TETRA BUTYL AMMONIUM HYDROXIDE 0.1 NORMAL IN IPA

Substance / Preparation: Preparation.

Hazardous component(s): This product is hazardous.

Substance name                                        Contents                CAS No

TETRABUTYL AMMONIUM:                   > 5 < 10 %                      -----

HYDROXIDEMethanol:                            > 50 < 75 %                67-56-1

Propan-                                                    2-ol:> 25 < 50 %          67-63-0

3.1. Classification  of  the  substance  or  mixture

Classificatio n  EC 67/548 or  EC 1999/45

Classification :  T;  R23/24/25 Xi;  R36R39/23/24/25

Hazard  Class  and  Category Code(s), Regulation  (EC)  No 1272/2008 

(CLP) Health  hazards :  Specific  Target  Organ Toxicity Danger  (CLP  : STOT SE  1)  H37

Acute  toxicity,  Inhalation0 Category  3-- Single  exposureCategory 

1 Danger  (CLP  :  Acute  Tox. 3)  H331

Eye  irritationCategory  2A Acute  toxicity, dermal-- Warning  (CLP  :  Eye  Irrit. 2)  H319

Category  3 Acute  toxicity,  OralCategory  3-- Danger  (CLP  :  Acute  Tox. 3)  H311 Danger

3.2. Label  elements

Labelling  EC 67/548 or  EC 1999/45

Symbol(s) :  T :  Toxic R Phrase(s) (CLP  :  Acute  Tox. 3) 

H301:  R23/24/25 :  Toxic  by  inhalation, in  contact  with skin and if  swallowed.

R36 :  Irritating  to eyes. R39/23/24/25 :  Toxic  :  danger  of  very serious  irreversible 

effects  through inhalation, in contact  with skin and if  swallowed.

S  Phrase(s) :  S4 :  Keep away  from  living  quarters.

S24 :  Avoid contact  with skin.

S26 :  In case  of  contact  with eyes, rinse  immediately  with plenty  of  water  and seekmedical advice.

S28 : After contact with skin, wash immediately with

S35 : This material and its container must be disposed of in a safe way.

S36/37 : Wear suitable protective clothing and gloves.

S38 : In case of insufficient ventilation, wear suitable respiratory equipment.

S45 : In case of accident or if you feel unwell,

seek medical advice immediately (show the label when possible).

S59 : Refer to manufacturer/supplier for information on recovery/recycling.

Contains: Methanol-Propan-2-ol-TETRABUTYLAMMONIUM HYDROXIDE AR

Labelling Regulation EC 1272/2008 (CLP)

Hazard pictograms

Signal words: Danger

Hazard statements: H301 : Toxic if swallowed.

H311 : Toxic in contact with skin.

H331 : Toxic if inhaled.

H319 : Causes serious eye irritation.

H370: Causes damage to organ.Precautionary statements

• Prevention: P280: Wear protective gloves, protective clothing, eye protection, faceprotection.

P271: Use only outdoors or in a well-ventilated area.

P260: Do not breathe dust, fume, gas, mist, vapours, spray.

P264: Wash thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

• Response: P301+P310: IF SWALLOWED : Immediately call a POISON CENTER ordoctor.

P307+P311: IF EXPOSED : Call a POISON CENTER or doctor.

P302+P352: IF ON SKIN : Wash with plenty of soap and water.

P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

P304+P340: IF INHALED : Remove to fresh air and keep at rest in a positioncomfortable for breathing.

P363: Wash contaminated clothing before reuse.

P337+P313: If eye irritation persists: Get medical advice/attention.

P361: Remove immediately all contaminated clothing.

• Storage: P403+P233: Store in well-ventilatedplace. Keep container tightly closed.

P405: Store locked up.

• Disposal considerations: P501: Dispose of this material and its container to hazardousor

special wastecollection point, in accordance with local, regional, national and/orinternationalregulation.

P501: Dispose of this material and its container to hazardous or special wastecollection point, in accordance

with local, regional, national and/or internationalregulation.

3.3. Other hazards

Other hazards: The substance does not fulfil the criteria to be identified as PBT

substance or vPvBsubstance according to Annex XIII of Regulation REACH.

4.1. Description of first aid measures

Inhalation: Specific treatment (see on this label). Immediately call a POISON CENTERordoctor.

Remove to fresh air and keep at rest in a position comfortable for breathing.

Skin contact: Remove affected clothing and wash all exposed skin area with mild soapandwater,

followed by warm water rinse. Wash contaminated clothing before reuse.

Remove/Take off immediately all contaminated clothing. Wash with plenty of soapand water.

Immediately call a POISON CENTER or doctor. Specific treatment (seeonthis label).

Eye contact: Rinse cautiously with water for several minutes.

Remove contactlenses, ifpresentand easy to do. Continue rinsing. Get medical advice

. If eye irritation persists :Ingestion: Immediately call a POISON CENTER or doctor.

Specific treatment (see onthislabel). Do NOT induce vomiting. Rinse mouth.

4.2. Most importantsymptoms and effects, both acute and delayed

Symptoms relating to use: Repeated exposure to this material can result in absorptionthrough

skin causingsignificant health hazard.Causes damage to organ.Danger ofserious damage to health

by prolonged exposure through inhalation.Causes serious eyeirritation.Swallowing a small quantity of

this material will result in serious health hazard.

4.3. Indication of any immediate medical attention and special treatment needed

General information: Never give anything by mouth to an unconscious person.

If youfeel unwell, seekmedical advice (show the label where possible)

. Call a POISONCENTER or doctor.Specific treatment (see on this label).

5.1. Extinguishing media

Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media: Do not use a heavy water stream.

Surrounding fires: Use water spray or fog for cooling exposed containers.

5.2. Special hazards arising from the substance ormixture

Hazardous combustion products: Under fire conditions, hazardous fumes will bepresent.

5.3. Advice for fire-fighters

Protection against fire: Do not enter fire area without proper protective equipment

,including respiratoryprotection.

Special procedures: Exercise caution when fighting any chemical fire.

Avoid (reject)fire-fighting water toenter environment.

6.1. Personal precautions, protective equipment and emergency procedures

For emergency responders: Equipcleanup crew with proper protection.

Ventilate area.Avoid breathing dust, fume, gas, mist, vapours, spray.

For non-emergency personnel: Evacuate unnecessary personnel.

6.2. Environmental precautions

Environmental precautions: Prevent entry to sewers and public waters.

Notifyauthorities if product enterssewers or public waters.

6.3. Methods and material for containment and cleaning up

Clean up methods: Soak up spills with inert solids, such as clay or diatomaceous

earthas soon aspossible. Collect spillage. Store away from other materials.

6.4. Reference to other sections

See section 8. Exposure controls/personal protection

9.1. Information on basic physical and chemical properties

Physical state at 20 °C: Liquid.

Odour threshold: No data available.

pH value: No data available.

Melting point [°C]: No data available.

Decomposition point [°C]: N/A

Critical temperature [°C]: No data available.

Auto-ignition temperature [°C]: No data available.

Flammability (solid, gas): Flammable.

Flash point [°C]: No data available.

Boiling point [°C]: N/A

Initial boiling point [°C]: No data available.

Final boiling point [°C]: No data available.

Evaporation rate: N/A

Vapour pressure [20°C]: No data available.

Vapour pressure mm/Hg: N/A

Vapour density: N/A

Density [g/cm3]: 1Relative density, gas (air=1): N/A

Relative density, liquid(water=1): N/A

Solubility in water [% weight]: N/A

Solubility in water: No data available.

Log Pow octanol / water at 20°C: No data available.

Solubility: 11,5Viscosity at 40°C [mm2/s]: No data available.

9.2. Other information

Explosive properties: N/A

Explosion limits-upper [%]: No data available.

Explosion limits-lower [%]: No data available.

Oxidising properties: No data available.

11.1. Information on toxicological effectsToxicity

information: The product has been not fully tested.

The calculated risk hasbeen done under therequirements of the EU regulations.Acute toxicity

• Inhalation: Toxic if inhaled.• Dermal: Toxic in contact with skin.

• Ingestion: Toxic if swallowed.Corrosion: Based on available data, the classification criteria are not met.

Irritation: Causes serious eye irritation.

Sensitization: Based on available data, the classification criteria are not met.

Mutagenicity: Based on available data, the classification criteria are not met.

Carcinogenicity: Based on available data, the classification criteria are not met.

Toxic for reproduction: Based on available data, the classification criteria are not met.

STOT-single exposure: Causes damage to organ.

STOT-repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard: Based on available data, the classification criteria are not met.

12.1. Toxicity

Toxicity information: The product hasbeen not fully tested.

The calculated risk hasbeen done under therequirements of the EU regulations.

12.2. Persistence-degradability

Persistence-degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: Not established.

12.4. Mobility in soil

Mobility in soil: Not established.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment: The substance does not fulfil the

criteria to beidentified as PBT substance or vPvBsubstance according to

Annex XIII of RegulationREACH.

12.6. Other adverse effects

Environmental precautions: Avoid release to the environment.

13.1. Waste treatment methods

General: Avoid release to the environment.

Dispose in a safe manner in accordancewithlocal/national regulations.

Dispose of this material and its container to hazardous orspecial waste

collectionpoint, in accordance with local, regional, national and/orinternational

regulation.Special precautions: Hazardous waste due to toxicity.

15.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixture

Safety, health and environmental: Ensure all national/local regulations are observed.

regulations/legislationspecific for thesubstance or mixture

REACH Restrictions-Annex XVII: The components of this product are not subject torestrictions

.REACH Authorisation-Annex XIV: The components of this product are not subjectto authorization.

15.2. Chemical Safety Assessment

Chemical Safety Assessment: It has not been carried out.

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL

of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH

Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.