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Product Name |
Amyl Alcohol SEC |
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Part Number |
RXSOL-19-1231-210 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
rxsolchemicals@gmail.com |
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Website |
www.rxmraine.com |
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Chemical Name |
CAS |
EC number |
Weight |
Formula |
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Amyl alcohol |
71-41-0 |
200-752-1 |
<= 100 % |
C5H12O |
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Signal Word |
Danger. |
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Hazard Statements |
H226 Flammable liquid and vapor. H315 Causes skin irritation. H318 Causes serious eye damage. H332 Harmful if inhaled. H335 May cause respiratory irritation. |
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P280 Wear protective gloves.P305 + P351 + P338 |
Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Precautionary statements |
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Classification of the substance or mixture |
Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
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Supplemental Hazard Statements |
None |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Lachrymator. |
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General advice |
Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air. |
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Eye Contact |
After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
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Inhalation |
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. |
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Extinguishing Media |
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fireexposed containers. Water may be ineffective. Do NOT use straight streams of water. |
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Ingestion |
Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
Flammable. |
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Flash Point |
23 deg C ( 73.40 deg F). |
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Suitable extinguishing media |
Carbon dioxide (CO2) Foam Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Nature of decomposition products not known. Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire. |
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Further information |
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
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Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
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Small Spillage |
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. |
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Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
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Enviromental Precaution |
Do not let product enter drains. Risk of explosion. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
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Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2. |
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Precautions for safe handling |
For precautions see section 2.2. |
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Conditions for safe storage, including any incompatibilities |
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
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Storage conditions |
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. |
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Storage class |
Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Requirements for storage |
Keep in cool and store under shade. |
Derived No Effect Level (DNEL)
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Application Area |
Routes of exposure |
Health effect |
Value |
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Worker DNEL, longterm |
inhalation |
Systemic effects |
73,16 mg/m3 |
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Worker DNEL, longterm |
inhalation |
Local effects |
73,16 mg/m3 |
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Worker DNEL, acute |
inhalation |
Systemic effects |
292 mg/m3 |
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Worker DNEL, acute |
inhalation |
Local effects |
292 mg/m3 |
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Consumer DNEL, longterm |
inhalation |
Systemic effects |
15,4 mg/m3 |
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Consumer DNEL, longterm |
inhalation |
Local effects |
15,4 mg/m3 |
Predicted No Effect Concentration (PNEC)
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Compartment |
Value |
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Fresh water |
0,013 mg/l |
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Sea water |
0,0013 mg/l |
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Aquatic intermittent release |
0,13 mg/l |
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Fresh water sediment |
0,055 mg/kg |
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Sea sediment |
0,0055 mg/kg |
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Soil |
2,5 mg/kg |
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Sewage treatment plant |
37 mg/l |
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Exposure controls |
TWA: 100 from ACGIH (TLV) [United States] Consult local authorities for acceptable exposure limits. |
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Engineering Control |
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
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Body Protection |
Flame retardant antistatic protective clothing. |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 480 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 240 min Material tested:KCL 720 Camapren® |
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Respiratory protection |
Required when vapours/aerosols are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type ABEK The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. Risk of explosion. |
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Physical state |
Liquid |
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Colour |
No data available |
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Odour |
No data available |
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Odor Threshold |
0.052 ppm |
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pH |
7 [Neutral.] |
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Melting Point |
78 °C - lit. |
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Boiling Point |
148°C (298.4°F) |
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Flash Point |
49 °C |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
8,0 %(V)/1,6 %(V) |
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Autoignition temperature |
300 °C at 1.004 - 1.008 hPa - DIN 51794 |
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Decomposition temperature |
No data available |
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Viscosity |
Dynamic: 3,441 mPa.s at 24,9 °C |
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Vapour pressure |
2,04 hPa at 20 °C |
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Density |
0,811 g/cm3 at 25 °C |
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Relative density |
Not available. |
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Vapour Density |
4.5 (air=1) |
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Freezing point |
No data available |
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Specific Gravity |
No data available |
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Partition coefficient |
log Pow: 1,41 at 25 °C |
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Explosive properties |
No data available |
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Solubility |
21 g/l at 20 °C |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Reactivity |
Vapor/air-mixtures are explosive at intense warming. |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature) . |
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Possibility of hazardous reactions |
Risk of ignition or formation of inflammable gases or vapours with: Fluorine Oxygen Violent reactions possible with: Oxidizing agents Alkali metals Alkaline earth metals halogens Acid chlorides Isocyanates lithium silicide acids |
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Conditions to avoid |
Heating. |
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Incompatible materials |
Rubber, various plastics |
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Hazardous Polymerization |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - male and female - 3.645 mg/kg (OECD Test Guideline 401) Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor(Expert judgment) Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment) LD50 Dermal - Rabbit - male - 2.292 mg/kg (OECD Test Guideline 402) |
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Skin corrosion/irritation |
Skin - Rabbit Result: Irritations - 20 h Remarks: (ECHA) |
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Serious eye damage/eye irritation |
Eyes - Rabbit Result: Causes serious eye damage.(OECD Test Guideline 405) Remarks: (ECHA) |
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Respiratory or skin sensitization |
Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) |
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Toxicity to Animal |
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat]. |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Carcinogenicity |
No data available |
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Germ cell mutagenicity |
Test Type: Micronucleus test Test system: Chinese hamster fibroblasts Metabolic activation: with and without metabolic activation Result: negative Remarks: (ECHA) Test Type: Ames test Test system: S. typhimurium Metabolic activation: with and without metabolic activation Result: negative Remarks: (ECHA) |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
No data available |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Additional Information |
RTECS: AF3675000 Gastrointestinal disturbance To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After uptake of large quantities: muscular symptoms agitation Convulsions Headache Tremors Nausea psychoses |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - NOAEL (No observed adverse effect level) - 1.000 mg/kg Repeated dose toxicity - Rat - male - inhalation (vapor) Remarks: (ECHA) RTECS: SB9800000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.After absorption: Headache somnolence lack of appetite Nausea Vomiting Diarrhea Dizziness Unconsciousness Coma narcosis Possible damages: Damage to: Liver Kidney Cardiac Lungs Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. Liver - Irregularities - Based on Human Evidence. |
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Persistence and degradability |
Biodegradability aerobic - Exposure time 18 d Result: 100 % - Readily biodegradable. (OECD Test Guideline 310) Biochemical Oxygen Demand (BOD) 1.278 mg/g Remarks: (IUCLID) Chemical Oxygen Demand (COD) 1.814 mg/g Remarks: (IUCLID) Ratio BOD/ThBOD 47 % |
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Toxicity to fish |
Static test LC50 - Danio rerio (zebra fish) - 530 mg/l - 96 h Remarks: (ECHA) |
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Toxicity to daphnia and other aquatic invertebrates |
Static test EC50 - Daphnia magna (Water flea) - 341,21 mg/l - 48 h (Regulation (EC) No. 440/2008, Annex, C.2) |
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Toxicity to algae |
Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - > 100 mg/l - 72 h (OECD Test Guideline 201) static test NOEC - Pseudokirchneriella subcapitata (green algae) - 100 mg/l - 72 h (OECD Test Guideline 201) |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
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Other adverse effects |
Additional ecological information No data available |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID: 1105 IMDG: 1105 IATA: 1105 |
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UN proper shipping name |
ADR/RID: PENTANOLS IMDG: PENTANOL IATA: PENTANOLS |
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Transport hazard class(es) |
ADR/RID: 3 IMDG: 3 IATA: 3 |
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Packaging group |
ADR/RID: III IMDG: III IATA: III |
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Environmental hazards |
ADR/RID: no IMDG Marine pollutant: no IATA: no |
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Special precautions for user |
Tunnel restriction code : (D/E) |
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Further information |
No data available |
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Inventory status |
Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : FLAMMABLE LIQUIDS |
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Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
A Chemical Safety Assessment has been carried out for this substance. |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
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