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Food Additive

Dibromo Dimethyl Hydantoin

A white crystalline solid that is sparingly soluble in water.
Part number
RXSOL-69-5961-050
Brand
RXSOL
RXSOL

Overview

Dibromo dimethyl hydantoin (DBDMH) is an organic compound that is used as a antimicrobial preservative by discharging formaldehyde as a disinfectant and a reagent for bromination. It is also used as a bleaching agent and for treating water cooling systems.

Applications

This white crystalline compound with a slight bromine odor is widely used as a disinfectant used for drinking water purification, recreational water treatment, as a bleaching agent in pulp and paper mills, and for treating industrial/commercial water cooling systems.

Dosage and directions

DMDM (dimethyl-dimethyl) hydantoin is an organic compound that is a member of the hydantoin family. It functions as an antimicrobial preservative by discharging formaldehyde. It is a broad-spectrum preservative that is effective against fungi, yeast, and gram-positive and gram-negative bacteria.

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet

Porduct Name               Dibromo dimethyl hydantoin
Part Number   RXSOL-69-5961-050

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
Website www.rxmraine.com

Chemical Name                 Cas No                        EC No              Weight                          Formula                   
1,3-Dibromo-5,5-dimethylhydantoin for        synthesis 77-48-5 201-030-9 285,92 g/mol C5H6Br2N2O2
Signal Word  Danger
Hazard Statements H272 May intensify fire; oxidizer. H301 Toxic if swallowed. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects
Precautionary statements   P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe dust. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of    the substance      or mixture   No data available
Supplemental Hazard    Statements No data available
Other hazards  This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher  The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

General advice First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled After inhalation fresh air.
Eye Contact  Rinse out with plenty of water. Remove contact lenses
Swallowed If swallowed give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.
Skin Contact   In case of skin contact Take off immediately all contaminated clothing. Rinse skin with water/ shower.
Inhalation No data available
Ingestion No data available
Most important    symptoms and effects,  both acute and delaye The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 
Indication of any    immediate medical    attention and special      treatment needed  No data available

Flammability                         No data available
Suitableextinguishing  media  Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing      media For this substance/mixture no limitations of extinguishing agents are given
Special hazards arising  from   the substance or mixture  Carbon oxides Nitrogen oxides (NOx) Hydrogen bromide gas Combustible. Fire may cause evolution of: hydrogen bromide, nitrogen oxides, nitrous gases Development of hazardous combustion gases or vapours possible in the event of fire. Has a fire-promoting effect due to release of oxygen.
Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion
products
No data available
Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Protective Equipment No data available
Specific Hazards  Arising        from  the Chemical No data available

Personal precautions,    protective equipment and      emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage No data available
Personal Protection No data available
Enviromental Precaution Do not let product enter drains. Risk of explosion.
Methods and materials for
containment and cleaning
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area
Reference to other          sections    For disposal see section 13

Advice on protection    against fire and              explosion Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. 
Incompatible materials  No data available
Hygiene measures Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Advice on  safe handling No data available
Conditions for safe    storage, including any      incompatibilities 

No data available

Storage conditions No metal or light-weight-metal containers. Protected from light.Tightly closed. Away from combustible materials and sources of ignition and heat. Keep locked up or in an area accessible only to qualified or authorized persons. Do not store near combustible materials. Recommended storage temperature see product label
Storage class Storage class (TRGS 510) 5.1B Oxidizing hazardous materials
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general      occupational hygiene No data available

Exposure controls  Personal protective equipment 
Engineering Control No data available
Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection Protective clothing
Skin protection This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: butyl-rubber Minimum layer thickness: 0,7 mm Break through time: 30 min Material tested:Butoject® (KCL 898)
Respiratory protection
Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type Filter type P3 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection  Measure No data available

Physical state Powder, Finecrystalline
Colour Light yellow
Odour Stinging
Odor Threshold No data available
pH No data available
Melting Point 177 - 179 °C at 1.013 hPa - OECD Test Guideline 102 - Decomposition
Boiling Point No data available 
Flash Point No data available 
Evaporation Rate No data available
Flammability (solid, gas) No data available
Explosive limits No data available
Upper/lower flammability or explosive        limits No data available 
Autoignition temperature No data available 
Decomposition temperature  No data available 
Vapour pressure No data available                                         
Viscosity No data available 
Density 1,00 g/cm3 at 25 °C
Relative Density No data available  
Specific Gravity No data available 
Partition coefficient Log Pow -0,94 - (Lit.), Bioaccumulation is not expected
Explosive properties No data available 
Solubility 1 g/l at 20 °C
Ignition temperature No data available 
Particle characteristics No data available 

Reactivity                        The following applies in general to flammable organic substances and mixtures in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed
Chemical stability The product is chemically stable under standard ambient conditions (room temperature)
Possibilityof hazardous      reactions Exothermic reaction with Strong acids strong alkalis Strong oxidizing agents strong reducing agents Violent reactions possible with: Alcohols phosphorus Ketones Reducing agents Acids Ammonia ammonium compounds
Conditions to avoid No data available                                                                           
Incompatible materials
Iron, Aluminum, Copper
Hazardous product        dicomposition                                                         No data available

Acute toxicity  LD50 Oral - Rat - 250 mg/kg Remarks: (RTECS) Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Acute toxicity estimate Oral - 250 mg/kg (ATE value derived from LD50/LC50 value)
Skin corrosion/irritation Skin - Rabbit Result Causes burns. (External MSDS)
Serious eye      damage/irritation Eyes - Rabbit Result Causes burns. (External MSDS) Causes serious eye damage
Respiratory or skin    sensitization  Sensitisation test - Guinea pig Result positive  (External MSDS)
Carcinogenicity No data available
Germ  cell            mutagenicity  No data available
Reproductive toxicity  No data available
Specific target organ toxicity-single      exposure
No data available
Additional Information Assessment The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice

Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 0 % - Not readily biodegradable. Remarks: (HSDB)
Toxicity to fish  Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 0,58 mg/l - 96 h
Toxicity to daphnia and other  aquatic invertebrates EC50 - Daphnia magna (Water flea) - 0,84 mg/l - 48 h  (ECOTOX Database)
Toxicity No data available
Toxicity to bacteria   No data available
Toxicity to algae No data available
Products Biodegradation No data available
Mobility in soil No data available
Results of PBT av PvB            assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting        properties The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects  Discharge into the environment must be avoided

Product No data available
Contaminated packaging No data available
Waste treatment  Method No data available

UN number

ADR/RID:3084                                   IMDG:3084                              IATA:3084 

UN proper shipping name  ADR/RID:CORROSIVE SOLID, OXIDIZING, N.O.S. (1,3-dibromo-5,5-                 dimethylhydantoin)  IMDG:CORROSIVE SOLID, OXIDIZING, N.O.S. (1,3-dibromo-5,5-dimethylhydantoin) IATA:CORROSIVE SOLID, OXIDIZING, N.O.S. (1,3-dibromo-5,5-dimethylhydantoin)
Transport hazard    classess               ADR/RID: 8 (5.1)                               IMDG:8 (5.1)                              IATA:8 (5.1) 
Packaging group ADR/RID:ll                                         IMDG:ll                                       IATA:ll
Environmental hazards ADR/RID:No                                      IMDG Marine pollutant:No         IATA: No
Special precautions for  user Tunnel restriction code (E)
Further information No data available

Safety, health and environmental    regulations/legislation specific for the      substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

No data available

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