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Product Name |
SULFOLANE |
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Part Number |
RXSOL-93-9303-250 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.com |
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Chemical Name |
CAS |
EC number |
Weight |
Formula |
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Sulpholane |
126-33-0 |
204-783-1 |
<= 100 % |
C4H8O2S |
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Signal Word |
Danger |
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Hazard Statements |
H302 Harmful if swallowed.
H360FD May damage fertility. May damage the unborn child.
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P280 Wear protective gloves.P305 + P351 + P338 |
Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Precautionary statements response |
P202 Do not handle until all safety precautions have been read and understood. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P308 + P313 IF exposed or concerned: Get medical advice/ attention. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air. Call in physician. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
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Inhalation |
Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
May be combustible at high temperature. |
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Suitable extinguishing media |
Water Foam Carbon dioxide (CO2) Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Carbon oxides Sulfur oxides Combustible. Fire may cause evolution of: Sulfur oxides Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. |
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Further information |
Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid inhalation of vapours/aerosols or dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. |
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Reference to other sections |
For disposal see section 13. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. |
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Precautions for safe handling |
For precautions see section 2.2. |
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Conditions for safe storage, including any incompatibilities |
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
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Storage conditions |
Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Recommended storage temperature see product label. |
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Storage class |
Storage class (TRGS 510): 6.1C: Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
Derived No Effect Level (DNEL)
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Application Area |
Routes of exposure |
Health effect |
Value |
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Worker DNEL, longterm |
dermal |
Systemic effects |
--- |
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Worker DNEL, |
Inhalation |
Systemic effects |
9 mg/m3 |
Predicted No Effect Concentration (PNEC)
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Compartment |
Value |
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Fresh water |
0,1 mg/l |
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Sea sediment |
0,01 mg/l |
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Fresh water sediment |
0,449 mg/kg |
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Sea sediment |
0,0449 mg/kg |
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Soil |
0,03104 mg/kg |
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Occupational Exposure limit values |
No specific occupational exposure limit has been established. |
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Biological limit values |
No data available |
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Exposure controls |
No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
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Engineering Control |
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
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Body Protection |
protective clothing |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 480 min Material tested:KCL 720 Camapren® This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Latex gloves Minimum layer thickness: 0,6 mm Break through time: 30 min Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M) |
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Respiratory protection |
Recommended Filter type: Filter A-(P2) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. |
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Physical state |
Solid mass, deliquescent |
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Colour |
White |
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Odour |
No data available |
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Odor Threshold |
Not Applicable |
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pH |
No data available |
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Melting Point |
27 °C |
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Boiling Point |
285 °C at 1.013 hPa |
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Flash Point |
177 °C - |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
No data available |
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Autoignition temperature |
No data available |
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Decomposition temperature |
No data available |
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Vapour pressure |
0,035 hPa at 30 °C |
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Density |
1,26 g/cm3 at 30 °C |
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Vapour Density |
No Data Available |
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Freezing point |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
No data available |
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Explosive properties |
No data available |
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Water Solubility |
100 g/l at 25 °C - OECD Test Guideline 105 |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
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Possibility of hazardous reactions |
Violent reactions possible with: Strong oxidizing agents. |
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Conditions to avoid |
Strong heating. |
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Incompatible materials |
Strong oxidizing agents. |
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Hazardous Polymerization |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Mouse - 1.900 mg/kg Remarks: (RTECS) Acute toxicity estimate Oral - 1.900 mg/kg (ATE value derived from LD50/LC50 value) Inhalation: No data available LD50 Dermal - Rat - male and female - > 2.000 mg/kg (Regulation (EC) No. 440/2008, Annex, B.3) |
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Skin corrosion/irritation |
Skin - Rabbit Result: No skin irritation Remarks: (ECHA) |
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Serious eye damage/eye irritation |
Eyes - In vitro study Result: No eye irritation (OECD Test Guideline 492) |
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Respiratory or skin sensitization |
Adjuvant and patch test - Guinea pig Result: negative (Regulation (EC) No. 440/2008, Annex, B.6) |
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Serious eye damage/eye irritation |
Eyes - Rabbit Result: Mild skin irritant Remarks: (ECHA) |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Germ cell mutagenicity |
Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Mouse lymphoma test Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive Test Type: In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 490 Result: negative Test Type: Chromosome aberration test in vitro Test system: Chinese hamster lung cells Metabolic activation: with and without metabolic activation Result: negative Remarks: (ECHA) Test Type: In vitro mammalian cell gene mutation test Test system: Mouse lymphoma test Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive |
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Carcinogenicity |
This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. |
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Reproductive toxicity |
May damage the unborn child. May damage fertility. |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Additional Information |
RTECS: AF3675000 Gastrointestinal disturbance To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After uptake of large quantities: muscular symptoms agitation Convulsions Headache Tremors Nausea psychoses |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 13 Weeks - NOAEL (No observed adverse effect level) - 25 mg/kg To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Systemic effects: If swallowed Gastrointestinal disturbance agitation, spasms Absorption can result in damage to:Handle in accordance with good industrial hygiene and safety practice. |
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Persistence and degradability |
Biodegradability aerobic - Exposure time 14 d Result: 10,1 % - Not readily biodegradable. (OECD Test Guideline 301C) |
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Toxicity to fish |
Static test LC50 - Oryzias latipes - > 100 mg/l - 96 h (OECD Test Guideline 203) |
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Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia magna (Water flea) - 852 mg/l - 48 h (OECD Test Guideline 202) |
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Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata (algae) - > 1.000 mg/l - 72 h (OECD Test Guideline 201) |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
Discharge into the environment must be avoided. |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. |
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Waste treatment Method |
No data available |
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UN number |
ADR/RID: IMDG: IATA: 3334 |
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UN proper shipping name |
ADR/RID:Not dangerous goods
IMDG:Not dangerous goods
IATA: Aviation regulated liquid, n.o.s.
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Transport hazard class(es) |
ADR/RID: IMDG: IATA: 9 |
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Packaging group |
ADR/RID: IMDG: IATA: III |
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Environmental hazards |
ADR/RID: No IMDG: No IATA: No |
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Special precautions for user |
No data available |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Transport in bulk according to IMOinstruments |
No data available |
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Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 |
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Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : OXIDISING LIQUIDS AND SOLIDS |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
A Chemical Safety Assessment has been carried out for this substance. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
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