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Product Name |
Sodium Formaldehyde Sulfoxylate |
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Part Number |
RXSOL-60-6215-500 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.com |
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Chemical Name |
CAS |
EC numbe |
Weight |
Formula |
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Sodium Formaldehyde Sulphoxylate |
6035-47-8 |
205-739-4 |
<= 100 % |
CH3NaO3S · 2H2O |
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Signal Word |
Warning |
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Hazard Statements |
H341 Suspected of causing genetic defects. |
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Precautionary statements |
P281 Use personal protective equipment as required. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
EUH031 Contact with acids liberates toxic gas. |
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Other hazards |
None. |
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General advice |
Consult a physician. Show this safety data sheet to the doctor in attendance. |
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If inhaled |
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. |
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Eye Contact |
Flush eyes with water as a precaution. |
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Swallowed |
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
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Skin Contact |
Wash off with soap and plenty of water. Consult a physician. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
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Flash Point |
Dry powder Dry sand |
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Suitable extinguishing media |
Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Carbon oxides, Sulphur oxides, Sodium oxides |
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Further information |
No data available |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Wear self contained breathing apparatus for fire fighting if necessary. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Wear respiratory protection. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Enviromental Precaution |
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Pick up and arrange disposal without creating dust. Sweep up and shovel. Do not flush with water. Keep in suitable, closed containers for disposal. |
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Advice on safe handling |
Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. |
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Advice on protection against fire and explosion |
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. For precautions see section 2.2. |
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Precautions for safe handling |
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. |
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Storage conditions |
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Never allow product to get in contact with water during storage. Do not store near acids. |
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Storage class |
Storage class (TRGS 510): 13: Non Combustible Solids |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
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Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Control parameters |
Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). |
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Body Protection |
Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. |
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Skin protection |
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. |
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Respiratory protection |
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
Gloves Suit
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Physical state |
Solid |
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Colour |
No data available |
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Odour |
Odorless |
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Odor Threshold |
Not Applicable |
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pH |
64 - 68 °C - lit |
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Melting Point |
No data available |
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Boiling Point |
No data available |
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Flash Point |
No data available |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
No data available |
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Vapour pressure |
No data available |
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Density |
No data available |
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Relative Density |
No data available |
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Freezing point |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
No data available |
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Solubility |
No data available |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
No data available |
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Stability |
Stable under recommended storage conditions. |
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Possibility of hazardous reactions |
No data available |
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Conditions to avoid |
No data available |
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Incompatible materials |
Strong oxidizing agents, acids |
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Hazardous decomposition products |
Other decomposition products - no data available In the event of fire: see section 5 |
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Acute toxicity |
No data available |
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Skin corrosion/irritation |
No data available |
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Serious eye damage/eye irritation |
No data available |
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Respiratory or skin sensitization |
Sensitisation test: - Guinea pig Result: negative (OECD Test Guideline 406) Remarks: The value is given in analogy to the following substances: disodium molybdate |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. |
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Germ cell mutagenicity |
In vitro tests showed mutagenic effects |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
No data available |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Additional Information |
RTECS: PB0390000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
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Bioaccumulative potential |
Bioaccumulation Oncorhynchus tshawytscha(Disodium molybdate dihydrate) Remarks: No data available |
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Persistence and degradability |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Toxicity to fish |
Semi-static test LC50 - Pimephales promelas (fathead minnow) - 609,1 mg/l - 96 h (OECD Test Guideline 203) Remarks: (ECHA) NOEC - Pimephales promelas (fathead minnow) - 143,8 mg/l - 32 d Remarks: (ECHA) |
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Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia magna (Water flea) - 130,9 mg/l - 48 h (OECD Test Guideline 202) Remarks: (ECHA) |
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Toxicity to algae |
Static test NOEC - Isochrysis galbana (salt water algae) - >= 9,5 mg/l - 72 h (OECD Test Guideline 201) Remarks: (ECHA)static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 289,2 mg/l - 72 h (OECD Test Guideline 201) Remarks: (ECHA) |
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Toxicity to bacteria |
Static test EC50 - activated sludge - 820 mg/l - 3 h (OECD Test Guideline 209) Remarks: The value is given in analogy to the following substances: disodium molybdate |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
No data available |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. |
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UN number |
ADR/RID: IMDG: IATA: |
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UN proper shipping name |
ADR/RID:, IMDG: IATA: |
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Transport hazard class(es) |
ADR/RID: IMDG: IATA: |
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Packaging group |
ADR/RID: IMDG: IATA: |
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Environmental hazards |
ADR/RID: NO IMDG: NO IATA: NO |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
No data available. |
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Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
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National legislation |
No data available. |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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