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Product Name |
TETRAMETHYL AMMONIUM HYDROGEN SULPHATE MONOHYDRATE FOR SYNTHESIS 98%ESIS |
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Part Number |
RXSOL-60-6605-694 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.comA |
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Chemical Name |
CAS |
EC number |
Weight |
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Tetramethylammonium hydrogen sulfate monohydrate |
103812-00-6 |
-- |
<= 100 % |
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Signal Word |
Warning |
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Hazard Statements |
H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. |
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Precautionary statements |
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face protection. P302 + P352 IF ON SKIN: Wash with plenty of water. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None. |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
Consult a physician. Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. |
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Eye Contact |
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
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Swallowed |
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
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Skin Contact |
Wash off with soap and plenty of water. Consult a physician. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
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Flash Point |
Dry powder Dry sand |
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Suitable extinguishing media |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Carbon oxides Nitrogen oxides (NOx) Sulfur oxides |
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Further information |
No data available |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Wear self-contained breathing apparatus for firefighting if necessary. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. |
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Advice on protection against fire and explosion |
Provide appropriate exhaust ventilation at places where dust is formed. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. For precautions see section 2.2. |
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Precautions for safe handling |
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. |
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Storage conditions |
Keep container tightly closed in a dry and well-ventilated place. Store in cool place. hygroscopic |
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Storage class |
Storage class (TRGS 510): 11: Combustible Solids |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
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Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Control parameters |
Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). |
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Body Protection |
Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. |
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Skin protection |
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:Dermatril® (KCL 740 / Aldrich Z677272, Size M) data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374 If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. |
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Respiratory protection |
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. |
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Physical state |
Crystalline |
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Colour |
White |
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Odour |
No data available |
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Odor Threshold |
No data available |
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pH |
No data available |
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Melting Point |
290 °C |
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Boiling Point |
No data available |
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Flash Point |
No data available |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
No data available |
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Vapour pressure |
No data available |
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Density |
No data available |
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Relative Density |
No data available |
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Relative vapor density |
No data available |
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Freezing point |
No data available |
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Viscosity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
No data available |
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Solubility |
No data available |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
No data available |
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Stability |
Stable under recommended storage conditions. |
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Possibility of hazardous reactions |
No data available |
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Conditions to avoid |
No data available |
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Incompatible materials |
Strong oxidizing agents |
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
Oral: No data available Inhalation: No data available Dermal: No data available |
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Skin corrosion/irritation |
Remarks: No data available |
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Serious eye damage/eye irritation |
Eyes - Rabbit Result: Irreversible effects on the eye - 8 Days Remarks: (IUCLID) Remarks: Causes serious eye damage. |
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Respiratory or skin sensitization |
No data available |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
No data available |
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Germ cell mutagenicity |
Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test in vitro Test system: Chinese hamster lung cells Metabolic activation: without metabolic activation Method: OECD Test Guideline 473 Result: negative |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
Inhalation - May cause respiratory irritation. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Bioaccumulative potential |
No data available |
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Persistence and degradability |
No data available |
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Toxicity to fish |
Static test LC50 - Pimephales promelas (fathead minnow) - 77 mg/l - 96 h (OECD Test Guideline 203) |
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Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia - 108,82 mg/l - 48 h Remarks: (ECHA) |
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Toxicity to algae |
IC50 - Desmodesmus subspicatus (green algae) - 46,7 mg/l - 72 h Remarks: (IUCLID) (butyric acid) |
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Toxicity to bacteria |
EC50 - activated sludge - > 261 mg/l - 30 min Remarks: (ECHA) |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
No data available |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. |
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UN number |
ADR/RID: IMDG: IATA: |
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UN proper shipping name |
ADR/RID: IMDG: IATA: |
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Transport hazard class(es) |
ADR/RID: IMDG: IATA: |
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Packaging group |
ADR/RID: IMDG: IATA: |
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Environmental hazards |
ADR/RID: NO IMDG: NO IATA: NO |
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Further information |
No data available |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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