ZINC CHLORIDE DRY AR
- Part number
- RXSOL-60-6605-840
- Category
- Lab Chemical
- Brand
- RXSOL
Overview
Zinc Chloride is an ionic salt essential for the synthesis of cholesterol, protein, and fats. Zinc plays an important role in the proper functioning of the immune system.Zinc chloride is used in dry cells as an electrolyte. Other Uses - It is used as a condensing agent, disinfecting purposes, dehydrating agent, wood preservative, deodorant, and disinfectant.
Applications
Zinc sulfate and zinc chloride are used in a wide range of comparatively small-scale applications. The former is used in agriculture as a weed killer and to give protection against pests. It is also an important constituent of the precipitating bath in the manufacture of viscose rayon.
Dosage and directions
Zinc chloride is used in dry cells as an electrolyte. Other Uses - It is used as a condensing agent, disinfecting purposes, dehydrating agent, wood preservative, deodorant, and disinfectant. A mixture of zinc oxide and hexachloroethane can be used in smoke grenades.
Characteristics and notes
Dilute aqueous zinc chloride was used as a disinfectant under the name "Burnett's Disinfecting Fluid". From 1839 Sir William Burnett promoted its use as a disinfectant as well as a wood preservative.
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name | ZINC CHLORIDE DRY AR |
| Part Number | RXSOL-60-6605-840 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com | |
| Website | www.rxmarine.com |
| Chemical Name | CAS | EC number | Weight | Index-No. |
| ZINC CHLORIDE DRY AR | 7646-85-7 | 231-592-0 | 136.29 g/mol | 030-003-00-2 |
| Signal Word | Danger |
| Hazard Statements |
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
|
| Classification of the substance or mixture |
Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Skin corrosion (Sub-category 1B), H314 Serious eye damage (Category 1), H318 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Short-term (acute) aquatic hazard (Category 1), H400
Long-term (chronic) aquatic hazard (Category 1), H410 For the full text of the H-Statements mentioned in this Section, see Section 16
|
| P280 Wear protective gloves.P305 + P351 + P338 | NA |
| Precautionary statements - response |
P260 Do not breathe dust.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel
unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.P260 Do not breathe dust.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face
protection.
P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel
unwell.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
|
| Response | None |
| Disposal | NA |
| Prevention | NA |
| Supplemental Hazard Statements | None |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. Call in physician. |
| Eye Contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| Swallowed | After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately. |
| Inhalation | Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
| Ingestion | NA |
| Notes to Physician | NA |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | NA |
| Flash Point | NA |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture |
Hydrogen chloride gas Zinc/zinc oxides Not combustible.
Ambient fire may liberate hazardous vapours
|
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system |
|
Hazardous combustion products |
NA |
| Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothingStay in danger area only with self-contained breathing apparatus. Prevent skin contact by
keeping a safe distance or by wearing suitable protective clothing
|
| Protective Equipment | NA |
| Specific Hazards Arising from the Chemical | NA |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. | |
| Spillage | NA | |
| Personal Protection | NA | |
| Enviromental Precaution | Do not let product enter drains. | |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. | |
| Reference to other sections | For disposal see section 13. |
| Advice on safe handling | NA |
| Advice on protection against fire and explosion | NA |
| Hygiene measures | NA |
| Precautions for safe handling | For precautions see section 2.2. |
| Conditions for safe storage, including any incompatibilities |
Handle under nitrogen, protect from moisture. Store under nitrogen.
Tightly closed. Dry.
strongly hygroscopic
|
| Storage conditions | NA |
| Storage conditions | NA |
| Storage class | Storage class (TRGS 510): 8B: Non-combustible, corrosive hazardous materials |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Handling | NA |
| Advice on general occupational hygiene | NA |
| Application Area |
Routes of exposure |
Health effect | Value |
|
Worker DNEL,
longterm
longtermWorker DNEL,
longterm
longtermWorker DNEL,
longterm
|
Inhalation | Systemic effects | 1 mg/m3 |
| Remarks | Zinc | ||
|
Worker DNEL,
longterm
longtermWorker DNEL,
longterm
|
dermal | Systemic effects | |
| Zinc | |||
|
Consumer DNEL,
longterm
|
inhalation | Systemic effects | 1,3 mg/m3 |
| Zinc | |||
|
Consumer DNEL,
longterm
longtermConsumer DNEL,
longterm
longtermConsumer DNEL,
longterm
|
dermal | Systemic effects | |
| Zinc | |||
|
Consumer DNEL,
longterm
|
oral | Systemic effects | |
| Zinc |
| Compartment | Value |
| Fresh water | 20,6 μg/l |
| Remarks | Zinc |
| Fresh water sediment | 117,8 mg/kg Zinc |
| Sea water | 6,1 μg/l Zinc |
| Sea sediment | 56,5 mg/kg Zinc |
| Sewage treatment plant | 52 μg/lZinc |
| Soil | 35,6 mg/kgZinc |
| Occupational Exposure limit values | No data available |
| Biological limit values | No data available |
| Exposure controls | NA |
| Engineering Control | NA |
| Eye/face protection |
Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety
goggles
|
| Body Protection | protective clothing |
| Skin protection |
This recommendation applies only to the product stated in the safety data sheet,supplied by us and for the designated use. When dissolving in or mixing with othersubstances and under conditions deviating from those stated in EN374 please
contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell,
Internet: www.kcl.de).Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L
|
| Respiratory protection | required when dusts are generated.Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.These measures have to be properly documented. |
| Other Protection Measure | NA |
| Control of environmental exposure | Do not let product enter drains. |
| Thermal hazards | No data available |
Gloves Suit
| Physical state | Powder |
| Colour | White |
| Odour | Odorless |
| Odor Threshold | Not Applicable |
| pH | Not Applicable |
| Melting Point | 293 °C |
| Boiling Point | No data available |
| Flash Point | No data available |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | No data available |
| Decomposition temperature | No data available |
| Vapour pressure | No Data Available |
| Density | No data available |
| Vapour Density | No Data Available |
| Specific Gravity | No data available |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | 851 g/l at 20 °C - OECD Test Guideline 105- completely soluble |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Oxidizing properties | None |
| Other safety information | No data available |
| Reactivity | No data available |
| Chemical stability | The product is chemically stable under standard ambient conditions (room temperature) |
| Stability | No data available |
| Possibility of hazardous reactions |
Violent reactions possible with:sodium
Strong oxidizing agentsViolent reactions possible with:
sodium
Strong oxidizing agents
|
| Conditions to avoid |
Exposure to moisture.
no information availableExposure to moisture.
no information available
|
| Incompatible materials | various metals |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity | LD50 Oral - Rat - male - 1.100 mg/kg (OECD Test Guideline 401) Acute toxicity estimate Oral - 1.100 mg/kg (ATE value derived from LD50/LC50 value) LC50 Inhalation - Rat - female - 10 min - <= 1.975 mg/m3 - aerosol Remarks: (ECHA) LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402) |
| Skin corrosion/irritation |
Skin - MouseSkin - Mouse Remarks: (ECHA)
Remarks: (ECHA)Skin - Mouse
Remarks: (ECHA)
|
| Serious eye damage/eye irritation | Remarks: Risk of blindness! (Regulation (EC) No 1272/2008, Annex VI) |
| Respiratory or skin sensitization | Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) |
| Rout Of Entry | NA |
| Toxicity to Animal | NA |
| Toxic Effects on Human | NA |
| Germ cell mutagenicity |
Test Type: In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells Metabolic activation: without metabolic activation Result: negative
Remarks: (ECHA) Test Type: Micronucleu Species: Mouse Cell type: Red blood cells (erythrocytes) Application Route: Intraperitoneal Result: negative Remarks: (in analogy to similar products) (ECHA) The value is given in analogy to the following substances: Zinc sulphate
|
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | No data available |
| Special Remarks on other Toxi Effects on Humans: |
NA |
| Additional Information | Endocrine disrupting properties |
| Assessment |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 13 Weeks - NOAEL (No observed adverse effect level) - 31,52 mg/kg - LOAEL (Lowest observed adverse effect level) - 53,8 mg/kg RTECS: ZH1400000
Zinc chloride and its aqueous solutions are corrosive to the eyes and skin. They cause conjunctivitis and corneal burns in the eye and produce chemical burns, particularly on areas where the skin is broken. Ingestion produces a corrosive action to the mouth, throat, and digestive tract which can include symptoms of stomach pain, nausea, vomiting, bloody diarrhea, swelling of the throat, blood in the urine, and shock. Inhalation irritates the nose and throat producing cough, chest pain, bluish skin, fever, nausea and vomiting, shortness of breath, difficulty in breathing (onset may be delayed by several hours), and pneumonia. Fatalities have occurred by inhalation and ingestion., To the best of our knowledge, the
chemical, physical, and toxicological properties have not been thoroughly investigated.
|
| Endocrine disrupting properties | NA |
| Persistence and degradability | No data available |
| Toxicity | NA |
| Bioaccumulative potential | No data available |
| Toxicity to fish | Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 0,169 mg/l 96 h Remarks: (ECHA) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - 0,33 mg/l - 48 h(OECD Test Guideline 202) |
| Toxicity to algae |
Static test NOEC - Pseudokirchneriella subcapitata (green algae) -
0,0049 mg/l - 72 h (OECD Test Guideline 201)
|
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | NA |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.
|
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Assessment |
The substance/mixture does not contain components
considered to have endocrine disrupting properties
according to REACH Article 57(f) or Commission
Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
|
| Other adverse effects | No data available |
| Disposal methods | NA |
| Contaminated packaging | NA |
| Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questionsSee www.retrologistik.com for processes regarding the return of chemicals and
containers, or contact us there if you have further questions
|
| UN number | ADR/RID: 2331 IMDG: 2331 IATA: 2331 |
| UN proper shipping name |
ADR/RID: ZINC CHLORIDE, ANHYDROU IMDG: ZINC CHLORIDE, ANHYDROUS
IATA: Zinc chloride, anhydrous
|
| Transport hazard class(es) | ADR/RID: 8 IMDG: 8 IATA: 8 |
| Packaging group | ADR/RID: III IMDG: III IATA: III |
| Environmental hazards | ADR/RID: yes IMDG Marine pollutant: yes IATA: no |
| Special precautions for user |
Tunnel restriction code : (E)
Further information : No data available
|
| Further information | NA |
| Transport in bulk according to IMOinstruments | No data available |
| Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.This material safety data sheet complies with the requirements of Regulation (EC) No.
1907/2006.
|
| Safety, health and environmental regulations specific for the product in question | NA |
| National legislation |
Seveso III: Directive 2012/18/EU of the European
Parliament and of the Council on the control of
major-accident hazards involving dangerous
substances.
|
| DSCL (EEC) | NA |
| Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or
stricter national regulations where applicable.
Take note of Dir 94/33/EC on the protection of young people at work.
|
| Chemical Safety Assessment | A Chemical Safety Assessment has been carried out for this substance |
| Full text of H-Statements referred to under sections 2 and 3. |
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H400 Harmful if swallowed.
H410 Causes severe skin burns and eye damage.
|
| Further information |
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
Copyright 2020 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies
for internal use only. The branding on the header and/or footer of this document may temporarily not visually match the product purchased as we transition our branding. However, all of the information in the document regarding the product remains unchanged and matches the product ordered. For further information please contact mlsbranding@sial.com.
|
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
| ZINC CHLORIDE DRY AR |
| ZINC CHLORIDE DRY AR |
| ZINC CHLORIDE DRY AR |
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