) : 558
PCA max net quantity (IATA) : 5kg
CAO packing instructions (IATA) : 562
CAO max net quantity (IATA) : 25kg
ERG code (IATA) : 5L
- Inland waterway transport
Classification code (ADN) : O2
Limited quantities (ADN) : 1 kg
Excepted quantities (ADN) : E2
Equipment required (ADN) : PP
Number of blue cones/lights (ADN) : 0
- Rail transport
Classification code (RID) : O2
Limited quantities (RID) : 1kg
Excepted quantities (RID) : E2
Packing instructions (RID) : P002, IBC08
Special packing provisions (RID) : B4
Mixed packing provisions (RID) : MP2
Portable tank and bulk container
instructions (RID) : T3
Portable tank and bulk container special
provisions (RID) : TP33
Tank codes for RID tanks (RID) : SGAN
Special provisions for RID tanks (RID) : TU3
Transport category (RID) : 2
Special provisions for carriage – Packages
(RID) : W11
Special provisions for carriage – Loading
and unloading (RID) : CW24
Colis express (express parcels) (RID) : CE10
Hazard identification number (RID) : 50
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable
15.1. Safety, health and environmental regulations/legislation specific for
the substance or mixture
15.1.1. EU-Regulations
No REACH Annex XVII restrictions
Sodium chlorite is not on the REACH Candidate List
Sodium chlorite is not on the REACH Annex XIV List
15.1.2. National regulations
Germany
AwSV/VwVwS Annex reference : Water hazard class (WGK) 2, hazardous to water
(Classification according to VwVwS, Annex 2; WGK No 487)
12th Ordinance Implementing the Federal
Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous
Incident Ordinance)
Denmark
Recommendations Danish Regulation : Young people below the age of 18 years are not
allowed to use the product Pregnant/breastfeeding women working with the product must
not be in direct contact with the product
15.2. Chemical safety assessment
No additional information available
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was
obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its
correctness. The conditions or methods of handling,storage, use or disposal of the product
are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense
arising out of or in any way connected with the handling, storage, use or disposal of the
product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be
applicable.
8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or safety glasses Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection
8.1. Control parameters No additional information available 8.2. Exposure controls Hand protection : protective gloves Eye protection : Chemical goggles or safety glasses Skin and body protection : Wear suitable protective clothing Respiratory protection : Wear respiratory protection
| Product Name | RXSOL-60-6605-488 |
| Product Type | SODIUM CHLORITE FLAKES 80% |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
2.1. Substance : SODIUM CHLORITE 80%
CAS No : 7758-19-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
2.2. Mixture
Not applicable
3.1. Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Oxidising Solids, H272
Category 2
Acute toxicity (oral), H301
Category 3
Acute toxicity (dermal), H310
Category 1
Acute toxicity H330
(inhalation:dust,mist)
Category 1
Skin corrosion/irritation, H314
Category 1
Hazardous to the aquatic H400
environment — Acute
Hazard, Category 1
Full text of classification categories and H statements : see section 16
Classification according to Directive 67/548/EEC or 1999/45/EC
Symbol(s) : O : Oxidizing
T : Very toxic
C: Corrosive
N : Dangerous for the environment
R Phrase(s) :R8 : Contact with combustible material may cause fire.
R20: Harmful by inhalation.
R24/25: Toxic in contact with skin and if swallowed.
R32: Contact with acids librates very toxic gas.
R36/37/38: Irritating to eyes, respiratory system and skin.
S Phrase(s) : S17 : Keep away from combustible material.
S26 : In the case of contact with eyes, rinse immediately with plenty of water and seek
medical advise
S27: Take off immediately all contaminated clothing
S36 : Wear suitable protective clothing.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).
3.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Extra labelling to displayExtra classification(s) to display
Hazard pictograms
Signal word : Danger
Hazard statements : H272 - May intensify fire; oxidiser
H301 - Toxic if swallowed
H310+H330 - Fatal in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
H400 - Very toxic to aquatic life
Precautionary statements : P220 - Keep/Store away from clothing/…/combustible
materials
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P284 - [In case of inadequate ventilation] wear respiratory protection
P301+P310 - IF SWALLOWED: immediately call a POISON CENTER or
doctor/physician
3.3. Other hazards
No additional information available
4.1. Description of first aid measures
First-aid measures after inhalation : Remove person to fresh air and keep comfortable for
breathing. Give oxygen or artificial respiration if necessary. If you feel unwell, seek
medical advice. First-aid measures after skin contact : Take off contaminated clothing.
Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do.
Continue rinsing. Rinse cautiously with water for several minutes. If eye irritation
persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth.
Do not induce vomiting. If you feel unwell, seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries : Causes severe skin burns and eye damage.
Symptoms/injuries after inhalation : Fatal if inhaled.
Symptoms/injuries after skin contact : Fatal in contact with skin.
Symptoms/injuries after ingestion : Toxic if swallowed.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.
5.1. Extinguishing media
Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon
dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Special hazards arising from the substance or mixture
Fire hazard : May intensify fire; oxidiser.
Explosion hazard : Explosive when mixed with combustible material. Heating may cause
an explosion. Hazardous decomposition products in
case of fire : Thermal decomposition generates : Toxic fumes may be released.
5.3. Advice for firefighters
Protection during firefighting : Do not attempt to take action without suitable protective
equipment.
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Emergency procedures : Evacuate unnecessary personnel.
6.1.2. For emergency responders
Protective equipment : Use personal protective equipment as required.
Emergency procedures : Ventilate area.
6.2. Environmental precautions
Very toxic to aquatic life.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Large spills: scoop solid spill into closing containers.
6.4. Reference to other sections
No additional information available
7.1. Precautions for safe handling
Precautions for safe handling : Avoid contact with skin, eyes and clothing.
Hygiene measures : Do not eat, drink or smoke when using this product. Wash ...
thoroughly after handling.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep container tightly closed. Store in original container. Store in a
dry place. Incompatible products : Oxidizing agent. Strong bases. Strong acids.
7.3. Specific end use(s)
No additional information available
8.1. Control parameters
No additional information available
8.2. Exposure controls
Hand protection : protective gloves
Eye protection : Chemical goggles or safety glasses
Skin and body protection : Wear suitable protective clothing
Respiratory protection : Wear respiratory protection
9.1. Information on basic physical and chemical properties
Odour threshold : No data available
pH : 10 - 11
Relative evaporation rate (butylacetate=1) : No data available
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : No data available
Relative vapour density at 20 °C : No data available
Relative density : No data available
Solubility : Water: Appreciable (> 10%) Log Pow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxi
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