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Porduct Name |
Trifluoroacetic anhydride |
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Part Number |
RXSOL-19-1347-026 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.com |
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Chemical Name |
Cas No |
EC No |
Whight |
Formula |
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Trifluoroacetic Anhydride for synthesis |
407-25-0 |
206-982-9 |
210,03 g/mol |
C4F6O3 |
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Signal Word |
Danger |
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Hazard Statements |
H314 Causes severe skin burns and eye damage.H412 Harmful to aquatic life with long lasting effects. |
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Precautionary statements |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
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Inhalation |
Fresh air. Call in physician. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
May be combustible at high temperature. |
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Suitable extinguishing media |
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
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Unsuitable extinguishing media |
Water Foam |
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Special hazards arising from the substance or mixture |
Carbon oxides Hydrogen fluoride Not combustible. Fire may cause evolution of: Hydrogen fluoride Caution! in contact with water product releases: Organic acids May not get in touch with: Water Ambient fire may liberate hazardous vapours. |
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Further information |
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8 |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
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Reference to other sections |
For disposal see section 13. |
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Advice on protection against fire and explosion |
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. Keep workplace dry. Do not allow product to come into contact with water. |
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Conditions for safe storage, including any incompatibilities |
Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Moisture sensitive. |
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Storage conditions |
Tightly closed Never allow product to get in contact with water during storage.Recommended storage temperature see product label. |
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Storage class |
Storage class (TRGS 510): 3: Flammable liquids |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Exposure controls |
No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
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Engineering Control |
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
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Body Protection |
protective clothing |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). |
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Respiratory protection |
Recommended Filter type: Filter B-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. |
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Physical state |
Liquid |
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Colour |
Colorless |
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Odour |
pungent |
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Odor Threshold |
Not Applicable |
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pH |
No data available |
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Melting Point |
-63,5 °C |
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Boiling Point |
97 °C - lit. |
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Flash Point |
6 °C - closed cup |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
No data available |
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Vapour pressure |
433 hPa at 20 °C |
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Viscosity |
No data available |
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Density |
1,49 g/cm3 at 25 °C |
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Relative Density |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
No data available |
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Solubility |
10.000 g/l - |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Reacts violently with water. |
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Chemical stability |
sensitive to moisture |
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Possibility of hazardous reactions |
No data available |
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Conditions to avoid |
Do not allow water to enter container. Moisture |
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Incompatible materials |
Strong oxidizing agents, Strong acids, Strong bases, Alcohols
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Hazardous decomposition products |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - 39 mg/kg LC50 Inhalation - 4 h - 11 mg/l LD50 Dermal - 51 mg/kg |
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Skin corrosion/irritation |
Skin - Rabbit Result: Mild skin irritation - 24 h |
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Serious eye damage/irritation |
Causes serious eye damage. |
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Respiratory or skin sensitization |
Local lymph node assay (LLNA) - Mouse Result: negative (OECD Test Guideline 429) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Ethyl trifluoroacetate |
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Carcinogenicity |
No data available |
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Germ cell mutagenicity |
Test Type: In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
No data available
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Additional Information |
RTECS: UF9625000 Lung irritation, Cyanosis, Central nervous system depression To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
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Persistence and degradability |
No data available |
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Toxicity to fish |
static test LC50 - Danio rerio (zebra fish) - > 999 mg/l - 96 h (OECD Test Guideline 203) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium trifluoroacetate |
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Toxicity to daphnia and other aquatic invertebrates |
static test EC50 - Daphnia magna (Water flea) - > 999 mg/l - 48 h (OECD Test Guideline 202) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium trifluoroacetate |
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Toxicity |
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h |
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Toxicity to bacteria |
NOEC - activated sludge - > 1.000 mg/l - 3 h (OECD Test Guideline 209) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium trifluoroacetate |
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Toxicity to algae |
static test NOEC - Phaeodactylum tricornutum - 97 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: Sodium trifluoroacetate |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No data available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
No data available |
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Other adverse effects |
No data available . |
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Product |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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Contaminated packaging |
Dispose of as unused product. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID:3265 IMDG:3265 IATA: 3265 |
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UN proper shipping name |
ADR/RID:ADR/RID: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (trifluoroacetic anhydride) IMDG:ADR/RID: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (trifluoroacetic anhydride) IATA:ADR/RID: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (trifluoroacetic anhydride) |
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Transport hazard class(es) |
ADR/RID: 8 IMDG: 8 IATA:8 |
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Packaging group |
ADR/RID: I IMDG: I IATA: I |
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Environmental hazards |
ADR/RID: No IMDG: No IATA: No |
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Special precautions for user |
No data available |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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