Total Chlorine Indicator Solution
CL17 Total Chlorine Indicator Solution. Use with Total Chlorine Buffer Solution (2263511) and DPD Compound (2297255) for testing Total Chlorine using the CL17 Analyzer or bulk analytical methods.
- Part number
- RXSOL-60-6205-051
- Category
- Lab Chemical
- Brand
- RXSOL
Applications
Application Industry: Aquaculture, Chemical, Clinical/Medical Lab, Drinking Water, Fertigation, Food & Beverage, Oil & Gas, Petroleum, Storm Water, Waste Water, Hospitality, Agriculture
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Porduct Name | Total Chlorine Indicator Solution |
| Part Number | RXSOL-60-6205-051 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Chemical Name | Chlorine |
| Cas no. | 7782-50-5 |
| Product code | 001015 |
| Other means of identification | Molecular chlorine; CHLORINE GAS; active chlorine released from chlorine; Dichlorine; Dichlor; Diatomic chlorine; Chlorine molecule; Chlorine mol.; Chlor mol.; Chlorine, liquefied; Liquid chlorine |
| Prevention | Wear protective gloves. Wear protective clothing. Wear eye or face protection. In case of inadequate ventilation wear respiratory protection. Keep away from clothing and other combustible materials. Keep reduction valves, valves and fittings free from oil and grease. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Do not breathe gas. |
| Response |
Collect spillage. In case of fire: Stop leak if safe to do so. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.Collect spillage. In case of fire: Stop leak if safe to do so. IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Immediately call a POISON
CENTER or doctor. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON
SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF
IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
|
| Storage | Store locked up. Protect from sunlight. Store in a well-ventilated place |
| Disposal | None known. |
Potential acute health effects
| Eye contact | Causes serious eye damage. Contact with rapidly expanding gas may cause burns or frostbite. |
| Inhalation | Fatal if inhaled. |
| Skin contact | Causes severe burns. Contact with rapidly expanding gas may cause burns or frostbite. |
| Frostbite | Try to warm up the frozen tissues and seek medical attention. |
| Ingestion | As this product is a gas, refer to the inhalation section. |
Over-exposure signs/symptoms
| Eye contact | Adverse symptoms may include the following:, pain, watering, redness |
| Inhalation | No specific data |
| Skin contact | Adverse symptoms may include the following:, pain or irritation, redness, blistering may occu. |
| Ingestion | Adverse symptoms may include the following:, stomach pains |
Indication of immediate medical attention and special treatment needed, if necessary
| Notes to physician |
Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
|
| Specific treatments | No specific treatment. |
| Protection of first-aiders |
No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
|
| Suitable extinguishing media | Use an extinguishing agent suitable for the surrounding fire |
| Special hazards arising from the substance or mixture | None known |
| Specific hazards arising from the chemical |
Contains gas under pressure. Oxidizing material. This material increases the risk of fire and may aid combustion. Contact with combustible material may cause fire. In a fire or if heated, a pressure increase will occur and the container may burst or explode.
This material is very toxic to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or
drain.
|
| Hazardous thermal | Decomposition products may include the following materials |
| decomposition products | halogenated compounds |
| Special protective actions for fire-fighters |
Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk.
|
| Special protective equipment for fire-fighters | Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. |
| For non-emergency personnel | No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. |
| For emergency responders |
If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel".
|
| Environmental precautions |
Ensure emergency procedures to deal with accidental gas releases are in place to avoid
contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
|
| Small spill | Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. |
| Large spill | Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. |
| Precautions for safe handling | |
| Protective measures | Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Avoid release to the environment. Empty containers retain product residue and can be hazardous. Keep away from clothing, incompatible materials and combustible materials. Do not breathe gas. Keep reduction valves free from grease and oil |
| Advice on general occupational hygiene | Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. |
| Conditions for safe storage, including any incompatibilities |
Store in accordance with local regulations. Store in a segregated and approved area.
Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Cylinders should be stored upright, with valve
protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Store locked up. Separate
from reducing agents and combustible materials. Store away from grease and oil. Keep container tightly closed and sealed until ready for use. See Section 10 for incompatible materials before handling or use.
|
| Ingredient name | Exposure limits |
| PERSONAL PROTECTION | |
| chlorine |
ACGIH TLV (United States, 3/2019).
STEL: 2.9 mg/m³ 15 minutes.
STEL: 0.4 ppm 15 minutes.
TWA: 1.5 mg/m³ 8 hours.
TWA: 0.1 ppm 8 hours.
NIOSH REL (United States, 10/2016).
CEIL: 1.45 mg/m³ 15 minutes.
CEIL: 0.5 ppm 15 minutes.
OSHA PEL (United States, 5/2018).
CEIL: 3 mg/m³
CEIL: 1 ppm
OSHA PEL 1989 (United States, 3/1989).
STEL: 3 mg/m³ 15 minutes.
STEL: 1 ppm 15 minutes.
TWA: 1.5 mg/m³ 8 hours.
TWA: 0.5 ppm 8 hours.
California PEL for Chemical Contaminants (
Table AC-1) (United States).
PEL: 0.5 ppm 8 hours.
STEL: 1 ppm 15 minutes.
|
| Appropriate engineering controls | Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. |
| Environmental exposure controls | Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. |
| Hygiene measures | Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. |
| Eye/face protection | Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. |
| Hand protection | Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated |
| Body protection |
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product
|
| Other skin protection | Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. |
| Respiratory protection | Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. |
| Appearance | |
| Physical state | Gas. [GREENISH-YELLOW GAS WITH SUFFOCATING ODOR] |
| Colour | Colorless. Green. Yellow. |
| Odour | Pungent. |
| Odour Threshold | No data available |
| pH | No data available |
| Melting point | -101°C (-149.8°F) |
| Boiling point | -34°C (-29.2°F) |
| Critical temperature | 143.85°C (290.9°F) |
| Flash point | [Product does not sustain combustion.] |
| Evaporation rate | No data available |
| Flammability (solid, gas) | Extremely flammable in the presence of the following materials or conditions: reducing materials, combustible materials, organic materials and alkalis. |
|
Upper/lower
flammability or
explosive limits |
Not available. |
| Vapour pressure | 85.3 (psig) |
| Vapour density | 2.5 (Air = 1) |
| Specific Volume (ft 3 /lb) | 5.4054 |
| Gas Density (lb/ft 3) | 0.185 |
| Relative density | Not applicable. |
| Solubility | Very slightly soluble in the following materials: cold water. |
| Solubility in water | 7.41 g/l |
| Partition coefficient: noctanol/water | Not available. |
| Auto-ignition temperature | Not available. |
| Decomposition temperature | Not available. |
| Viscosity | Not available. |
| Flow time (ISO 2431) | Not available. |
| Molecular weight | 70.9 g/mole |
| Reactivity | No specific test data related to reactivity available for this product or its ingredients |
| Chemical stability | The product is stable. |
| Possibility of hazardous reactions |
Hazardous reactions or instability may occur under certain conditions of storage or use. Conditions may include the following contact with combustible materials Reactions may include the following:
risk of causing fireHazardous reactions or instability may occur under certain conditions of storage or use.
Conditions may include the following:
contact with combustible materials
Reactions may include the following:
risk of causing fire
|
| Conditions to avoid | Heat, flames and sparks. |
| Incompatible materials | Oxidizing agents, Copper |
| Hazardous decomposition products | No specific data. |
| Incompatible materials | Highly reactive or incompatible with the following materials: combustible materials reducing materials grease oil |
| Hazardous decomposition products | Under normal conditions of storage and use, hazardous decomposition products should not be produced. |
| In the event of fire | see section 5 |
| Hazardous polymerization | Under normal conditions of storage and use, hazardous polymerization will not occur. |
Information on toxicological effects
| Product/ingredient name | Result | Species | Dose | Exposure |
| chlorine | LC50 Inhalation Gas . | Rat | 293 ppm | 1 hours |
| Product/ingredient name | Not available. |
| Sensitization | Not available. |
| Mutagenicity | Not available. |
| Carcinogenicity | Not available. |
| Reproductive toxicity | Not available. |
| Teratogenicity | Not available. |
| Specific target organ toxicity (single exposure) | Not available. |
| Specific target organ toxicity (repeated exposure | Not available. |
| Aspiration hazard | Not available. |
| Information on the likely routes of exposure | Not available. |
| Eye contact | Causes serious eye damage. Contact with rapidly expanding gas may cause burns or frostbite. |
| Inhalation | Fatal if inhaled. |
| Skin contact | Causes severe burns. Contact with rapidly expanding gas may cause burns or frostbite. |
| Ingestion | As this product is a gas, refer to the inhalation section. |
| Symptoms related to the physical, chemical and toxicological characteristics | |
| Eye contact | Adverse symptoms may include the following:, pain, watering, redness |
| Inhalation | No specific data. |
| Skin contact | Adverse symptoms may include the following:, pain or irritation, redness, blistering may occur |
| Ingestion | Adverse symptoms may include the following:, stomach pains |
| Delayed and immediate effects and also chronic effects from short and long term exposure | |
| Short term exposure Potential immediate effects | Not available. |
| Long term exposurePotential delayed effects | Not available. |
| Potential immediate effects | Not available. |
| Potential delayed effects | Not available. |
| General | No known significant effects or critical hazards. |
| Carcinogenicity | No known significant effects or critical hazards. |
| Mutagenicity | No known significant effects or critical hazards. |
| Teratogenicity | No known significant effects or critical hazards. |
| Developmental effects | No known significant effects or critical hazards. |
| Fertility effects | No known significant effects or critical hazards. |
Acute toxicity estimates
| Route | ATE value |
| Inhalation (gases) | 146.5 ppm |
| Chlorine |
Acute EC50 5.1 ppm Marine wate
Acute EC50 930000 µg/l Fresh water
Acute LC50 2.03 µg/l Fresh water
Acute LC50 30 µg/l Fresh water
Acute LC50 14 µg/l Fresh water
|
Algae - Macrocystis pyrifer
Aquatic plants - Lemna minor
Crustaceans - Asellus racovitzai
Daphnia - Daphnia pulex
Fish - Oncorhynchus mykiss |
4 days
4 days
2 days
48 hours
96 hours |
| Persistence and degradability | Not available. |
| Bioaccumulative potential | Not available. |
| Soil/water partition coefficient (Koc) | Not available. |
| Other adverse effects | No known significant effects or critical hazards. |
| Disposal methods |
The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate containery.
|
| DOT | TDG | Mexico | IMDG | IATA | |
| UN number | UN1017 | UN1017 | UN1017 | UN1017 | UN1017 |
| UN proper shipping name | CHLORINE | CHLORI | CHLORINE | CHLORINE | CHLORINE |
| Environmental hazards | Yes. | Yes. |
Yes. The
environmentally
hazardous
substance mark is not required.
|
Yes. |
Yes. The
environmentally
hazardous
substance mark is not required.
|
Additional information
| DOT Classification |
Toxic - Inhalation hazard Zone B
This product is not regulated as a marine pollutant when transported on inland waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in non-bulk sizes,
provided the packagings meet the general provisions of §§ 173.24 and 173.24a.
Reportable quantity 10 lbs / 4.54 kg. Package sizes shipped in quantities less than
the product reportable quantity are not subject to the RQ (reportable quantity)
transportation requirements.
Limited quantity Yes.
Quantity limitation Passenger aircraft/rail: Forbidden. Cargo aircraft: Forbidden.
Special provisions 2, B9, B14, T50, TP19
|
| TDG Classification |
Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.13-2.17 (Class 2), 2.23-2.25 (Class 5), 2.40-2.42 (Class 8), 2.7
(Marine pollutant mark).
The marine pollutant mark is not required when transported by road or rail.
Explosive Limit and Limited Quantity Index 0
ERAP Index 500
Passenger Carrying Vessel Index Forbidden
Passenger Carrying Road or Rail Index Forbidden
|
| IMDG | The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg. |
| IATA |
The environmentally hazardous substance mark may appear if required by other
transportation regulations. Quantity limitation Passenger and Cargo Aircraft: Forbidden. Cargo Aircraft Only: Forbidden.
|
| Special precautions for user |
Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage
|
| Transport in bulk according to IMO instruments | Not available. |
| SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed | |
| State regulationsy | |
| Massachusetts | This material is listed. |
| New York | This material is listed. |
| New Jersey | This material is listed.. |
| Pennsylvania | This material is listed. |
| International regulations | |
| Chemical Weapon Convention List Schedules I, II & III Chemicals | Not listed. |
| Chemical Weapon Convention List Schedules I, II & III Chemicals | Not listed. |
| Stockholm Convention on Persistent Organic Pollutants | Not listed. |
| Stockholm Convention on Persistent Organic Pollutants | Not listed. |
| Stockholm Convention on Persistent Organic Pollutants | Not listed. |
| Inventory list | This material is listed or exempted. |
| Australia | This material is listed or exempted. |
| Canada | This material is listed or exempted. |
| Europe | This material is listed or exempted. |
| Japan |
Japan inventory (ENCS): Not determined.
Japan inventory (ISHL): Not determined.
|
| New Zealand | This material is listed or exempted. |
| Philippines | This material is listed or exempted. |
| Republic of Korea | This material is listed or exempted. |
| Taiwan | This material is listed or exempted |
| Thailand | Not determined. |
| Turkey | This material is listed or exempted |
| United States | This material is active or exempted. |
| Viet Nam | This material is listed or exempted |
| No data available |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
| Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| 760 mm Hg @ 105°C |
| 760 mm Hg @ 105°C |
