Vinylidene Chloride
Vinylidene Chloride
- Part number
- RXSOL-19-1482-025
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Vinylidene Chloride its chemical name is 1,1-dichloroethylene, a colourless, dense, toxic, volatile, flammable liquid belonging to the family of organic halogen compounds.
Technical specifications
| PRODUCT NAME | : | VINYLIDENECHLORIDE |
| CAS number | : | 75-35-4 |
| UN number | : | 1303 |
| Formula | : | CH2:CCI2 |
| Odour | : | Sweet smell |
| Solubility in water | : | INSOLUBLE |
| Density | : | 1.218 at 20oC |
| Boiling point | : | 37oC |
| Melting point | : | -122 oC |
| Viscosity | : | |
| Flashpoint | : | -10oC |
| Explosive limits | : | 6.5 – 15 Vol% |
| Vapour pressure | : | 665 mbar at 20 oC |
| Skin absorption/irritation | : | YES |
| TLV Country NL Year 1995 | : | 5 ppm 20 mg/m3 |
| Pollution category 1994 | : | D |
Applications
1, 1-Dichloroethene is an industrial chemical solvent having sweet smell. It is also called vinylidene chloride. 1, 1-Dichloroethene is used to make certain plastics, such as flexible films like food wrap, and in packaging materials.
Vinylidene Chloride is non soluble in water and soluble in organic solvent.
Vinylidene chloride is used as an intermediate in chemical synthesis and to produce polyvinylidene chloride copolymers.
Dosage and directions
Uses
Vinylidene chloride is used as an intermediate for organic chemical synthesis.
Vinylidene chloride is also used in the production of polyvinylidene chloride copolymers. The major application of these chloride copolymers is in the production of flexible films for food packaging.
These copolymers are also used extensively in many types of packing materials, as flame retardant coatings for fiber and carpet backing and in piping, coating for steel pipes, and adhesive applications.
Characteristics and notes
Vinylidene Chloride CAS No. 75-35-4
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | Vinylidene Chloride |
| Part Number | RXSOL-19-1482-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS | EC number | Weight | Formula |
| 1,1-Dichloroethylene | 75-35-4 | 200-864-0 | 96,94 g/mol | C2H2Cl2 |
| Signal Word | Danger |
| Hazard Statements | H224 Extremely flammable liquid and vapor. H302 + H332 Harmful if swallowed or if inhaled. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H372 Causes damage to organs (Nose) through prolonged or repeated exposure if inhaled. H373 May cause damage to organs (Liver) through prolonged or repeated exposure if swallowed. H412 Harmful to aquatic life with long lasting effects. |
| Precautionary statements | P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P273 Avoid release to the environment. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P308 + P313 IF exposed or concerned Get medical advice/ attention. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. |
| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Supplemental Hazard Statements | No data available |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. |
| Eye Contact | After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
| Swallowed | If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
| Inhalation | Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
| Ingestion | Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | May be combustible at high temperature. |
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Hydrogen chloride gas Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures. |
| Further information | Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. Risk of explosion. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
| Advice on safe handling | Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
| Advice on protection against fire and explosion | Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
| Incompatible materials | Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
| Hygiene measures | Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities | Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
| Storage conditions | Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons. |
| Storage class | Storage class (TRGS 510) 3 Flammable liquids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Requirements for storage | Keep in cool and store under shade. |
| Exposure controls | No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
| Body Protection | Flame retardant antistatic protective clothing. |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 pleasecontact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
| Respiratory protection | Required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type AX The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. Risk of explosion. |
| Physical state | Liquid |
| Colour | Colorless |
| Odour | No data available |
| Odor Threshold | Not Applicable |
| pH | No data available |
| Melting Point | 122 °C - lit. |
| Boiling Point | 30 - 32 °C - lit. |
| Flash Point | 19 °C |
| Evaporation Rate | No data available |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | 15,5 %(V) / 6,5 %(V) |
| Autoignition temperature | 520,0 °C 580,0 °C |
| Decomposition temperature | No data available |
| Viscosity,kinematic | No data available |
| Vapour pressure | 667,3 hPa at 20,0 °C 2.137,4 hPa at 55,0 °C |
| Density | 1,213 g/cm3 at 20 °C - lit. |
| Relative Vapour Density | No data available |
| Freezing point | No data available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | No data available |
| Solubility | 0,2 g/l at 20 °C |
| Ignition temperature | No data available |
| Particle characteristics | No data available |
| Reactivity | Vapors may form explosive mixture with air. |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) . |
| Possibility of hazardous reactions | No data available |
| Conditions to avoid | Warming. |
| Incompatible materials | Oxidizing agents, Copper, Aluminum, and its alloys, Peroxides, Strong bases, Oxygen |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity | Acute toxicity estimate Oral - 200 mg/kg (Calculation method) LD50 Oral - Rat - 1.500 mg/kg Acute toxicity estimate Oral - 1.500 mg/kg (Calculation method) Acute toxicity estimate Inhalation - 4 h - 11 mg/l - vapor(Calculation method) Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Skin corrosion/irritation | Skin - reconstructed human epidermis (RhE) Result: No skin irritation - 3 - 60 min (Regulation (EC) No. 440/2008, Annex, B.40) |
| Serious eye damage/eye irritation | Eyes - Bovine cornea Result: Causes serious eye irritation. - 10 min (OECD Test Guideline 437) |
| Respiratory or skin sensitization | Eyes - Bovine cornea Result: Causes serious eye irritation. - 10 min (OECD Test Guideline 437) |
| Carcinogenicity | Suspected of causing cancer. |
| Germ cell mutagenicity | Based on available data the classification criteria are not met. Test Type: comet assay Species Rat Cell type: Bone marrow Application Route: inhalation (vapor) Method OECD Test Guideline 489 Result: positive Test Type: Micronucleus test Species: Mouse Cell type: Bone marrow Application Route: Inhalation Method OECD Test Guideline 474 Result: negative Test Type Micronucleus test Species: Mouse Cell type: Bone marrow Application Route: Oral Method OECD Test Guideline 474 Result negative Test Type Mutagenicity (mammal cell test) chromosome aberration. Species Rat Cell type: Implant Application Route: Inhalation Method: OECD Test Guideline 478 Result: negative |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxic Effects on Humans | Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Additional Information | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - female - Oral - 90 Days - NOAEL (No observed adverse effect level) - 9 mg/kg - LOAEL (Lowest observed adverse effect level) - 14 mg/kg Remarks: (ECHA) RTECS: KV9275000 Nausea, Headache, Vomiting, Dizziness, Drowsiness, Confusion., Incoordination., Central nervous system depression To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After absorption: Headache somnolence Unconsciousness Coma After absorption of large quantities: Damage to Liver Kidney Lungs Central nervous system This substance should be handled with particular care. |
| Persistence and degradability | Biodegradability Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301D) . |
| Bioaccumulative potential | Bioaccumulation Cyprinus carpio (Carp) - 6 Weeks at 25 °C - 0,5 mg/l(1,1-Dichloroethene) Bioconcentration factor (BCF) 2,5 - 6,4 (OECD Test Guideline 305C) |
| Toxicity to fish | Flow-through test LC50 - Pimephales promelas (fathead minnow) - 108 mg/l - 96 h (ECHA) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - 37 mg/l - 48 h (OECD Test Guideline 202) (ECHA) |
| Toxicity to algae | Static test EC50 - Chlamydomonas reinhardtii (green algae) - 9,12 mg/l - 72 h Remarks: (ECHA) (ECHA) |
| Toxicity to bacteria | EC50 - Pseudomonas putida - > 2.000 mg/l - 17 h (IUCLID) |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Discharge into the environment must be avoided. |
| Disposal methods | The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
| Contaminated packaging | Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. |
| Waste treatment Method | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID:1303 IMDG:1303 IATA:1303 |
| UN proper shipping name |
ADR/RID: Vinylidene chloride, stabilized IMDG: Vinylidene chloride, stabilized IATA:Vinylidene chloride, stabilized |
| Transport hazard class(es) | ADR/RID: 3 IMDG: 3 IATA: 3 |
| Packaging group | ADR/RID: l IMDG: l IATA:l |
| Environmental hazards | ADR/RID: No IMDG: No IATA: No |
| Special precautions for user | Tunnel restriction code (C/E) |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Authorisations and/or restrictions on use | REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles (Annex XVII) 1,1-Dichloroethene |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
Availability
Vinylidene Chloride supplier in Mumbai, Manglore, Visakhapatnam, Chennai, Kolkata, Gandhidham, Fujairah, Dubai, Abu Dhabi, Sharjah, Muscat - OMAN.
