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Product Name |
RXSOL-60-6605-683 |
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Product Type |
TETRACHLOROETHYLENE AR |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation : Tetrachloroethylene
CAS No :127-18-4
Substance.
Contains no other components or impurities which will influence the classification of the
product
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : Carc. Cat. 3; R40
N; R51-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351
Acute toxicity, Inhalation - Category 4 - Warning (CLP : Acute Tox. 4) H332
Environmental hazards : Hazardous to the aquatic environment - Chronic hazard
- Category 2 (CLP : Aquatic Chronic 2) H411
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : Xn : Harmful
N : Dangerous for the environment
R Phrase(s) : R40 : Limited evidence of a carcinogenic effect.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S Phrase(s) : S2 : Keep out of the reach of children.
S23 : Do not breathe the gas, fumes, vapours, spray.
S36/37 : Wear suitable protective clothing and gloves.
S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Warning
Hazard statements : H351 : Suspected of causing cancer.
H332 : Harmful if inhaled.
H411 : Toxic to aquatic life with long lasting effects.
Precautionary statements
• General : P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
P201: Obtain special instructions before use.
• Prevention : P281: Use personal protective equipment as required.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P273: Avoid release to the environment.
• Response : P308+P313: If exposed or concerned : get medical advice.
P391: Collect spillage.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
• Storage : P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT substance
or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Call a POISON CENTER or doctor if you feel unwell. Remove to fresh air
and keep at rest in a position comfortable for breathing.
Skin contact : Specific treatment (see on this label). Get medical advice. If skin irritation
occurs : Wash with plenty of soap and water. Wash contaminated clothing before reuse.
Eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse
cautiously with water for several minutes. If eye irritation persists : Get medical advice.
Ingestion : Obtain emergency medical attention. Do NOT induce vomiting. Rinse mouth.
Call a POISON CENTER or doctor if you feel unwell.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Swallowing a small quantity of this material will result in
serious health hazard. Causes serious eye irritation. Causes skin irritation. May cause
respiratory irritation. 4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
Seesection 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash hands and other exposed areas with mild soap and water before eat,
drink or smoke and when leaving work. Use only outdoors or in a well-ventilated area.
Avoid breathing dust, fume, gas, mist, vapours, spray. Obtain special instructions before
use.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container closed when not in use.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
Specific end use(s) : None
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour : Ethereal odor
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -22 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flash point [°C] : N/A
Boiling point [°C] : 121 °C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : 0,33
Vapour pressure [20°C] : 17.3 hPa at 20°C
Vapour pressure mm/Hg : N/A
Vapour density : 5,7
Density [g/cm3] : 1,623
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : 0.015 g in 100 g of
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Harmful if inhaled.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Suspected of causing cancer.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
14.1. Land transport (ADR-RID)
Proper shipping name : TETRACHLOROETHYLENE
UN N° : 1897
H.I. nr : 60
ADR - Class : 6.1
Labelling - Transport : 6.1 : Toxic substances.
ADR - Classification code : T1
ADR - Group : III
ADR - Packing instructions : P001 R001 LP001
ADR - Limited Quantity : 5 L
ADR - Tunnel code : E : Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : TETRACHLOROETHYLENE
UN N° : 1897
IMO-IMDG - Class or division : 6.1 : Toxic substances.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P001 LP01
IMO-IMDG - Limited quantities : 5 L
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-A S-A
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : TETRACHLOROETHYLENE
UN N° : 1897
IATA - Class or division : 6.1 : Toxic substances.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 655
instruction
- Passenger and Cargo - Maximum : 60 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 663
- Cargo only - Maximum Quantity/ : 220
L Packing IATA - Limited Quantites : 2 L
ERG-Nr : 6L
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH
Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.