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Product Name |
SULPHURIC ACID N/50 |
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Part Number |
RXSOL-60-6605-641 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.com |
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Chemical Name |
CAS |
EC number |
Weight |
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Sulfuric acid |
7664-93-9 |
231-639-5 |
>= 20 - < 30 % |
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Signal Word |
Danger |
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Hazard Statements |
H290 May be corrosive to metals.H314 Causes severe skin burns and eye damage. |
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P280 Wear protective gloves.P305 + P351 + P338 |
Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Precautionary statements |
P234 Keep only in original packaging. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
First aiders need to protect themselves. |
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If inhaled |
After inhalation: fresh air. Call in physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
May be combustible at high temperature. |
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Flash Point |
Higher than 93.3°C (200°F). |
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Suitable extinguishing media |
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Sulfur oxides Not combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: Sulfur oxides. |
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Further information |
Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert.Advice for emergency responders: For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills.Observe possible material restrictions (see sections 7 and 10).Take up with liquid-absorbent and neutralising material (e.g. Chemizorb® H⁺, Merck Art. No. 101595). Dispose of properly. Clean up affected area. |
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Reference to other sections |
For disposal see section 13. |
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Advice on safe handling |
Observe label precautions. |
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Advice on protection against fire and explosion |
Provide appropriate exhaust ventilation at places where dust is formed. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Change contaminated clothing and immerse in water. Preventive skin protection Wash hands and face after working with substance. For precautions see section 2.2. |
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Precautions for safe handling |
Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. |
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Conditions for safe storage, including any incompatibilities |
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Storage class (TRGS 510): Non-combustible, corrosive hazardous materials |
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Storage conditions |
No metal or light-weight-metal containers. Tightly closed. No metal containers. Recommended storage temperature see product label. |
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Storage class |
Storage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
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Occupational Exposure limit values |
No specific occupational exposure limit has been established. |
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Biological limit values |
No data available |
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Exposure controls |
No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Tightly fitting safety goggles |
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Body Protection |
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 120 min Material tested:Butoject® (KCL 898) |
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Respiratory protection |
Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. |
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Thermal hazards |
No data available |
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Physical state |
Liquid |
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Colour |
Colorless |
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Odour |
Odorless |
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Odor Threshold |
Not Applicable |
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pH |
20 °C |
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Melting Point |
No data available |
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Boiling Point |
103 °C at 1.013 hPa |
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Flash Point |
Not Applicable |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
338 °C |
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Vapour pressure |
No data available |
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Density |
1,18 g/cm3 at 20 °C |
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Vapour Density |
No Data Available |
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Freezing point |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
None |
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Solubility |
20 °C |
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Ignition temperature |
No information available. |
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Reactivity |
Strong oxidising agent |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
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Possibility of hazardous reactions |
A risk of explosion and/or of toxic gas formation exists with the following substances: Violent reactions possible with: Water Alkali metals alkali compounds AmmoniaAldehydes acetonitrile Alkaline earth metals alkalines Acids alkaline earth compounds Metals metal alloys Oxides of phosphorus phosphorus hydrides halogen-halogen compounds oxyhalogenic compounds permanganates nitrates Carbides combustible substances organic solvent acetylidene Nitriles organic nitro compounds anilines Peroxides picrates nitrides lithium silicide iron(III) compounds bromates chlorates Amines perchlorates hydrogen peroxide. |
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Conditions to avoid |
Strong heating (decomposition). |
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Incompatible materials |
Animal/vegetable tissues, MetalsContact with metals liberates hydrogen gas. |
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Hazardous Polymerization |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - male and female - 2.140 mg/kg Remarks: (ECHA) Inhalation: Corrosive to respiratory system. Dermal: No data available. |
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Skin corrosion/irritation |
Skin - Rabbit Result: Extremely corrosive and destructive to tissue. Remarks: (IUCLID) |
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Serious eye damage/eye irritation |
Causes serious eye damage. |
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Respiratory or skin sensitization |
No data available |
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Carcinogenicity |
No data available |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Germ cell mutagenicity |
Test Type: Ames test Test system: Salmonella typhimurium Result: negative Remarks: (HSDB) |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
No data available |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Additional Information |
RTECS: BD0725000 Fluoride ion can reduce serum calcium levels possibly causing fatal hypocalcemia. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated., Salivation, Nausea, Vomiting, Fever |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Irritation and corrosion, Cough, Shortness of breath, Nausea, Vomiting, Diarrhea, Pain, Risk of blindness! After inhalation of aerosols: damage to the affected mucous membranes. After skin contact: severe burns with formation of scabs. After eye contact: burns, corneal lesions. After swallowing: severe pain (risk of perforation!), nausea, vomiting and diarrhoea. After a latency period of several weeks possibly pyloric stenosis. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. |
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Persistence and degradability |
No data available |
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Toxicity |
No data available |
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Bioaccumulative potential |
No data available |
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Toxicity to fish |
LC50 - Danio rerio (zebra fish) - > 10 mg/l - 96 h (OECD Test Guideline 203) Remarks: No toxicity at the limit of solubility. |
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Toxicity to daphnia and other aquatic invertebrates |
LC50 - Daphnia magna (Water flea) - > 10 mg/l - 48 h (OECD Test Guideline 202) Remarks: No toxicity at the limit of solubility.static test EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h (OECD Test Guideline 202) |
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Toxicity to algae |
LC50 - Chlorella vulgaris (Fresh water algae) - 8,4 mg/l - 3 d static test ErC50 - Desmodesmus subspicatus (green algae) - > 100 mg/l - 72 h (OECD Test Guideline 201) |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
Forms corrosive mixtures with water even if diluted. Harmful effect due to pH shift.Endangers drinking-water supplies if allowed to enter soil or water. Discharge into the environment must be avoided. No data available |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID: 2796 IMDG: 2796 IATA: 2796 |
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UN proper shipping name |
ADR/RID : SULPHURIC ACID IMDG: SULPHURIC ACID IATA:SULPHURIC ACID |
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Transport hazard class(es) |
ADR/RID: 8 IMDG: 8 IATA: 8 |
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Packaging group |
ADR/RID: II IMDG: II IATA: II |
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Environmental hazards |
ADR/RID: No IMDG: No IATA: No |
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Special precautions for user |
Tunnel restriction code : (C/E) |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Transport in bulk according to IMOinstruments |
No data available |
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Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : OXIDISING LIQUIDS AND SOLIDS : ENVIRONMENTAL HAZARDS |
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Authorisations and/or restrictions on use |
Regulation (EU) 2019/1148 on the marketing and use of explosives precursors : sulphuric acid |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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