|
Product Name |
TRIETHYLENE GLYCOL FOR SYNTHESIS 98% |
|
Part Number |
RXSOL-60-6605-770 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
|
Phone |
+91 22 20871200 - 1400 |
|
Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
|
Email |
rxsolchemicals@gmail.com |
|
Website |
www.rxmraine.comA |
|
Chemical Name |
CAS |
EC number |
Weight |
Formula |
|
Triethylene glycol |
112-27-6 |
203-953-2 |
100 % |
C6H14O4 |
|
Signal Word |
None. |
|
Hazard Statements |
H225 Highly flammable liquid and vapor. H290 May be corrosive to metals. H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H370 Causes damage to organs (Eyes, Central nervous system). |
|
Precautionary statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
|
Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
|
Supplemental Hazard Statements |
None. |
|
Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
|
General advice |
None. |
|
If inhaled |
After inhalation: fresh air. |
|
Eye Contact |
After eye contact: rinse out with plenty of water. Remove contact lenses. |
|
Swallowed |
After swallowing: make victim drink water (two glasses at most). Consult doctor if feeling unwell. |
|
Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
|
Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
|
Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
|
Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
|
Indication of any immediate medical attention and special treatment needed |
No data available |
|
Flammability |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
|
Suitable extinguishing media |
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. |
|
Unsuitable extinguishing media |
Water Foam |
|
Special hazards arising from the substance or mixture |
Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. |
|
Further information |
Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
|
Advice for firefighters |
In the event of fire, wear self-contained breathing apparatus. |
|
Protective Equipment |
Use personal protective equipment. |
|
Specific Hazards Arising from the Chemical |
Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours. |
|
Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
|
Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
|
Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
|
Advice on protection against fire and explosion |
Provide appropriate exhaust ventilation at places where dust is formed. |
|
Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
|
Hygiene measures |
General industrial hygiene practice. For precautions see section 2.2. |
|
Precautions for safe handling |
For precautions see section 2.2. |
|
Storage conditions |
Tightly closed. Recommended storage temperature see product label. |
|
Storage class |
Storage class (TRGS 510): 10: Combustible liquids |
|
Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
|
Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
|
Requirements for storage |
Keep in cool and store under shade. |
|
Exposure controls |
Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
|
Control parameters |
Contains no components with established occupational exposure limits. |
|
Engineering Control |
A laboratory fumehood or other appropriate form of local exhaust ventilation should be used to avoid exposure. |
|
Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
|
Body Protection |
Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. |
|
Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
|
Respiratory protection |
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
|
Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
|
Control of environmental exposure |
Do not let product enter drains. |
|
Physical state |
Liquid |
|
Colour |
Colorless |
|
Odour |
Odorless |
|
Odor Threshold |
No data available |
|
pH |
6,5 - 7,5 at 100 g/l at 20 °C |
|
Melting Point |
-7 °C |
|
Boiling Point |
286,5 °C at 1.013 hPa |
|
Flash Point |
166 °C - closed cup |
|
Evaporation Rate |
Not Applicable |
|
Flammability (solid, gas) |
No data available |
|
Explosive limits |
No Data Available |
|
Upper/lower flammability or explosive limits |
9,2 %(V) / 0,9 %(V) |
|
Autoignition temperature |
347 °C |
|
Decomposition temperature |
> 200 °C |
|
Vapour pressure |
< 0,1 hPa at 24,7 °C |
|
Density |
1,13 g/cm3 at 15 °C |
|
Relative Density |
No data available |
|
Relative vapor density |
5,18 - (Air = 1.0) |
|
Freezing point |
No data available |
|
Viscosity dynamic |
47,8 mPa.s at 20 °C |
|
Partition coefficient |
log Pow: -1,98 at 25 °C - |
|
Explosive properties |
No data available |
|
Solubility |
1.000 g/l at 20 °C - |
|
Ignition temperature |
No information available. |
|
Particle characteristics |
No data available |
|
Reactivity |
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
|
Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
|
Possibility of hazardous reactions |
Exothermic reaction with: Bases Strong acids hydrogen peroxide Oxidizing agents Oxygen Violent reactions possible with:Isocyanates permanganates Peroxides halogen oxides persulfates |
|
Conditions to avoid |
Strong heating. |
|
Incompatible materials |
Zinc |
|
Hazardous decomposition products |
No data available |
|
Acute toxicity |
LD50 Oral - Rat - male and female - > 2.000 mg/kg (ATC METHODE) Inhalation: Respiratory disorder Symptoms: slight mucosal irritations, Cough Dermal: No data available |
|
Skin corrosion/irritation |
Skin - Rabbit Result: No skin irritation - 4 h (Draize Test) |
|
Serious eye damage/eye irritation |
Eyes - Rabbit Result: No eye irritation - 24 h (Draize Test) Eyes - Rabbit Result: Mild eye irritation |
|
Respiratory or skin sensitization |
No data available |
|
Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
|
Carcinogenicity |
No data available |
|
Germ cell mutagenicity |
Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Mutagenicity (mammal cell test): chromosome aberration. Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative |
|
Reproductive toxicity |
No data available |
|
Specific target organ toxicity - single exposure |
No data available |
|
Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
|
Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male - Oral - 13 Weeks - NOAEL (No observed adverse effect level) - 1.522 mg/kg prolonged or repeated exposure can cause:, Nausea, Headache, Vomiting To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Possible symptoms: After absorption: Headache Nausea Vomiting After absorption of large quantities: Damage to: Liver Kidney However, when the product is handled appropriately, hazardous effects are unlikely to occur. Handle in accordance with good industrial hygiene and safety practice. |
|
Bioaccumulative potential |
No bioaccumulation is to be expected (log Pow <= 4). |
|
Persistence and degradability |
Biodegradability aerobic - Exposure time 28 d Result: 25 - 92 % - Readily biodegradable. (OECD Test Guideline 301C) Theoretical oxygen demand 1.600 mg/g Remarks: (Lit.) Ratio BOD/ThBOD 1,4 - 32 % Remarks: (Lit.) |
|
Toxicity to fish |
Static test LC50 - Lepomis macrochirus (Bluegill sunfish) - > 10.000 mg/l - 96 h Remarks: (ECHA) |
|
Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia magna (Water flea) - > 10.000 mg/l - 48 h (DIN 38412) |
|
Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata - ca. 22.000 mg/l - 96 h (OECD Test Guideline 201) Remarks: Methanol |
|
Toxicity to bacteria |
Static test EC10 - activated sludge - > 1.995 mg/l - 30 min Remarks: (ECHA) |
|
Mobility in soil |
No Information available |
|
Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
|
Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
|
Other adverse effects |
No data available |
|
Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
|
Contaminated packaging |
Dispose of as unused product. |
|
Waste treatment Method |
No data available |
|
UN number |
ADR/RID: IMDG: IATA: |
|
UN proper shipping name |
ADR/RID: IMDG: IATA: |
|
Transport hazard class(es) |
ADR/RID: IMDG: IATA: |
|
Packaging group |
ADR/RID: IMDG: IATA: |
|
Environmental hazards |
ADR/RID: NO IMDG: NO IATA: NO |
|
Further information |
No data available |
|
Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
|
Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
|
Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
|
Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out |
|
Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
|
