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Product Name |
RXSOL-60-6605-691 |
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Product Type |
TETRALIN FOR SYNTHESIS 98% (1,2,3,4-tetrahydronaphthalene) |
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Revised date |
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Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
Substance / Preparation : 1,2,3,4-tetrahydronaphthalene
CAS No :119-64-2
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : R19
Xi; R36/38
N; R51-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Eye irritation - Category 2A - Warning (CLP : Eye Irrit. 2) H319
Skin irritation - Category 2 - Warning (CLP : Skin Corr. 2) H315
Environmental hazards : Hazardous to the aquatic environment - Chronic hazard -
Category 2 (CLP : Aquatic Chronic 2) H411
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : Xi : Irritant
N : Dangerous for the environment
R Phrase(s) : R19 : May form explosive peroxides.
R36/38 : Irritating to eyes and skin.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
S Phrase(s) : S2 : Keep out of the reach of children.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S28 : After contact with skin, wash immediately with
S61 : Avoid release to the environment. Refer to special instructions/Safety data
sheets.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Warning
Hazard statements : H319 : Causes serious eye irritation.
H315 : Causes skin irritation.
H411 : Toxic to aquatic life with long lasting effects.
Precautionary statements
• General : P102: Keep out of reach of children.
P103: Read label before use.
P101: If medical advice is needed, have product container or label at hand.
• Prevention : P280: Wear protective gloves, protective clothing, eye protection, face
protection.
P273: Avoid release to the environment.
P264: Wash thoroughly after handling.
• Response : P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P332+P313: If skin irritation occurs : Get medical advice.
P391: Collect spillage.
P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P363: Wash contaminated clothing before reuse.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest.
Skin contact : Wash contaminated clothing before reuse. Wash with plenty of soap and
water. If skin irritation occurs : Specific treatment (see on this label). Get medical advice.
Eye contact : If eye irritation persists : Get medical advice. Remove contact lenses, if
present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes.
Ingestion : Obtain emergency medical attention. Rinse mouth. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Causes serious eye irritation. Causes skin irritation.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Flammable class : May form explosive peroxides.
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present. May form flammable/ explosive vapour-air mixture.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment. DO NOT fight fire when fire reaches explosives.
Evacuate area.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
Technical measures : Use special care to avoid static electric charges.
Special precautions : No naked lights. No smoking. Reacts vigorously with strong
oxidizers and acids. Remove ignition sources.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash thoroughly after handling. Wash thoroughly after handling.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour. Proper grounding procedures to avoid static electricity should be
followed. Special precautions : No naked lights. No smoking.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container closed when not in use. Keep in fireproof place.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
Oxidizing agent. Heat sources.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Skin protection : Wear suitable protective clothing.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Liquid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : -35 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 3850C
Flammability (solid, gas) : N/A
Flash point [°C] : 710C
Boiling point [°C] : 207 °C
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : <1
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : 1 mm Hg @ 380C
Vapour density : 4,55
Density [g/cm3] : 0,97
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Insoluble in water
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
May form explosive peroxides.
Explosion limits - upper [%] : 5%
Explosion limits - lower [%] : 0,80%
Oxidising properties : No data available.
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures. Heat. Sparks.
Open flame. Direct sunlight. Overheating.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases. Oxidizing agent.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide.
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Based on available data, the classification criteria are not met.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Causes serious eye irritation. Causes skin irritation.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Hazardous waste due to potential risk of explosion.
Dispose of this material and its container to hazardous or special waste collection
point, in accordance with local, regional, national and/or international regulation.
14.1. Land transport (ADR-RID)
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
UN N° : 3082
H.I. nr : 90
ADR - Class : 9
Labelling - Transport : 9 : Miscellaneous dangerous substances and articles.
ADR - Classification code : M6
ADR - Group : III
ADR - Packing instructions : P001 R001 LP001
ADR - Limited Quantity : 5 L
ADR - Tunnel code : E : Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
UN N° : 3082
IMO-IMDG - Class or division : 9 : Miscellaneous dangerous substances and articles.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P001 LP01
IMO-IMDG - Limited quantities : 5 L
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-A S-F
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
UN N° : 3082
IATA - Class or division : 9 : Miscellaneous dangerous substances and articles.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 964
instruction
- Passenger and Cargo - Maximum : 450 L
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 964
- Cargo only - Maximum Quantity/ : 450 L
Packing IATA - Limited Quantites : 30 kg G
ERG-Nr : 9L
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the
substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out.
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.