PICRIC ACID LR NOT for SALE
PICRIC ACID LR
- Part number
- RXSOL-60-6605-255
- Category
- Leather Chem
- Brand
- RXSOL
Overview
Picric acid is an organic compound with the formula (O2N)3C6H2OH. Its IUPAC name is 2,4,6-trinitrophenol (TNP). Like other strongly nitrated organic compounds, picric acid is an explosive, which is its primary use. NOT FOR SALE
Applications
Picric acid is used in the production of explosives, matches, and electric batteries. It is also used in etching copper and manufacturing colored glass, in the leather industry, and in the synthesis of dyes. Picric acid is very unstable and is a flammmable/combustible material. It may be ignited by heat, sparks, or flames. Dried-out picric acid may explode if expose to heat, flame, friction, or shock, and should be treated as an explosive. Picric acid can react vigorously with oxidizing materials, and it can form unstable salts with concrete, ammonia, bases, and metals.
Dosage and directions
doses of tannic acid (0.5 to 1.0 percent) daily for 3 days
Characteristics and notes
Picric acid (2,4,6-trinitrophenol) is one of the toxic nitroaromatic compounds present in over 1000 munition sites in the United States, and this constitutes a major environmental and human health hazard. In a laboratory study, 250 mg/l of picric acid was degraded in an aqueous medium with Fenton's reagent [acidified ferrous (Fe(2+)) solution and hydrogen peroxide (H(2)O(2))]. Different dosages of Fe(2+) and H(2)O(2) were employed to investigate the efficiency of the degradation. NOT FOR SALE ONLY FOR EDUCATIONAL PURPOSE
Safety and SDS
Read the safety data sheet before handling. Wear suitable gloves and eye protection.
View safety data sheet
| Product Name |
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| Product Type | PICRIC ACID LR | |
| Revised date |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
| Phone | +91 22 27815541 / 42 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| rxsolchemicals@gmail.com |
Substance / Preparation : 2,4,6-trinitrophenol; picric acid
CAS No :88-89-1
Substance.
Substance name Contents CAS No
Water 75-99 732-18-5
2,4,6-trinitrophenol picric acid : 1-5% 88-89-1
Contains no other components or impurities which will influence the classification of the
product.
3.1 Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : F; R11
T; R23/24/25
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Acute toxicity, Inhalation - Category 3 - Danger (CLP : Acute Tox. 3)
H331
Acute toxicity, Oral - Category 3 - Danger (CLP : Acute Tox. 3) H301
Acute toxicity, dermal - Category 3 - Danger (CLP : Acute Tox. 3) H311
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : F : Highly flammable
T : Toxic
R Phrase(s) :R3 : Extreme risk of explosion by shock friction. Fire or other source of
ignition.
R4 : Forms very sensitive explosive metallic compounds.
R23/24/25 : Toxic by inhalation, in contact with skin and if swallowed.
S Phrase(s) : S28 : After contact with skin, wash immediately with plenty of …(to be
specified by manufacturer).
S35 : This material and its container must be disposed of in a safe way.
S36/37 : Wear suitable protective clothing and gloves.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Danger
Hazard statements : H301 : Toxic if swallowed.
H311 : Toxic in contact with skin.
H331 : Toxic if inhaled. Precautionary statements
• Prevention : P280: Wear protective gloves, protective clothing, eye protection, face
protection.
P271: Use only outdoors or in a well-ventilated area.
P261: Avoid breathing dust, fume, gas, mist, vapours, spray.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P301+P310: IF SWALLOWED : Immediately call a POISON CENTER
or doctor.
P302+P352: IF ON SKIN : Wash with plenty of soap and water.
P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position
comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P361: Remove immediately all contaminated clothing.
• Storage : P403+P233: Store in well-ventilated place. Keep container tightly closed.
P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
P501: Dispose of this material and its container to hazardous or special waste
collection point, in accordance with local, regional, national and/or international
regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest. Immediately call a
POISON CENTER or doctor. Specific treatment (see on this label). Remove to fresh air
and keep at rest in a position comfortable for breathing.
Skin contact : Remove affected clothing and wash all exposed skin area with mild soap
and water, followed by warm water rinse. Specific treatment (see on this label).
Immediately call a POISON CENTER or doctor. Wash with plenty of soap and
water. Remove/Take off immediately all contaminated clothing. Wash contaminated
clothing before reuse.
Eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain,
blinking or redness persist.
Ingestion : Specific treatment (see on this label). Immediately call a POISON CENTER
or doctor. Do NOT induce vomiting. Rinse mouth.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Repeated exposure to this material can result in absorption
through skin causing significant health hazard. Danger of serious damage to health by
prolonged exposure through inhalation. Swallowing a small quantity of this material will
result in serious health hazard.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person. If you
feel unwell, seek medical advice (show the label where possible).
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream
Surrounding fires : Use water spray or fog for cooling exposed containers
. 5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth
as soon as possible. Store away from other materials. Collect spillage.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Use only outdoors or in a well-ventilated area. Avoid breathing dust, fume
, gas, mist, vapours, spray. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container tightly closed.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure
• Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke
. 8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : No data available.
Melting point [°C] : 121 - 123 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : 300°C
Flammability (solid, gas) : N/A
Flash point [°C] : 150 °C
Boiling point [°C] : N/A
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : N/A
Vapour density : 7,9
Density [g/cm3] : 1,763
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : Soluble in water
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : N/A
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established
. 10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Toxic if inhaled.
• Dermal : Toxic in contact with skin.
• Ingestion : Toxic if swallowed.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Based on available data, the classification criteria are not met.
Toxic for reproduction : Based on available data, the classification criteria are not met.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not
met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Not established.
12.2. Persistence - degradability
Persistence - degradability : Biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.
Special precautions : Hazardous waste due to toxicity
14.1. Land transport (ADR-RID)
Proper shipping name : TRINITROPHENOL (PICRIC ACID), WETTED with not less
than 30% water, by mass
UN N° : 1344
ADR - Class : 4.1
Labelling - Transport : 4.1 : Flammable solids, self-reactive substances and desensitized
explosives.
ADR - Group : I
ADR - Tunnel code
14.2. Sea transport (IMDG) [English only]
Proper shipping name : TRINITROPHENOL (PICRIC ACID), WETTED with not less
than 30% water, by mass
UN N° : 1344
IMO-IMDG - Class or division : 4.1 : Flammable solids, self-reactive substances and
desensitized explosives.
IMO-IMDG - Packing group : I
IMO-IMDG - Marine pollution : No
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : TRINITROPHENOL (PICRIC ACID), WETTED with not less
than 30% water, by mass
UN N° : 1344
IATA - Class or division : 4.1 : Flammable solids, self-reactive substances and
desensitized explosives.
IATA - Packing group : I
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 451
instruction
- Passenger and Cargo - Maximum : 1 kg
Quantity/Packing
- Cargo only - Packing instruction : 451
- Cargo only - Maximum Quantity/ : 15 kg
Packing ERG-Nr : 3E
15.1. Safety, health and environmental regulations/legislation specific for
the substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLPRegulation
(CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was
obtained from sources which we believe are reliable. However, the information is
provided without any warranty, express or implied, regarding its correctness. The
conditions or methods of handling,storage, use or disposal of the product are beyond our
control and may be beyond our knowledge. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This MSDS
was prepared and is to be used only for this product. If the product is used as a
component in another product, this MSDS information may not be applicable
Availability
PICRIC ACID LR NOT FOR SALE ONLY FOR EDUCATIONAL PURPOSE
Lab chemicals manufacturers, suppliers, exporters in India, UAE Middle East, Barka, Sohar, Muscat, Oman, Canada.
PICRIC ACID LR NOT FOR SALE ONLY FOR EDUCATIONAL PURPOSE
