TRIBUTYLAMINE FOR SYNTHESIS99%

Substance / Preparation: TRIBUTYLAMINE 99%

CAS No :102-82-9

Substance.

Contains no other components or impurities which will influence the classification of theproduct.

3.1. Classifica tion  of  the  substance  or  mixture

Classification  EC 67/548 or  EC 1999/45

Classification :  T;  R23/24 Xn;  R22 Xi;  R38 0 002  (INDIA)

  Tel: Hazard  Class  and  Category Code(s), Regulation  (EC) 

No 1272/2008  (CLP) Health  hazards :  Acute  toxicity, dermal H311

Skin irritationCategory  2-- Category  3Danger 

(CLP  :  Ac Warning  (CLP  :  Skin Corr. 2)  H315 Acute  toxicity,

  InhalationCategory  3ute  Tox. 3) Danger  (CLP  :  Acute  Tox. 3)  H331

Acute  toxicity,  Oral

3.2. Label  elements

LabellingCategory 4Warning  (CLP  :  Acute  Tox. 4) 

H302 EC 67/548 or  EC 1999/45

Symbol(s) :  T :  Toxic R Phrase(s) :  R22 :  Harmful  if  swallowed.

R23/24 :  Toxic  by  inhalation and in contact  with skin. R38 :  Irritating  to

skin. S  Phrase(s) and seek :  S26 :  In case  of  contact  wit

h eyes, rinse  immediately  with plenty  of water

medical advice.S36/37 : Wear suitable protective clothing and gloves

.S45 : In case of accident or if you feel unwell,

seek medical advice immediately(show the label when possible)

.Labelling Regulation EC 1272/2008 (CLP)

Hazard pictograms

Signal words: DangerHazard statements: H311 : Toxic in contact with skin.

H331 : Toxic if inhaled.H302 : Harmful if swallowed.

H315 : Causes skin irritation.Precautionary statements

• Prevention: P280: Wear protective gloves, protective clothing, eye protection, faceprotection

.P271: Use only outdoors or in a well-ventilated area.

P261: Avoid breathing dust, fume, gas, mist, vapours, spray.

P264: Wash thoroughly after handling.

P270: Do not eat, drink or smoke when using this product.

• Response: P302+P352: IF ON SKIN : Wash with plenty of soap and water.

P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you feelunwell.

P332+P313: If skin irritation occurs : Get medical advice.

P304+P340: IF INHALED : Remove to fresh air and keep atrest in a positioncomfortable for breathing.

P363: Wash contaminated clothing before reuse.

P361: Remove immediately all contaminated clothing.

• Storage: P403+P233: Store in well-ventilated place. Keep container tightly closed.

P405: Store locked up.

•Disposal considerations: P501: Dispose of this material and its container to hazardousor

special wastecollection point, in accordance with local, regional, national and/orinternationalregulation

.P501: Dispose of this material and its container to hazardous or special

wastecollection point, in accordance with local, regional, national and/or internationalregulation

3.3. Other hazardsOther

hazards: The substance does not fulfil the criteria to be identified as PBT

substance or vPvBsubstance according to Annex XIII of Regulation REACH.

4.1. Description of first aid measures

Inhalation: Assure fresh air breathing. Allow the victim to rest.

Specific treatment (seeon thislabel). Remove to fresh air and keep at rest in a

position comfortable forbreathing.Immediatelycall a POISON CENTER or doctor.

Skin contact: Immediately call a POISON CENTER or doctor.

Specific treatment (seeon thislabel). Wash with plenty of soap and water.

Remove/Take off immediately allcontaminated clothing. If

skin irritation occurs : Get medical advice. Washcontaminatedclothing before reuse.

Eye contact: Rinse immediately with plenty of water.

Obtain medical attention if pain,blinking orredness persist.

Ingestion: Obtain emergency medical attention. Call a POISON CENTER or doctor ifyou feelunwell.

Do NOT induce vomiting. Rinse mouth.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms relating to use: Repeated exposure to this material can result in absorptionthrough

skin causingsignificant health hazard.Danger of serious damage to health byprolonged exposure

through inhalation.Causes skin irritation.Swallowing a smallquantity of this material will result in serious health hazard

.4.3. Indication of any immediate medical attention and special treatment needed

General information: Never give anything by mouth to an unconscious person

. If youfeel unwell, seekmedical advice (show the label where possible).

5.1. Extinguishing media

Suitable extinguishing media: Foam. Dry powder. Carbon dioxide. Water spray. Sand.

Unsuitable extinguishing media: Do not use a heavy water stream.

Surrounding fires: Use water spray or fog for cooling exposed containers.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products: Under fire conditions, hazardous fumes will bepresent.

5.3. Advice for fire-fighters

Protection against fire: Do not enter fire area without proper protective

equipment,including respiratoryprotection.Special procedures: Exercise caution

when fighting any chemical fire. Avoid (reject)fire-fighting water toenter environment.

6.1. Personal precautions, protective equipment and emergency procedures

For emergency responders: Equip cleanup crew with proper protection.Ventilate area.

For non-emergency personnel: Evacuate unnecessary personnel.

6.2. Environmental precautions

Environmental precautions: Prevent entry to sewers and public waters.

Notifyauthorities if product enterssewers or public waters.

6.3. Methods and material for containment and cleaning up

Clean up methods: Soak up spills with inert solids, such as clay or diatomaceous

earthas soon aspossible. Store away from other materials. Collect spillage.

6.4. Reference to other sections

See section8. Exposure controls/personal protection

9.1. Information on basic physical and chemical properties

Physical state at 20 °C: Liquid.

Odour threshold: No data available.

pH value: No data available.

Melting point [°C]:-70°C

Decomposition point [°C]: N/A

Critical temperature [°C]:N/A

Auto-ignition temperature [°C]: 210°C

Flammability (solid, gas): N/A

Flash point [°C]: 63°C

Boiling point [°C]: 216.5°C

Initial boiling point [°C]: N/A

Final boiling point [°C]: N/A

Evaporation rate: N/A

Vapour pressure [20°C]: 0.3 mm of Hg (@20°C

Vapour pressure mm/Hg: 0.3 mm of Hg (@ 20°C

Vapour density: 6,38Density [g/cm3]: 0,7782

Relative density, gas (air=1): N/A

Relative density, liquid (water=1): N/A

Solubility in water [% weight]: Sparingly soluble in

Solubility in water: N/A

Log Pow octanol / water at 20°C: No data available.

Solubility: Strong alkalis.

Viscosity at 40°C [mm2/s]: N/A

9.2. Other information

Explosive properties: N/A

Explosion limits-upper [%]: 6%

Explosion limits-lower [%]: 1,40%

Oxidising properties:No data available.

11.1. Information on toxicological effectsAcute toxicity

• Inhalation: Toxic if inhaled.• Dermal: Toxic in contact with skin

.• Ingestion: Harmful if swallowed

.Corrosion:Based on available data, the classification criteria are not met

.Irritation: Causes skin irritation.

Sensitization: Based on available data, the classification criteria are not met.

Mutagenicity: Based on available data, the classification criteria are not met.

Carcinogenicity: Based on available data, the classification criteria are not met.

Toxic for reproduction: Based on available data, the classification criteria are not met.

STOT-single exposure: Based on available data, the classification criteria are not met.

STOT-repeated exposure: Based on available data, the classification criteria are not met.

Aspiration hazard: Based on available data, the classification criteria are not met.

12.1. Toxicity

Toxicity information: Not established.

12.2. Persistence-degradability

Persistence-degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: Not established.

12.4. Mobility in soil

Mobility in soil: Not established.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB assessment: The substance does not fulfil the

criteria to beidentified as PBT substance or vPvBsubstance according to Annex XIII of RegulationREACH.

12.6. Other adverse effects

Environmental precautions:Avoid release to the environment.

13.1. Waste treatment methods

General: Avoid release to the environment.

Dispose in a safe manner in accordance withlocal/national regulations.

Dispose of this material and its container to hazardous orspecial waste collectionpoint,

in accordance with local, regional, national and/orinternational regulation.

Special precautions: Hazardous waste due to toxicity.

15.1. Safety, health and environmental regulations/legislation specific for thesubstance or mixture

Safety, health and environmental: Ensure all national/local regulations are observed.

regulations/legislation specific for thesubstance or mixture

REACH Restrictions-Annex XVII: The components of this product are notsubject torestrictions.

REACH Authorisation-Annex XIV: The components of this product are not subjectto authorization.

15.2. Chemical Safety Assessment

Chemical Safety Assessment: It has not been carried out.

Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vPvB: very persistent and very bioaccumulative

Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL

of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives

67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 Further information : None. In accordance with REACH

Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.