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Test Kit For Water

Carbohydrazide Test KIT

The test develops a peach-pink colored complex within 1 minute that is then matched to a color comparator.
Part number
RXSOL-62-2541-001
Brand
RXSOL
RXSOL

Overview

RXSOL convenient visual test kits utilize PDTS chemistry to test for carbohydrazide. The test develops a peach-pink colored complex within 1 minute that is then matched to a color comparator. Readings are obtained in ppm (mg/L) carbohydrazide.

Technical specifications

Why Hydrazine is replace by Carbohydrazide ?
Carbohydrazide (CH6N4O) - RXSOL-42-2541-025 is an oxygen scavenger often added to boiler systems to control corrosion. It reacts with oxygen at low temperatures and pressures. It also passivates metal surfaces preventing further corrosion. The reaction products are volatile, so they do not contribute to dissolved solids in the system. Carbohydrazide is widely used to replace hydrazine as an oxygen scavenger because it is less toxic.

Applications

Why Test for Carbohydrazide?
As an oxygen scavenger, carbohydrazide is a critical component employed to prevent corrosion within a system. Testing for carbohydrazide ensures the dosing of systems with sufficient chemical to protect metal from corrosion but not so much that treatment chemicals are wasted. Regular testing therefore ensures maximum efficiency of the boiler system.

Dosage and directions

The PDTS Method : Reference: G. Frederick Smith Chemical Co., The Iron Reagents, 3rd ed., p. 47 (1980). The test kits employ the PDTS chemistry. Carbohydrazide Reduces Ferric iron to the Ferrous state, and the Ferrous iron reacts with PDTS (3-(2-pyridyl)-5,6-bis (4-phenylsulfonic acid)-1,2,4-triazine disodium salt) to form a peach-pink colored complex in direct proportion to the carbohydrazide concentration. Test results are expressed as ppm (mg/L) carbohydrazide.

Characteristics and notes

For testing Hydrazine or Carbohydrazide 
The kit includes 2 x 65ml 10% Sulphuric Acid and 2 x 6.5g Hydrazine Reagent Powder
Use Colour Comparator: 
LOVIBOND 2000 COMPARATOR (555565)

Safety and SDS

Read the safety data sheet before handling. Wear suitable gloves and eye protection.

View safety data sheet
Product Name               Carbohydrazide Test KIT  
Part Number   RXSOL-62-2541-001

Company Details:....

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA  

Phone +91 22 20871200 - 1400
Fax +91 22 27612100 :::AOH :0091 9821214367
Email rxsolchemicals@gmail.com
Website www.rxmraine.com

Substances

Formula      CH6N4O
Molecular weight       90,08 g/mol      
CAS-No. 497-18-7
EC-No. 207-837-2
Component Classification      Concentration                            
1,3-diaminourea    
CAS-No.             497-18-7
EC-No                207-837-2        
Acute Tox. 4; Skin Irrit. 2;
Skin Sens. 1; Aquatic
Chronic 2; H302, H315,
H317, H411
<= 100 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008  
Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Skin sensitization (Category 1), H317
Long-term (chronic) aquatic hazard (Category 2), H411
For the full text of the H-Statements mentioned in this Section, see Section 16.

Label elements

Signal Word Warning

Hazard Statements

H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.

Precautionary Statements

P273 Avoid release to the environment.
P280 Wear protective gloves.
P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. Rinse mouth.
P302 + P352 IF ON SKIN: Wash with plenty of water.
Supplemental Hazard Statements None
Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
levels of 0.1% or higher.

Description of first aid measures

General advice Consult a physician. Show this material safety data sheet to the doctor in attendance.
If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact Wash off with soap and plenty of water. Consult a physician.
In case of eye contact Flush eyes with water as a precaution.
If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed No data available

Extinguishing media

Suitable extinguishing media                                             Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
In a fire or if heated, a pressure increase will occur and the container may burst, with the
risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along
the ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back.
Carbon oxides
Nitrogen oxides (NOx)
Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information
No data available
spray to keep fire-exposed containers cool.Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust. For personal protection see section 8
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections For disposal see section 13.

Precautions for safe handling

Advice on safe handling  Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Advice on protection against fire and explosion Provide appropriate exhaust ventilation at places where dust is formed.
Hygiene measures Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities  
Storage conditions Keep container tightly closed in a dry and well-ventilated place. Store in cool place.
Storage class Storage class (TRGS 510): 11: Combustible Solids
Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Control parameters 

Ingredients with workplace control parameters

Exposure controls

Personal protective equipment

Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU)
2016/425 and the standard EN 374 derived from it.
Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator. For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EUEN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
Physical state Crystalline
Colour White
Odor Odorless
Melting point/freezing point Melting point/range: 150 - 153 °C - lit.
Initial boiling point and boiling range No data available
Flammability (solid, gas) No data available
Upper/lower flammability or explosive limits No data available
Flash point No data available
Autoignition temperature No data available
Decomposition temperature No data available
pH
6,7 - 8,3
materials.Extremely flammable in the presence of the following materials or conditions: oxidizing
materials.
Viscosity
Viscosity, kinematic: No data available
Viscosity, dynamic: No data available
Water solubility Soluble
Partition coefficient: n-octanol/water No data available
Vapor pressure 16 hPa at 20 °C                               
Density 1,020 g/cm3 at 20 °C
Relative density No data available
Relative vapor density No data available
Particle characteristics No data available
Explosive properties No data available
Oxidizing properties No data available
Other safety information No data available
Reactivity                        No data available
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous reactions No data available
Conditions to avoid No data available
Incompatible materials
Strong oxidizing agents, Strong acids, Copper, Zinc, Nickel, Lead, Brass
Hazardous decomposition products In the event of fire: see section 5

Information on toxicological effects

Acute toxicity 
LD50 Oral - Rat - female - 311 mg/kg
Acute toxicity estimate Oral - 311 mg/kg
(Calculation method)
Inhalation: No data available
Dermal: No data available                
Skin corrosion/irritation Remarks: No data available
Serious eye damage/eye irritation   No data available
Respiratory or skin sensitization No data available
Germ cell mutagenicity
Result: negative
Remarks: Histidine reversion (Ames)
Carcinogenicity
No data available
Reproductive toxicity No data available
Specific target organ toxicity - single exposure   No data available
Specific target organ toxicity - repeated exposure   No data available
Aspiration hazard No data available
 Additional Information
RTECS: FF2625000
To the best of our knowledge, the chemical, physical, and toxicological properties have not
been thoroughly investigated.
Persistence and degradability No data available
Toxicity to fish  Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates Static test EC50 - Daphnia magna (Water flea) - 42,81 mg/l - 48 h (OECD Test Guideline 202) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h
Toxicity to bacteria  EC10 - Bacteria - 14 mg/l - 72 h Remarks: (Lit.) EC5 - E.coli - 15.000 mg/l Remarks: (Lit.) (maximum permissible toxic concentration)
Toxicity to algae Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 74,35 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Products Biodegradation The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil No data available
Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting       properties No data available
Other adverse effects No data available .
Waste treatment methods  
Product Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging Dispose of as unused product.
UN number ADR/RID:3077                 IMDG:3077             IATA: 3077
UN proper shipping name 
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,3-diaminourea)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,3-diaminourea)

IATA: Environmentally hazardous substance, solid, n. o. s. (1,3-diaminourea) 

Transport hazard class(es)      ADR/RID: 9               IMDG: 9              IATA:9
Packaging group ADR/RID: IlI                 IMDG:     lII      IATA:IIl
Environmental hazards ADR/RID: No                     IMDG: No                IATA: No
Special precautions for user  
Further information EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9
Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment For this product a chemical safety assessment was not carried out
Other Information

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

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